简介:Multilayerblackphosphorus(BP)nanoplateletsofdifferentthicknesseswerepreparedbytheliquidphaseexfoliationmethodanddepositedontoyttriumaluminumgarnetsubstratestoformsaturableabsorbers(SAs).Thesewerecharacterizedwithrespecttotheirthickness-dependentsaturableabsorptionpropertiesat3μm.TheBP-SAswereemployedinapassivelyQ-switchedEr:Lu2O3laserat2.84μm.ByusingBPexfoliatedindifferentsolvents,stablepulsesasshortas359nsweregeneratedatanaverageoutputpowerofupto755mW.Therepetitionrateintheexperimentwas107kHz,correspondingtoapulseenergyof7.1μJ.TheseresultsprovethatBP-SAshaveagreatpotentialforopticalmodulationinthemid-infraredrange.
简介:Sn-dopedTiO_2nanoparticleswithhighsurfaceareaof125.7m~2·g~(-1)aresynthesizedviaasimpleone-stephydrothermaimethodandexploredasthecathodecatalystsupportforprotonexchangemembranefuelcells.ThesynthesizedsupportmaterialsarestudiedbyX-raydiffractionanalysis,energydispersiveX-rayspectroscopyandtransmissionelectronmicroscopy.Itisfoundthattheconductivityhasbeengreatlyimprovedbytheadditionof30mol%SnandPtnanoparticlesarewelldispersedonTi_(0.7)Sn_(0.3)O_2supportwithanaveragesizeof2.44run.ElectrochemicalstudiesshowthattheTi_(0.7)Sn_(0.3)O_2nanoparticleshaveexcellentelectrochemicalstabilityunderahighpotentialcomparedtoVulcanXC-72.Theas-synthesizedPt/Ti_(0.7)Sn_(0.3)O_2exhibitshighandstableelectrocatalyticactivityfortheoxygenreductionreaction.ThePt/Ti_(0.7)Sn_(0.3)O_2catalystreservesmostofitselectrochemicallyactivesurfacearea(ECA),anditshalfwavepotentialdifferenceis11mV,whichislowerthanthatofPt/XC-72(36mV)under10hpotentialholdat1.4Vvs.NHE.Inaddition,theECAdegradationofPt/Ti_(0.7)Sn_(0.3)O_2is1.9timeslowerthancommercialPt/XC-72under500potentialcyclesbetween0.6Vand1.2Vvs.NHE.Therefore,theassynthesizedPt/Ti_(0.7)Sn_(0.3)O_2canbeconsideredasapromisingalternativecathode,catalystforprotonexchangemembranefuelcells.
简介:Todemonstratetheviabilityofsteady-statetokamakoperationinahighperformanceregime,whichisoneofthekeyphysicsissuesforaviableeconomicfusionreactor,thequasi-stationaryreversedshear(RS)modeofoperationintheHL-2AtokamakhavebeenmodeledwiththeTRANSPcode.InordertosustaintheRSoperationtowardssteady-state,off-axiscurrentdrivewithlowerhybrid(LH)waveat2.45GHzisusedtocontrolthecurrentprofile.
简介:AnapplicatiopnoftheopticalpyrometerisstudiedformeasuringmonochromaticemissivitiesofcementclinkerwithvariousFe2O3contnet.Theidsaofusing“brightnesstemperature”isintroducedintotheeimssivitymeasurement.Inthismethod,thereisnoneedformeasuringanactualtemperatureofsamplesurfaces,onlywithdeterminingbothbrightnesstemperaturesofasampleandablackbodycantherequiredemissivitybeevaluatedaccordingtoWien'sradiationlaw.Inpractice,thecementclinkerisregardedasagreybody,themonochromaticemissivityisapproximatelyequaltothetotalemissivity,soasingle-colouropticalpyrometerisappliedforthispurpose,Testmeasurementsarecarriedouton10kindsofcementclinkers,Experimentaldataaretreatedbytheleastsquaremethod.Asaresult,theemissivityvariationwithtemperatureatacertainFe2O3contentisquitewellrepresentedbyεn=a+bT.Furthermore,thisworkfirstreportedthattheeimissivitiesofcementclinkerchangeconsierablywithFe2O3contents.Inmultiplecementproductionthisconclusionisveryimportant.
简介:Ithasbeenproposedthatfusionreactionsbetweenneutron-richlightnuclei,forexample24C,24Oand28Ne,maycontributetoachievingtheignitiontemperatureforexplosivecarbonburningprocessduringsuperbusrsts[1,2].Studiesoffusionreactionsinvolvingneutron-richnucleiarebeyondordinaryexperimentaltechniques,sincetheintensityofradioactivebeambecomelowforthesemeasurements[3].TheactivetargettechniqueusingTPC(TimeProjectionChamber),withpropertiesofmulti-sampling,highefficiencyandlowbackground,isasuitablesolutiontotheproblem.
简介:Unlikeorganic–inorganichybridperovskites,all-inorganiccesiumleadhalideperovskitesholdgreatpromisefordevelopinghigh-performanceoptoelectronicdevices,owingtotheirimprovedstability.Herein,weinvestigatetheperovskite-relatedCsPb2Br5nanoplatelets(NPLs)withtunableemissionwavelengthsviachangingthereactiontemperaturesto100°C,120°C,and140°C.ReactiontemperatureplaysakeyroleindeterminingtheshapesandthicknessesoftheresultingCsPb2Br5NPLs.AhighertemperatureisinfavoroftheformationofsmallerandthickerNPLs.Todeveloptheirpotentialapplicationsinoptoelectronicdevices,greenlightemittingdiodes(LEDs)andphotodetectorsbasedonCsPb2Br5NPLsarefabricated.ThegreenLEDsbasedonCsPb2Br5NPLssynthesizedat140°Cexhibitanexcellentpuregreenemission(fullwidthathalf-maximumof<20nm)anddisplayaluminousefficiencyof34.49lm∕Wunderanoperationcurrentof10mA.Moreover,thephotodetectorbasedonCsPb2Br5NPLssynthesizedat100°Chasbetterperformancewitharisetimeof0.426s,adecaytimeof0.422s,andaratioofthecurrent(withandwithoutirradiation)of364%.
简介:Entangledphotonsarethefundamentalresourceinquantuminformationprocessing.Howtoproducethemefficientlyhasalwaysbeenamatterofconcern.HereweproposeanewwaytoproducecorrelatedphotonsefficientlyfrommonolayerWS2basedonboundstatesinthecontinuum(BICs).TheBICsofradiationmodesinthemonolayerWS2arerealizedbydesigningthephotoniccrystalslab-WS2-slabstructure.Thegenerationefficiencyofcorrelatedphotonpairsfromsuchastructurehasbeenstudiedbyusingarigorousquantummodelofspontaneousparametricdown-conversionwiththeplanewaveexpansionmethod.ItisfoundthatthegenerationefficiencyofcorrelatedphotonpairsisgreatlyimprovedifthesignalandidlerfieldsarelocatedattheBICsdeterminedbytheinversescatteringmatrixofthestructure.Thisisincontrasttotheparametricdown-conversionprocessfortheenhancedgenerationofnonlinearwavesifthepumpfieldislocatedattheBICsdeterminedbythescatteringmatrixofthestructure.Thegenerationrateofthecorrelatedphotonpairscanbeimprovedby7ordersofmagnitudeinsomedesignedstructures.Thegeneratedquantumsignalsaresensitivetothewavelengthandexhibitnarrowedrelativelinewidth,whichisverybeneficialforquantuminformationprocessing.
简介:Inthispaper,thevariableseparationapproachisusedtoobtainlocalizedcoherentstructuresofthe(2+1)-dimensionalgeneralizedDavey-Stewarsonequations:iqt+1/2(qxx+qyy)+(R+S)q=O,Rx=-σ/2|q|2ySy=-σ/2|q|2/x.ApplyingaspecialBacklundtransformationandintroducingarbitraryfunctionsoftheseedsolutions,anabundanceofthelocalizedstructuresofthismodelisderived.Byselectingthearbitraryfunctionsappropriately,somespecialtypesoflocalizedexcitationssuchasdromions,dromionlattice,breathers,andinstantonsareconstructed.
简介:怪物状态在1D数组被学习了,并且许多不同怪物状态用不同模型被发现了。研究最近被扩大了到2D数组,但是仅仅到他们的阶段模型。这里,我们把它递非局部的联合的影响上的神经原和焦点的2D数组的一个nonphase模型。用广泛的数字模拟,令人惊讶地,我们发现这个系统能显示出以前观察的怪物状态的大多数类型,与以前的模型相对照,在怪物状态的仅仅或一些类型能在每个模型被观察的地方。我们也发现这个模型能显示出象gridding那样的一些特殊像怪物的模式和multicolumn模式,它以前仅仅在阶段模型被观察。进一步,我们在场一条有效途径,即,移开联合的一些连接,产生异构的联合,它导致多样的像怪物的模式并且甚至从一个像怪物的模式导致转变到另外一个。
简介:Thegreenlong-after-glowluminescencefromTb3+-dopedSr2SiO4phosphors,whicharesynthesizedbythehightemperaturesolidstatereactioninareductiveatmosphere,isobservedinthispaper.Theresultsshowthatunderultravioletexcitation,theobtainedphosphorsproduceanintensegreen-lighting-emissionfromtheTb3+,andthegreen-lightinglongafter-glowluminescencerelatedtoTb3+canlasthalfanhouraftertheirradiationsourcehasbeenremoved.Moreover,theeffectsofco-dopingLi+,Dy3+,Er3+,Gd3+,andYb3+withTb3+onthedecaypropertiesandthermoluminescencepropertiesareinvestigatedtoconfirmthelong-after-glowmechanism.
简介:ThecharacteristicsofradiationanddryingpropertiesofTiO2bulbinthefixedbedwithinfraredradiationhavebeenstudiedinthispaper,andtheexperimentsondryingdynamicshasbeenanalysedalso.Theoptimizationofheatandmasstransferdatahasbeendetermined,whichcouldprovidethescientificbasisengineeringdesign.
简介:Theremediationofgroundwaterwhichcontainschlorinatedorganiccompounds(COCs)bynanoscalebimetalliccatalystshasreceivedincreasinginterestinrecentyears.Thisreportpresentsthedechlorinationof2,4-dichlorophenol(2,4-DCP)byPd-Febimetallicnanoparticlesinthepresenceofhumicacid(HA)toinvestigatethefeasibilityofusingPd-Fefortheinsituremediationofcontaminatedgroundwater.OurexperimentalresultsindicatedthatHAhadanadverseeffectonthedechlorinationof2,4-DCPbyPd-Fenanoparticles.Therateconstantkvaluesof2,4-DCPdechlorinationwere0.017,0.013,0.009,0.006and0.004min?1forHAconcentrationsof0,5,10,15and20mg/L,respectively.TherelationshipbetweenHAdosageandkvaluescanbedescribedasalinearmodel.
简介:ThepresolarSiCgrains[1]carrytheoriginalstellarnucleosynthesissignature.Theirisotopicanomaliescomparedtothesunarethestrongconstrainsinthesupernovae(SN)modelcalculations.The15N-excessinsomeSiC-ABgrains(12C/13C<10and14N/15N<272)isoneofthechallengesofcore-collapsesupernovae(CCSNe)models[2].Recently,PignataripointedoutthattheentrainmentofH-richmaterialintotheHeshellbeforetheSNexplosionallowsthecoproductionof13C,15Nand26Al,whichprovidesanewproductionscenarioforSiC-ABgrains[2].IntheHeshellnucleosynthesis,the13Cisproducedthrough12C(p,γ)13N(β+γ)13Creaction.The14Nissynthesizedthrough13N(n,γ)and13C(p,γ)reactions.
简介:WedemonstrateafacilerouteforthemassiveproductionofSnCb/carbonnanocompositeusedashigh-capacityanodematerialsofnextgenerationlithium-ionbatteries.ThenanocompositehadauniquestructureofultrafineSnO2nanocrystals(5nm,80wt%)homogeneouslydispersedinamorphouscarbonmatrix.ThisstructuredesigncanwellaccommodatethevolumechangeofLi+insertion/desertioninSnO2,andpreventtheaggregationofthenanosizedactivematerialsduringcycling,leadingtosuperiorcycleperformancewithstablereversiblecapacityof400mAh/gatahighcurrentrateof3.3A/g.
简介:Two-dimensional(2D)periodicalAuandindiumtinoxide(ITO)nanocompositearrayshavebeenfabricatedbasedonaself-assemblednanospherelithographytechnique.Abutton-shapedAunanoparticlewasformedoneachhollowhemisphere-shapedITOshell.Importantly,theunderlyingformationmechanismduringthethermaltreatmenthasbeenthoroughlyexploredbycomparingstructuresresultingfromdifferentdepositionconditionsindetail.ComparedtotheAunanoparticlearrayswithoutITOshells,theAu/ITOnanocompositearraysshowedastrongerlocalizedsurfaceplasmonresonanceeffectandhigherabsorptioninthenear-infrared(NIR)region,benefitingfromthefree-electroninteractionenhancementbetweenAuandITO.Thenonlinearopticalpropertieswereinvestigatedusingamodifiedfemtosecondintensity-scansystem,andtheresultsdemonstratedAu/ITOnanocompositearrayswitharemarkabletwo-photonabsorptionsaturationeffectforfemtosecondpulsesat1030nm.TheversatileNIRopticalresponsesindicatethegreatpotentialoftheelaboratelyprepared2DperiodicalAu/ITOnanocompositearraysinmanyapplicationssuchassolarcells,photocatalysis,andnovelnanooptoelectronicdevices.
简介:PlanarringresonatorwaveguidesarefabricatedinthinfilmsofAs2S3chalcogenideglass,depositedonsilicaon-siliconsubstrates.WaveguidecoresaredirectlywrittenbyscanningthefocusedilluminationofafemtosecondTi:sapphirelaseratacentralwavelengthof810nm,throughatwo-photonphoto-darkeningprocess.Alargephotoinducedindexchangeof0.3–0.4refractiveindexunitsisobtained.Theradiusoftheringresonatoris1.9mm,correspondingtoatransmissionfreespectralrangeof9.1GHz.Ahighloaded(intrinsic)Qvalueof110,000(180,000)isachieved.Thethermaldependenceoftheresonatortransferfunctionischaracterized.Theresultsprovidethefirstreport,tothebestofourknowledge,ofdirectlywrittenhigh-Qringresonatorsinchalcogenideglassfilms,anddemonstratethepotentialofthissimpletechniquetowardsthefabricationofplanarlightguidecircuitsinthesematerials.