学科分类
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12 个结果
  • 简介:ThechemicalcompositionandmicrostructureofTibetanmicrocrystallinemagnesitewerestudiedbymeansofXRF,XRDandFESEM.Itisfoundthatthemicrocrystallinemagnesitehasuniformlydistributedgrains,mostlyintherangeof2-4μm,andtheMgOcontentis47.80%.Infusedmagnesia,thedrusesarecolorlesstransparentpericlasemegacrystswithoutimpurity,whilethecrustsandiswhite,withahighMgOcontentupto97%-99%.Thepericlasecrystalsarebig,appearingasfacedandstep-growthmorphology.Massivesecondarylongcolumnarpericlaseiscrystallized.

  • 标签: 结晶行为 电熔镁砂 X射线荧光光谱法 MGO含量 高纯 方镁石
  • 简介:ThechromiumoxidematerialswerepreparedusingCr2O3micropowderasmainstartingmaterial,TiO2micropowderassinteringaid,polyvinylalcoholasbinder,byaseriesofprocessessuchasslurrying,sprayinggranulation,machinemouldingandcoldisostaticpressing,andfiringat1500℃for3hinair(oxygenpartialpressurewas2.1×104Pa),industrialnitrogen(oxygenpartialpressurewas1×103Pa),purenitrogen(oxygenpartialpressurewas10Pa),highpuritynitrogen(oxygenpartialpressurewas0.1Pa),andcarboncakeembeddedatmosphere(oxygenpartialpressurewas2.3×10-12Pa).EffectsofoxygenpartialpressuresonthesinteringbehaviorofCr2O3materialswereinvestigated.Theresultsshowthat(1)for3wt%TiO2-dopedspecimens,thereisasubstantialdependenceofsinteringonoxygenpartialpressure(0.1Pa-2.1×104Pa),andthebulkdensityincreasesandapparentporositydecreaseswithoxygenpartialpressuredecreasing;(2)eveniftheoxygenpartialpressureis0.1Pa,thespecimenwithoutTiO2cannotreachdensificationsintering;(3)underverylowoxygenpartialpressureofcarbonembeddedatmosphere,Cr2O3materialscontainingTiO2ornotcanattaindensification.

  • 标签: 三氧化二铬 烧结行为 材料制备 大气 二氧化钛粉体 低氧分压
  • 简介:Rheologyofcastablesisgreatlyaffectedandcontrolledbyrheologicalbehavioroftheirmatrix.Inthiswork,therheologicalpropertiesofbauxite-basedcastablematrixhavebeenstudied.Theeffectsofsuper-finesilicaandaluminaaddition,water/cementratio,dispersantsandbauxiteparticle-sizeonviscosity,shearrateandshearstressoftheslurrieshavebeeninvestigated.Basedontheseresults,therangeofoptimumcompositionofthematrixwithgoodrheologicalbehaviorhasbeenobtained.

  • 标签: 流变行为 矩阵 矾土 浇注料 耐火材料
  • 简介:1IntroductionKyaniteisanimportantnaturallyoccurringindustrialmineralandisusedinthemanufactureofavarietyofindustrialceramicproducts;notableexamplesincluderefractoriesandporcelains.Itisahighpressurepolymorphofthealuminosilicatesofthenesosilicategroup,whichincludeskyanite,sillimanite,andandalusite.

  • 标签: 结构 性质 蓝晶石 性能 应用 耐火单块集成电路
  • 简介:Effectsofstartingmaterialsandfourdispersants(STP,SHP,FDNandFS60)onZetapotentialandrheologicalbehaviorofaluminabasedULCcastablesmatrixwereinvestigated.Theresultsshowthat:characteristicsofsilicafumeandaluminacementsplayaveryimportantroleinZetapotentialandviscosityofsuspensionsofthecastablesmatrix;thedispersantsSTPandSHPcanchangeZetapotentialvaluesofthematrixsuspensionsremarkably;thefourdispersantscaneffectivelyimprovetherheologicalpropertiesofmatrixsuspensions.Forthepointoflowerviscosityofthematrixsuspensions,thesuitableadditionsofthethreedispersants(SHP,FDNandFS60)areabout0.2%whilethatofSTPisabout0.3%.

  • 标签: Ζ电位 粘性 分散剂 流变学
  • 简介:Aluminamagnesiacastablecruciblespecimenswerepreparedusingtabularcorundum(≤5mm),fusedmagnesiapowder(≤0.088mm),fusedspinelpowder(≤0.044mm),andα-Al2O3micropowder(d50≤0.7μm)asmainstartingmaterials,batching,mixing,shaping,anddrying.Slagresistancewasdeterminedbystaticcruciblemethodat1600℃for3hadoptingtwoladleslagswithdifferentbasicities(3.40and1.03).Thecorrosionandpenetrationindexesandmicrostructurecharacteristicsofthespecimensafterslagresistancetestwereanalyzedtostudythecorrosionbehaviorsofthetwoslagstoaluminamagnesiacastables.Theresultsshowthatthecorrosionofthelowbasicityslagtoaluminamagnesiacastablesismuchmoreseriousthanthatofthehighbasicityslagforthattheirreactionswithcastablesformdifferentproducts;forthelowbasicityslag,themulti-phasecoexistenceofCA6andcompoundsofCaO-Al2O3-SiO2inthematerialstogetherwithvolumeexpansioncausedbytheformationofCA6intensifytheslagcorrosionandpenetration;forthehighbasicityslag,thereactionbetweenslagandcastablesgeneratesaCA2denselayerandalargeamountofin-situMAintheinterface,reducingtheslagcorrosiontothematerialseffectively.

  • 标签: 铝镁浇注料 腐蚀行为 AL2O3-SIO2 碱性渣 静态坩埚法 显微结构特征
  • 简介:Theinterrelationofvariousfactorsaffectingthemechanicalstrength,thethermalshockresistivityandcreepdeformationofslabinasimplesettingconditionofthefiringoftablewarearediscussed,Theconrolofparametersinfavourofthedesiredperformanceoftheslabispropsed.

  • 标签: 耐火材料 板坯 扁坯 抗热冲击 抗蠕变 窑具
  • 简介:HightemperatureoxidationbehavioroftwokindsofnitridebondedSiCbasedrefractorieswasinvestigatedat11001500℃bymeansofX-raydiffractometer,scanningelectronicmicroscopyandthermogravimetry.Theresultsshowthat:(1)withthetemperatureincreasing,theoxidationmassincrementrateofthespecimenincreasesfirstandthendecreases,andoxidationpassivationoccurs;(2)theoxidationresistanceofSiAlONbondedSiCrefractoriesissuperiortothatofSi3N4bondedSiCrefractories;(3)hightemperatureoxidationresultsintheincreaseofcompressivestrengthatroomtemperatureofSiCbasedrefractoriescomparedwithspecimenbeforeoxidation;thecompressivestrengthofSiAlONbondedSiCspecimensoxidizedathightemperaturesdecreaseswiththeincreaseofthetemperatureasaresultofformationandburstofsurfacebubble,whilethedecreaseofcompressivestrengthofSi3N4bondedSiCspecimensoxidizedathightemperaturesisowingtotheincreaseoftheconsistencyofnet-likecrackassociatedwithcristobalitetransformationduringcooling.

  • 标签: 碳化硅耐火材料 高温氧化行为 碳化硅基 氮化硅 扫描电子显微镜 抗压强度
  • 简介:Lowcement(LC)andultra-lowcement(ULC)bauxite-SiCcastablesareimportantandhighperformancemonolithicrefiactoriesandtheyhavebeenwidelyusediniron-makingandincineratorlinings.Inthiswork,rheo-logicalbehaviorofLCandULCbauxite-basedSiC-contain-ingcastableshasbeenstudied,includingtheeffectsofSiCcontentandcementcontentonrheologicalpropertiesofthecastables.TheresultsshowthatwithanincreaseofSiCandcementcontent,rheologicalpropertiesofthecastablesdeteriorate.Ontheotherhand,moderateamountsofSiC(4%~8%)andofcalciumaluminatecement(2%~4%)haveveryslightinfluenceonrheologicalproperties,(i.e.whenthecastablesareshearedtheirtorqueandyieldtorqueonlyslightlyincreasewiththeshearingspeed).Therheologicalcharacteristicsofthecastablesfol-lowBinghamfiuidandalwaysshowshearthinningbehav-ior.

  • 标签: 流变学 金刚砂 水泥 耐火材料
  • 简介:YB/T384-20111ScopeThisstandardspecifiestheclassification,technicalrequirements,testmethods,qualityappraisalprocedures,packing,marking,transportation,storage,andqualitycertificateofsilicarefractorymortars.Thisstandardisapplicabletosilicarefractorymortarsforliningsilicabricks.2NormativeReferencesThefollowingdocumentsareessentialtotheapplicationofthisstandard.Fordatedreferences,onlytheeditioncitedapplies.

  • 标签: 晶体形态 菱镁矿 热分解行为 微晶 表征 纯度
  • 简介:Zirconiagraphiterefractoryisusedasacore-nozzleinthethin-stripcastingofsteel.Post-mortemanalysisofusedrefractorywasperformedinanefforttoestablishthefailuremechanism.CorrosionbehaviorwasstudiedagainstmoltensteelwithMnO-SiO2basedliquidinclusions.CorrosionofthesematerialsinvolvesdissolutionandoxidationofgraphiteinthematrixfollowedbypenetrationofliquidslagleadingtodegradationofZrO2particles.Thermodynamicequilibriumcalculationswereperformedtostudythiscorrosionmechanism.

  • 标签: 石墨耐火材料 腐蚀行为 薄带连铸 氧化锆 钢水 失效机理
  • 简介:Al2O3-MgOcastableshavebeenwidelyusedforworkingliningsofsteelladleduetotheirsuperiorhotstrengthandcorrosionresistance.Inthiswork,effectsofmicrosilica,ultrafinealuminaandMgOfinesadditionsontherheologicalbehaviorofthecastableswereinvestigatedbymeansofIBBrheometerV1.0tomeasuretorque(shearstress)undervaryingshearrates.Theresultsshowthatrheologicalpropertiesofcastablesatvaryingshearratesaresignificantlyimprovedwithincreaseofmicrosilicaadditions(from1mass%to5mass%)andcorrespondingdecreaseinwateraddition;thereisonlylittlechangeinrheologicalbehaviorwithvariationofultrafinealuminaandMgOfinesadditions.Optimumultrafinealuminaandmicrosilicaadditionsarerecommendedforcastableswithgoodrheologicalbehavior.

  • 标签: 超细氧化铝 流变行为 浇注料 氧化镁 水泥 剪切速率