简介:采用化学平衡模拟软件GEMS预测了锌湿法冶金过程中涉及的锌在Zn(Ⅱ)-NH3-H2O和Zn(Ⅱ)-NH3-Cl--H2O体系中的溶解度,并构建了其含锌物种分布图和优势区图。采用平衡实验方法测定了相同条件下锌的溶解度,其结果与预测结果相吻合。含锌物种的分布图和优势区图表明,在弱碱性条件下,2个体系均为以锌氨和羟基锌氨配合物为溶液的主要物种,其中Zn(NH3)24-为主要优势物种;在Zn(Ⅱ)-NH3-Cl--H2O体系中,锌氨氯三元配合物的形成能有效增大锌在中性条件下的溶解度,在该体系中存在Zn(OH)2、Zn(OH)1.6Cl0.4和Zn(NH3)2Cl23种固相,固相产物的形成取决于体系中总锌、总氨和总氯浓度。这些热力学平衡图表明了体系中各种物种之间的相互影响作用,并预测了总氨和总氯浓度的变化对锌溶解度的影响,为锌湿法冶金提供了热力学数据。
简介:分析了刻录机中HOLDER—GEL零件的注射成型原理、注射工艺和其相关的工艺参数,论述了HOLDER—GEL零件的生产工艺,论证HOLDER—GEL零件的注射成型技术,阐述了该零件质量检验的意义和方法。
简介:Anewenvironmentalfriendlycatalyst,H4SiW12O40/PAnwaspreparedandidentifiedbymeansofFT-IR,XRDandTG/DTA.Cyclohexanone1,2-propanediolketalwassynthesizedfromcyclohexanoneand1,2-propanediolinthepresenceofH4SiW12O40/PAn.Thefactorsinfluencingthesynthesiswerediscussedandthebestconditionswerefoundout.Theoptimumconditionsare:molarratioofcyclohexanoneto1,2-propanediolis1:1.4,thequantityofcatalystisequalto1.0%offeedstocks,andthereactiontimeis40min.H4SiW12O40/PAnisanexcellentcatalystforsynthesizingcyclohexanone1,2-propanediolketalanditsyieldcanreachover96.5%.
简介:TheeffectofyttriaonthesolidreactionmechanismofaCaHPO4·2H2O+CaCO3systematdifferenttemperatureswasexperimentallystud-ied.Thesampleswithandwithoutyttriaweresubjectedtothermogravimetric/differentialscanningcalorimetrymeasurement.ThesampleswereheattreatedatthetemperaturescorrespondingtothepeaksontheDSCspectra,andtheresultedphasecompositionswereidentifiedbyX-raydiffraction.Thetransformationmechanismwasdeducedbycomparingthephasesobtainedatdifferenttemperatures.Theresultsshowthatthetransformationsatbelow1073Karenotaffectedbyyttria,butallthoseatabove1073Karecompletelyaltered.Theformationtem-peratureofhydroxyapatitedecreasesby134K,andthedecompositiontemperatureincreasesby38K.ThepolymorphoustransformationofCa3(PO4)2fromβphasetoαphaseincreasesby47K.Thethermodynamicpropertiesofthetransformationsatabove1073Karealsomodi-fiedbytheadditionofyttria;thatis,theendothermalpeaksaresubstitutedbyexothermalpeaks.
简介:ThesusceptibilityofweldedjointfortheX65pipelinesteeltoH2Sstresscorrosioncracking(SCC)isinvestigated.SCCtestsonthesteelarecarriedoutintheenvironmentbasedonNACETM-01-77solutionwithsaturatedgaseousH2S.Thethresholdstressintensityfactorandcrackpropagationvelocityarecalculatedaccordingtowedge-openingloading(WOL)specimens.Thethree-dimensionalelastic-plasticfiniteelementanalysisofWOLspecimensisperformedbyusingtheFEMprogrammingpackageANSYS.Stressfieldandconcentrationofhydrogendistributionpropertyaheadofthecracktipareobtained.ThispapersurveyedthemicrostructureofweldedjointandstudiedonthemechanicalpropertiesofX65pipelinesteel.Itprovidesexperimentalbasisforstudyingstresscorrosion.Theresultsofnumericalanalysisareconsistentwithconclusionsofstresscorrosiontest.
简介:1IntroductionTherareearthcobaltalloyshavethepotentialformakingthemagneticandmagnetoopticalmaterials.Sofar,therareearthcobaltalloyfilmsaresubstantiallyproducedbysputteringorvacuumplating.Ifsuchfilmsarepreparedbyelectrodepositioninstead,productionefficiencywouldbeimprovedandthecompositionofthealloycouldbecontrolled.Becausetheoxidationreductionpotentialsofrareearthelementsareverynegative,organicsolventsmaybeusedaselectrolyticmedia.ElectrodepositionofGdCoandSmCoinorganicsolutionshasbeenreporte...
简介:TiO2nanoparticleswithdifferentphasesarepreparedbyhydrolysisoftitaniumtetrabutoxideinthepresenceofHCl.ThecompositionandmicrostructureoftheresultingsamplesarestudiedbyXRDandTEM.TheseresultsshowthattherangeofparticlesizeofTiO2isfrom20to30nm.ThemechanismofTiO2photocatalysisreactionhasbeendiscussedextensively.PhotocatalyticactivitiesofnanometerTiO2arealsoevaluatedbydegradationofthecrystalvioletsolution.ExperimentalresultsindicatethatthesynergisticactionofH2O2andultrasonicwavegreatlyenhancesphoto-catalyticreactionofTiO2.