简介:Toeffectivelysolvetheagglomerationproblemsinthesolidstatereactionprocess,pre-addingglucoseisadoptedtothesynthesisofLiFePO4/CenergymaterialsusingFe–Pwasteslag.Theaverageparticle&grainsizeofLiFePO4/Cdecreases,andtheimpuritiesinLiFePO4/Ccompositesreducetoagreatextent.Itmakesgreatsensetothemassindustrialproduction.Theoptimumsynthesisconditionsdeterminedinthisworkarebasedontheorthogonalexperiments.Thesamplessynthesizedinascaleof500gexhibithighpurity,excellentelectrochemicalperformance,highreactionactivity,goodreversibility,andlowpolarizationlevel.Thedischargecapacitiesare145,134,117,and102mAh/gatthecurrentdensitiesof0.1C,0.2C,0.5Cand1C,respectively.ThisworkputsforwardapracticalsuggestionformassproducingenvironmentalbenignandlowcostLiFePO4/Cascathodematerialsoflithiumionbatteries.
简介:基于4阶Runge-Kutta法,介绍了“强光一号”加速器长脉冲状态的电路模型。该模型不仅考虑了电爆炸丝导体断路开关(electronexplosiveopeningswitch,EEOS)金属丝的电阻率随比作用量变化的特性,而且考虑了油间隙和真空二极管间隙击穿过程中等效阻抗的变化特性。仿真结果表明,该模型能够更好地反映EEOS的初始参数对放电回路电流和电压的影响规律,能够为加速器的运行和性能提升提供有力的技术参考。通过仿真计算和理论分析,认为“强光一号”加速器的初级储能系统——直线型变压器(lineartransformerdriver,LTD)经过升级改造后,EEOS的工作电压能够提升大约20%,且获得了EEOS最佳工作状态的参数。
简介:Inthispaper,normalincidenceverticalp-i-nphotodetectorsonagermanium-on-insulator(GOI)platformweredemonstrated.Theverticalp-i-nstructurewasrealizedbyion-implantingboronandarsenicatthebottomandtopoftheGelayer,respectively,duringtheGOIfabrication.Abruptdopingprofileswereverifiedinthetransferredhigh-qualityGelayer.Thephotodetectorsexhibitadarkcurrentdensityof~47mA∕cm~2at-1Vandanopticalresponsivityof0.39A/Wat1550nm,whichareimprovedcomparedwithstate-of-the-artdemonstratedGOIphotodetectors.Aninternalquantumefficiencyof~97%indicatesexcellentcarriercollectionefficiencyofthedevice.Thephotodetectorswithmesadiameterof60μmexhibita3dBbandwidthof~1GHz,whichagreeswellwiththeoreticalcalculations.Thebandwidthisexpectedtoimproveto~32GHzwithmesadiameterof10μm.ThisworkcouldbesimilarlyextendedtoGOIplatformswithotherintermediatelayersandpotentiallyenrichthefunctionaldiversityofGOIfornear-infraredsensingandcommunicationintegratedwithGeCMOSandmid-infraredphotonics.
简介:Theoreticalmodelsofstellarevolutionpredictnegligiblequantitiesof6Li,9Be,and11Binthehydrogenburningphasesofastar’sevolution[1].TheprimordialBig-Bangnucleosynthesis(BBN)modelmightbemoregenerousinitsproductionoftheseelements[2].Theradiative-capturecrosssectionforprotoncaptureon11Bleadingto12CissmallatastrophysicallyinterestingenergiesbecauseofthelargeCoulombbarrier.
简介:TheeffectsofSO2,SO3ondenovosynthesisofpolychlorinateddibenzo-p-dioxins(PCDDs)anddibenzofurans(PCDFs)werestudiedusingmodelflyashesincorporatingcopperoxideandactivatedcarbon.ItwasfoundthattheinhibitiveeffectofSO2onPCDD/FsformationissimilartothatofSO3.Toinvestigatetheinhibitionmechanism,CuSO4formationsfrombothCuOandCuCl2wereexamined.TheabilityofSO3toconvertCuCl2andCuOonasilicasupportintosulfateismuchstrongerthanthatofSO2.However,replacingsilicabyactivatedcarbonleadstoamuchhighconversionofCuCl2toCuSO4inthepresenceofSO2.ThepromotionbyactivatedcarbonisexplainedbythereductionofCuCl2toCu2Cl2andtheeventualconversionofCu2Cl2intoCuSO4isthemaininhibitionmechanismofSO2ondenovosynthesisofPCDD/Fs.
简介:WereportonN-dopedp-typeZnOfilmswiththec-axisparalleltothesubstrate.ZnOfilmswerepreparedonana-Al2O3(0001)substratebysolid-sourcechemicalvapourdeposition(CVD),Zn(CH3COO)2.2H2OwasusedastheprecursorandCH3COONH4asthenitrogensource.Thegrowthtemperaturewasvariedfrom300℃to600℃,theas-grownZnOfilmdepositedat500℃showedp-typeconductionwithitsresistivityof42Ωcm,carrierdensity3.7×10^17cm^-3andHallmobility1.26cm^2V^-1.s^-1atroomtemperature,whicharethebestpropertiesforp-typeZnOdepositedbyCVD.Thep-typeZnOfilmpossessesatransmittanceofabout85%inthevisibleregionandabandgapof3.21eVatroomtemperature.
简介:AnovelSr2CuInO3Soxysulfidep-typesemiconductorphotocatalysthasbeenpreparedbysolidstatereactionmethodanditexhibitsintriguingvisiblelightabsorptionpropertieswithabandgapof2.3eV.Thep-typesemiconductorcharacterofthesynthesizedSr2CuInO3SwasconfirmedbyHallefficientmeasurementandMott-Schottkyplotanalysis.First-principlesdensityfunctionaltheorycalculations(DFT)andelectrochemicalmeasurementswereperformedtoelucidatetheelectronicstructureandtheenergybandlocations.Itwasfoundthattheas-synthesizedSr2CuInO3Sphotocatalysthasappreciateconductionandvalencebandpositionsforhydrogenandoxygenevolution,respectively.Photocatalytichydrogenproductionexperimentsunderavisiblelightirradiation(λ>420nm)werecarriedoutbyloadingdifferentmetalandmetal-likecocatalystsonSr2CuInO3SandRhwasfoundtobethebestoneamongthetestedones.
简介:ThecompressionbehaviourofPd39Ni10Cu30P21bulkmetallicglassisivestigatedatroomtemperatureupto23.5GPausinginsituhighpressureenergydispersivex-raydiffractionwithasynchrotronradiationsource.Pressureinducedstrucuralrelaxationofthebulkmetallicglassisexhibitedwithinthepressurerange.Itisfoundthatbelowabout5GPa,theexistenceofexcessfreevolumecontributestorapidstructuralrelaxation,whichgivesrisetorapidvolumeticchange.Underhigherpressure,furtherrelaxationresultsinstructuralstiffness.