简介:ThepolycrystallinephaseWO3/g-C3N4wassynthesizedunderstirringusingtungstenicacid(H2WO4)andgraphiticcarbonnitride(g-C3N4)asrawmaterials.ThecatalystwascharacterizedbyX-raydiffraction(XRD),scanningelectronmicroscopy(SEM),energydispersivespectroscopy(EDS),theFouriertransforminfraredspectroscopy(FT-IR),andtheBrunauer-Emmett-Telleranalysis(BET).ThepolycrystallinephaseWO3/g-C3N4wasdeterminedbyXRDtechnique.TheoxidativedesulfurizationprocesswasinvestigatedusingWO3/g-C3N4asthecatalyst,30%hydrogenperoxide(H202)astheoxidant,and1-butyl-3-methylimidazoliumtetrafluoroborate([bmim]BF4)ionicliquids(ILs)astheextractant.Theoperatingconditions,includingH2WO4amount,ILdose,H2O2volume,temperature,catalystdosage,andtypesofsulfurcompounds,weresystematicallyresearched.Thedesulfurizationratecouldreach98.46%forremovingdibenzothiophene(DBT)fromthemodeloilunderoptimalreactionconditions.Inaddition,thecatalyticactivitywasslightlydecreasedafterfiverecyclesofcatalysts.Thereactionkineticsanalysisshowsthattheoxidativedesulfurizationsystemwasinaccordwiththefirst-orderreactionkineticsequation.Themechanismofoxidativedesulfurizationwasproposed.
简介:摘要:我公司设计研发的 TPZ80/2500型节段拼装造桥机可同时架设铁路 64m简支箱梁及 80m跨连续箱梁,并成功应用于京唐铁路潮白河特大桥 2联( 48+80+48) m连续梁胶接拼装施工。本文主要阐述了造桥机总体构造设计理念及优势,采用 MIDAS/Civil软件进行造桥机整体结构计算,对关键部位进行手算,保证造桥机各项设计均满足规范要求并达到安全使用的目的。该造桥机适应能力强,自动化程度高,操作简便,工效高,安全可靠。该造桥机的设计理念及计算过程,对同类设计具有借鉴意义。
简介:摘要CO2灭火系统是燃机安全运行的重要保护系统,系统复杂,本文对燃机CO2灭火系统的配置和特点进行了分析和总结,同时也介绍了CO2灭火系统运行中应注意的问题。
简介:A60%Fe/Al2O3catalystwaspreparedbytheco-precipitationmethod.ItwasreducedbyH2toproducemetallicFe,whichwasthensulfidedbyCS2toFe0.96SandFe3S4orphosphidedbytriphenylphosphine(PPh3)inliquidphasestoFe2PandFeP.Itwasfoundthattheironsulfides(Fe0.96SandFe3S4)exhibitedthelowactivityforthehydrodesulfurization(HDS)reactions.TheHDSactivitywasalsolowontheFe(metal)/Al2O3andFe2P/Al2O3catalystssincetheywereconvertedintoFe0.96SandFe3S4duringtheHDSreactions.Incontrast,theFeP/Al2O3wasfoundtobestableandactivefortheHDSreactions.Inparticular,FeP/Al2O3possessedsignificantlysmallerFePparticlesthanFeP/C,leadingtothesignificanthigherHDSactivityofFeP/Al2O3thanFeP/C.