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简介:Recentlytheproject'Developmentofpackagetechnologyforregenerationofstyrenethroughextractivedistillationofpyrolysisgasoline(STED)'undertakenjointlybytheSINOPECResearchInstituteofPetroleumProcessing(RIPP)andotherinstitutionshaspassedtheappraisalheldinBeijing.Theexpertgroupattendingtheappraisal
简介:Thisarticleanalyzedtheproblemsarisingfromretrofittingthe800kt/avirgindieselhydrofiningunitintoa1.0Mt/aOCT-MgasolineHDSunitattherefineryofLuoyangPetrochemicalCompany,andtheoptimizedmeasuresaimedatimprovementsinoperationofHDSunit.ThepreliminarycalibrationresultshaveindicatedthehighdesulfurizationrateandgoodselectivityoftheHDStechnologytofulfillthedemandofLuoyangPetrochemicalCompanyforproductqualityupgradingwiththetargetsoftechnicalrevampfullyimplemented.
简介:OnJuly7,2014theprojectcoveringtheenlarged-scalepilottestandcommercialsidelinetestoftheMTPcatalystandPDPofthe1.8Mt/aSMTPpackagedtechnology,jointlyundertakenbytheSINOPEC’sShanghaiPetrochemicalResearchInstituteanditscooperativeinstitutions,hadpassedtherevieworganizedbytheSINOPEC
简介:Aninnovativeideawasproposedtopreparetheoverbasednano-sizedcalciumcarbonate-calciumpetroleumsulfonatein-situtheHIGEEreactor.ThetestsamplepreparedbythistechnologycouldmeettherequirementoftheindustrystandardSH0042-91forthefirst-gradeproductonaparwithsimilaroverseasproduct.Thetestresultsobtaineduponobservationundermicroscopeafterfreezingetchingofspecimenrevealedthatthecrystalsizeofcolloidalcalciumsulfonatewasintherangeof10-30nmwithanaveragesizeof20nm.Thesizeofthedetergentadditivewasuniformwithgoodtransmittanceandfluidity.TheHIGEEtechnologypossessesfivespecificfeaturesasshownbelow:Firstly,thecarbonationreactioniscompletedinonestepwiththereactiontimereducedbymorethan50%ascomparedtotraditionalbatchreactorprocessalongwithenhancedreactionefficiency,goodoperabilityoftheprocessandstabilizedproductquality.Secondly,ammoniaemittedfromthereactionisusedastheco-promoterwithouttheneedforaddingammoniaandwateraspromoterstosimplifythepromotersystemalongwitheffectiveandstrongcouplingofreactions.Thirdly,theutilizationrateofCa(OH)2andCO2isincreasedby15%and30%,respectively,withproductyieldincreasedby15%,andcalciumresiduedecreasedby65%.Fourthly,theHIGEEtechnologyisenvironmentalbenignbecauseofgasolineisusedinthistechnologyinsteadoftoxictolueneandxylene.Fifthly,thedimensionofHIGEEreactorisreducedbyabovetwo-thirds.ThesuccessindevelopmentofthisnewtechnologywilloffernewideasandtechnologyplatformforthesynthesisofmetaldetergentadditivetolubricatingoilsinChina.
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简介:Amorphousnickelbasedalloycatalysts(denotedastheSRNAseriescatalysts)werepreparedviarapidquenchingmethodfollowedbyalkalileachingandotheractivationprocedures.Thephysicochemicalcharacterizationsshowthatnickel,theactivecomponentinthesecatalysts,existsintheamorphousstate,andthecatalystparticlespossessmanynanosizedvoidsleadingtolargesurfacearea(thehighestis145m2/g).TheevaluationresultsinsomemodelreactionsshowthattheSRNAseriescatalystshave2to4timeshigheractivityandselectivitythanconventionalRaneyNicatalystforthehydrogenationofcompoundswithunsatur-atedfunctionalgroups.Atpresent,theSRNAseriescatalystshavebeensuccessfullyusedinhydrogenationofglucose,hydrogenationofpharmaceuticalintermediatesandpurificationofcaprolactam.Inordertousethesecatalystsefficiently,amagneticallystabilizedbed(MSB)technologyhasbeendevelopedbycombiningtheferromagneticpropertyofthecatalystwiththegoodmasstransfercharacteristicsofMSB.ThedemonstrationunitofMSBhydrogenationtechnologyhasbeensetupandhaskeptrunningfor2800hours.Theresultsshowthat,afterrunning2800hours,thecatalyststillretainedgoodactivity;meanwhile,thehydrogenationeffi-ciencyhadbeenimproved10timesincomparisonwiththetraditionalCSTRprocess.
简介:The60kt/astyreneunitatSINOPECQiluBranchCompanywasputonstreamin1988,withethylbenzeneandstyrenemanufacturedrespectivelythroughhigh-temperaturealkylation(theAlCl3method)andadiabaticdehydrogenationunderreducedpressurethatwerejointlydevelopedbyMonsanto/Lummus.AlCl3methodcancausecorrosionandenvironmentalproblems,whichwouldaffectnormaloperationoftheunittoposeadefinitesafetyhazard.