简介:TheuseofX-raymicrotomographic(XMT)methodsinanalysingparticulatesystemshasexpandedrapidlyinrecentyearswiththeavailabilityofaffordabledesk-topapparatus.ThisreviewpresentsasummaryofthemajorapplicationsinwhichcomputersimulationsareexplicitlycoupledwithXMTintheareaofgranularandporousmaterials.Weenvisagetwomainwaysofestablishingthecouplingbetweenbothtechniques,basedonthetransferenceorexchangeofinformationbyusingphysicalorgeometricalparameters(i.e.aparametriclinkthroughfittingtoaprocessmodel)orthroughthedirectuseof3DXMTdigitalimages(i.e.comparingimagepixelsandfeaturesdirectly).Examplesofcoupledapplicationsareshownforthestudyoftransportpropertiesofrocks,particlepacking,mechanicalloadingandsintering.Often,thelinkbetweenXMTandcomputersimulationsisbasedonvisualcomparisonsandweconcludethattheuseofquantitativeparameterssuchasthenumberofinterparticlecontacts,forcenetworksorgranuleshapetolinkbothtechniquesisstillunderrepresentedintheliterature.Strategiestoprovideamorerobustandquantitativeapproachtooptimisetheinformationobtainedfromsuchtomographyanalysesareproposed.
简介:分析了X射线辐照电缆的物理过程,建立了基于有限元方法的二维诺顿等效电流源计算模型,将泊松方程、电场强度、电荷守恒方程等求解过程转换为矩阵和向量运算,并利用PETSc程序包编程计算,模拟了辐射感应电导率和间隙效应对屏蔽电缆X射线辐照响应的影响。结果显示,仅考虑辐射感应电导率效应时,随着X射线注量的增加,诺顿等效电流源逐渐趋于饱和,波形宽度变窄,并逐渐变为双极性波形。仅考虑间隙效应时,诺顿等效电流源幅度与间隙宽度近似成正比;间隙效应会大幅抵消辐射感应电导率效应的影响,诺顿等效电流源幅度仍近似正比于间隙宽度。该方法实现了电缆X射线辐照非线性效应的模拟,并将计算对象扩展到屏蔽多导体电缆。
简介:TheadsorptionofCOonPtgroupmetals,asamostfundamentalelementaryreactionstep,hasbeenwidelystudiedincatalysisandelectrocatalysis.Particularly,thestructuresofCOonPt(111)havebeenextensivelyinvestigated,owingtoitsimportancetobothfundamentalandappliedcatalysis.Yet,muchlessisknownregardingCOadsorptiononaPt(111)surfacemodulatedbysupportedoxidenanostructures,whichisofmorerelevancetotechnicalcatalysis.Wethusinvestigatedthecoverage-dependentadsorptionofCOonaPt(111)surfacepartiallycoveredbyFeOxnanostructures,whichhasbeendemonstratedasaremarkablecatalystforlow-temperatureCOoxidation.Wefoundthat,duetoitsstrongchemisorption,thecoverage-dependentstructureofCOonbarePtisnotinfluencedbythepresenceofFeOx.But,oxygen-terminatedFeOxnanostructurescouldmodulatethediffusivityofCOattheirvicinity,andthusaffecttheformationoforderedCOsuperstructuresatlowtemperatures.Usingscanningtunnelingmicroscopy(STM),weinspectedthediffusivityofCO,followedthephasetransitionsofCOdomains,andresolvedthemoleculardetailsofthecoverage-dependentCOstructures.OurresultsprovideafullpictureforCOadsorptiononaPt(111)surfacemodulatedbyoxidenanostructuresandshedlightsontheinter-adsorbateinteractiononmetalsurfaces.
简介:ThroughacomparisonbetweentheexpressionsofmasterbalancelawsandtheconservationlawsderivedbyNoether'stheorem,aunifiedmasterbalancelawandsixphysicallypossiblebalanceequationsformicropolarcontinuummechanicsarenaturallydeduced.Amongthem,byextendingthewell-knownconventionalconceptofenergymomentumtensor,therathergeneralconservationlawsandbalanceequationsnamedafterenergy-momentum,energy-angularmomentumandenergy-energyareobtained.Itisclearthattheformsofthephysicalfieldquantitiesinthemasterbalancelawforthelastthreecasescouldnotbeassumeddirectlybyperceivingthroughtheintuition.Finally,someexistingresultsarereducedimmediatelyasspecialcases.
简介:Wehaveshownthat,incontrasttotheresultsintheliterature,theBraggpeakintensityofNi80Fe20/Cusuperlatticesisenhancedattheincidentx-rayenergyslightlyhigherthantheabsorptionedgeoftheheavierelement(Cu).TheatomicdensityatNi80Fe20/Cuinterfacewasanalysedbythediffractionanomalousfinestructuretechnologywiththeincidentangleofx-rayfixedatthefirstBraggpeak.OurresultsdemonstratetheepitaxygrowthofNi80Fe20/Cusuperlattices.Uponannealing,theepitaxityofNi80Fe20/Cumultilayersbecomespoorbutthelocalcrystallinityineachlayerisimproved.
简介:Veryrecently,theBelleandBESIIIexperimentsobservedanewcharmonium-likestateX(3823),whichisagoodcandidatefortheD-wavecharmonium(13D2).BecausetheX(3823)isjustneartheDˉDthreshold,thedecayX(3823)!J=+??canbeagoldenchanneltotestthesignificanceofcoupled-channeleffects.Inthiswork[1],thisdecayisconsideredincludingboththehidden-charmdipionandtheusualquantumchromodynamicsmultipoleexpansion(QCDME)contributions.
简介:X射线成像技术在医疗诊断和无损检测等领域有着广泛的应用。对于软组织等弱吸收物体,传统的吸收成像无法获得高对比度的图像。为了解决这个问题,产生了X射线相位衬度成像技术。本文介绍类同轴全息测量下的X射线相位衬度层析成像技术,重点讨论该成像技术的Bronnikov模型和基于Helmholtz方程的模型,及相应的重建方法。
简介:通过建立一个典型的金/硅界面结构模型,对X射线入射界面时的剂量增强效应进行了研究。采用MonteCarlo方法计算了不同能量X射线入射金/硅界面的输运过程。其中,对X射线产生的次级电子在介质中的输运,采用了单次碰撞直接模拟方法;对电子的弹性散射截面和非弹性散射截面,分别采用Mott微分截面和Born近似下的广义振子强度模型计算得到。研究计算了不同能量X射线入射下,金/硅界面的剂量增强系数及特定X射线能量下剂量增强系数随金厚度的变化规律。结果表明:X射线能量为几十至几百keV时,剂量增强效应最明显,最大剂量增强系数对应的X射线能量随距金/硅界面的距离增加而增加;金的厚度影响界面附近剂量增强效果,当X射线能量不变时,剂量增强系数随金的厚度增加而增加,并趋于饱和值。
简介:Inthispaper,analmostP-stabletwo-stepsixth-orderHybridmethodwithphase-lagoforderinfinityandaclassexpliciteighth-orderObreckoffmethodswithphase-lagoforder10-24aredevelopedforthenumericalintegrationofthespecialsecond-orderperiodicinitial-valueproblems.Thesemethodshavetheadvantageofhigheralgebraicorderandconsiderablysmallerphase-tagcomparedwithsomemethodsin[1-6].Numericalexamplesindicatethatthesenewmethodsaremoreaccuratethanmethodsdevelopedby[1-6].
简介:Thetransitionsandmorphologyofaseriesofmain-chainliquidcrystallinepolymerwithX-shapedmesogenswerestudiedbymeansofDSC,SALSandpolarizingmicroscopytechniques.Aneven-oddeffectwasobservedforsampleswithdifferentsizeofthesubstituentsonthemesogenends.Theisotropizationprocesswassimilartothatofmain-chainpolymerswithrod-likemesogens.Nocrystallizationwasdetectedforspecimenscoolingdownfromtheirisotropicmeltstate.Howevertwoofthesamplesmaycrystallizeincoolingprocessdirectlyfromtheliquidcrystallinestate.
简介:Tungstenisregardedasanimportantcandidateofplasmafacingmaterialininternationalthermonuclearexperimentalreactor(ITER),sothedeterminationandmodelingofspectraoftungstenplasma,especiallythespectraathightemperaturewereintenselyfocusedonrecently.Inthiswork,usingtheatomicstructurecodeofCowan,acollisionalradiativemodel(CRM)basedonthespin-orbit-split-arraysisdeveloped.Basedonthismodel,thechargestatedistributionoftungstenionsisdeterminedandthesoftX-rayspectrafromhighchargedionsoftungstenatdifferenttemperaturesarecalculated.Theresultsshowthatboththeaverageionizationchargeandlinepositionsarewellagreedwithotherscalculationsandmeasurementswithdiscrepanciesoflessthan0.63%and1.26%,respectively.Thespectraathighertemperaturesarealsoreportedandtherelationshipbetweenionabundanceandtemperatureispredictedinthiswork.
简介:LetL~2([0,1],x)bethespaceoftherealvalued,measurable,squaresummablefunctionson[0,1]withweightx,andlet■_nbethesubspaceofL~2([0,1],x)definedbyalinearcombinationofJ_0(μ_kx),whereJ_0istheBesselfunctionoforder0and{μ_k}isthestrictlyincreasingsequenceofallpositivezerosofJ_0.Forf∈L~2([0,1],x),letE(f,■_n)betheerrorofthebestL~2([0,1],x),i.e.,approximationoffbyelementsof■_n.Theshiftoperatoroffatpointx∈[0,1]withstept∈[0,1]isdefinedbyT(t)f(x)=(1/π)∫_0~πf((x~2+t~2-2xtcosθ)~(1/2))dθ.Thedifferences(1-T(t))~(r/2)f=∑_(j=0)~∞(-1)~j(_j~(r/2))T~j(t)foforderr∈(0,∞)andtheL~2([0,1],x)-modulusofcontinuityω_r(f,τ)=sup{||(I-T(t))~(r/2)f||:0≤t≤τ}oforderraredefinedinthestandardway,whereT~0(t)=Iistheidentityoperator.Inthispaper,weestablishthesharpJacksoninequalitybetweenE(f,■_n)andω_r(f,τ)forsomecasesofrandτ.Moreprecisely,wewillfindthesmallestconstant■_n(τ,r)whichdependsonlyonn,r,andτ,suchthattheinequalityE(f,■_n)≤■_n(τ,r)ω_r(f,τ)isvalid.