学科分类
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174 个结果
  • 简介:生物的膜为房间生活和水和是必要的。水为许多房间部件的集会和稳定性提供驱动力。这里,我们在phospholipid膜学习水的结构的性质。我们描绘本地结构,检查中间的范围顺序(国际难民组织)并且采用最近Martelli等建议的一个敏感本地顺序度量标准。与完美的冰的结构测量并且分级本地环境的重叠的度。近到膜,水获得一个高国际难民组织并且改变它的动态性质;即,它慢,在一个区域,那从膜在1nm上扩大的自由的翻译、旋转的度连接。令人惊讶地,我们证明在远及从接口的2:5nm的距离,尽管像体积的动力学被恢复,水的IRO在在一样的热力学的条件下面的体积仍然是比那稍微高级的。因此,水膜接口以比经常调用的1-nm长度规模进一步宣传的周围的条件有结构的效果。因而,当分析膜限制的水的试验性的数据时,这应该被考虑并且能帮助我们在生物系统理解水的角色。

  • 标签: 结构测量 动态性质 习水 水膜 生物系统 度量标准
  • 简介:Basedon3DBiot’sconsolidationtheoryandnonlinearDuncan-Chang’smodel,a3DFEM(finiteelementmethod)programisdevelopedconsideringthecouplingofgroundwaterseepageandsoilskeletondeformationduringexcavation.Thecomparisonbetweentheanalysisresultconsideringthevariationofwaterheaddifferenceandthatwithoutconsideringitshowsthattheporewaterpressuredistributionoftheformerisdistinctlydifferentfromthatofthelatterandthatthefoundationpitde-formationsoftheformerarelargerthanthoseofthelatter,sothattheresultwithoutconsideringthevariationofwaterheaddif-ferenceisunreliable.Thedistributionrulesofsoilhorizontalandverticaldisplacementsaroundthepitandexcessporewaterpressureareanalyzedindetailintimeandspace,whichisverysignificantforguidingundergroundengineeringconstructionandensuringenvironmentsafetyaroundthepit.

  • 标签: 环境作用 地基变形 孔隙压力 建筑工程
  • 简介:Bilayermembranesself-assembledfromamphiphilicmoleculessuchaslipids,surfactants,andblockcopolymersareubiquitousinbiologicalandphysiochemicalsystems.Theshapeandstructureofbilayermembranesdependcruciallyontheirmechanicalpropertiessuchassurfacetension,bendingmoduli,andlinetension.Understandinghowthemolecularpropertiesoftheamphiphilesdeterminethestructureandmechanicsoftheself-assembledbilayersrequiresamolecularlydetailedtheoreticalframework.Theself-consistentfieldtheoryprovidessuchatheoreticalframework,whichiscapableofaccuratelypredictingthemechanicalparametersofself-assembledbilayermembranes.Inthisminireviewwesummarizetheformulationoftheself-consistentfieldtheory,asexemplifiedbyamodelsystemcomposedofflexibleamphiphilicchainsdissolvedinhydrophilicpolymericsolvents,anditsapplicationtothestudyofself-assembledbilayermembranes.

  • 标签: 自洽场理论 自组装膜 应用程序 弯曲弹性模量 双亲分子 亲水性聚合物
  • 简介:Thegoalofthisstudywastodevelopanddesignacompositeprotonexchangemembrane(PEM)andmembraneelectrodeassembly(MEA)thataresuitableforthePEMbasedwaterelectrolysissystem.Inparticular,itfocusesonthedevelopmentofsulphonatedpolyetheretherketone(SPEEK)basedmembranesandcaesiumsaltofsilico-tungsticacid(CsSiWA)matrixcomparedwithoneofthetransitionmetaloxidessuchastitaniumdioxide(TiO_2),silicondioxide(SiO_2)andzirconiumdioxide(ZrO_2).TheresultantmembraneshavebeencharacterizedbyFouriertransforminfraredspectroscopy,scanningelectronmicroscopy,ionexchangecapacity(IEC),wateruptakeandatomicforcemicroscopy.ComparativestudiesontheperformanceofMEAswerealsoconductedutilizingimpregnation-reductionandconventionalbrushcoatingmethods.ThePEMelectrolysisperformanceofSPEEK-CsSiWA-ZrO_2compositemembranewasmoresuperiorthanthatofothermembranesinvolvedinthisstudy.Electrochemicalcharacterizationshowsthatamaximumcurrentdensityof1.4A/cm~2wasachievedat60°C,explainedbyanincreasedconcentrationofprotonicsitesavailableattheinterface.

  • 标签: 膜电极组件 大电流密度 水电解槽 电解系统 复合质子交换膜 傅里叶变换红外光谱
  • 简介:Westudyoptomechanicallyinducedtransparencyinaspinningmicroresonator.Wefindthatinthepresenceofrotation-inducedSagnacfrequencyshift,boththetransmissionrateandthegroupdelayofthesignalarestronglyaffected,leadingtoaFano-likespectrumoftransparency.Inparticular,tuningtherotaryspeedleadstotheemergenceofnonreciprocalopticalsidebands.Thisindicatesapromisingnewwaytocontrolhybridlight–sounddeviceswithspinningresonators.

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  • 简介:制备了以磷酸酯化聚乙烯醇为活性分离层的渗透汽化复合膜并用于乙醇-水混合物的分离。实验结果表明,在进料中乙醇浓度为20~95wt%的范围内,磷酸酯化聚乙烯醇复合膜对乙醇-水混合物中的水均具有很好的渗透选择性,而且,复合膜活性层酯化度对其分离性能具有显著的影响

  • 标签: 渗透汽化 磷酸酯化聚乙烯醇 复合膜
  • 简介:Laser-inducedbreakdownspectroscopy(LIBS)isananalyticaldetectiontechniquebasedonatomicemissionspectroscopytomeasuretheelementalcomposition.LIBShasbeenextensivelystudiedanddevelopedduetothenon-contact,fastresponse,highsensitivity,real-timeandmulti-elementalde-tectionfeatures.ThedevelopmentandapplicationsofLIBStechniqueinAsiaaresummarizedanddiscussedinthisreviewpaper.TheresearchersinAsiaworkondifferentaspectsoftheLIBSstudyinfundamentals,dataprocessingandmodeling,applicationsandinstrumentations.Accordingtothecurrentresearchstatus,thechallenges,opportunitiesandfurtherdevelopmentofLIBStechniqueinAsiaarealsoevaluatedtopromoteLIBSresearchanditsapplications.

  • 标签: LASER-INDUCED BREAKDOWN SPECTROSCOPY (LIBS) QUANTITATIVE analysis
  • 简介:Laser-induceddamageinfusedsilicaopticsgreatlyrestrictstheperformancesoflaserfacilities.Grayhazedamage,whichisalwaysinitiatedonceriapolishedoptics,isoneofthemostimportantdamagemorphologiesinfusedsilicaoptics.Inthispaper,thelaser-inducedgrayhazedamagesoffourfusedsilicasamplespolishedwithCeO_2,Al_2O_3,ZrO_2,andcolloidalsilicaslurriesareinvestigated.Foursamplesallpresentgrayhazedamageswithmuchdifferentdamagedensities.Then,thepolishing-inducedcontaminantandsubsurfacedamagesinfoursamplesareanalyzed.TheresultsrevealthatthegrayhazedamagescouldbeinitiatedonthesampleswithoutCecontaminantandareinclinedtoshowatightcorrelationwiththeshallowsubsurfacedamages.

  • 标签: 激光诱导损伤 熔融石英 灰色 抛光 光学 浅层
  • 简介:Inthispaper,blendmembranesfrompolyvinylacetate(PVAc)andblockcopolymerpoly(amide-12-b-ethyleneoxide)(Pebax1074)arepreparedbysolutioncastingandsolventevaporationmethod.Althoughtheyarehomogeneousonamacro-scale,theobservationsfromDSCandSEMindicatemicro-phaseseparationforPVAc/Pebax1074blendmembranes.WiththeincreaseofPebax1074content,gaspermeabilitiesofCO2,H2,N2andCH4allincreasegreatly.PVAc/Pebax1074blendmembraneswithhighPVAccontentareappropriateforCO2/CH4separation.Thetemperaturedependenceofgaspermeabilityisdividedintorubberyregionandglassyregion.Theactivationenergiesofpermeationinrubberyregionaresmallerthanthoseinglassyregion,andtheyalldecreasewithincreasingPebax1074content.ForN2,H2andCH4,theirgaspermeationpropertiesaremainlyinfluencedbythedual-modesorptionandhydrostaticpressureeffect.ButforCO2,itspermeabilityincreaseswiththeincreaseofpressureduetoCO2-inducedplasticizationeffect,whichismoreobviousforPVAc/Pebax1074blendmembraneswithhighPVAccontent.

  • 标签: polyvinyl acetate poly(amide-12-b-ethylene oxide) blend membrane
  • 简介:Novelhierarchicalporouscarbonmembraneswerefabricatedthroughasimplecarbonizationprocedureofwell-definedblendingpolymermembraneprecursorscontainingthesourceofcarbonpolyacrylonitrile(PAN)andanadditiveofpolyvinylpyrrolidone(PVP),whichwaspreparedusingphaseinversionmethod.Theas-fabricatedmaterialswerefurtherusedastheactiveelectrodematerialsforsupercapacitors.TheeffectsofPVPconcentrationinthecastingsolutiononstructurefeatureandelectrochemicalcapacitiveperformanceoftheas-preparedcarbonmembraneswerealsostudiedindetail.Astheelectrodematerialforsupercapacitor,ahighspecificcapacitanceof278.0F/gcouldbeattainedatacurrentof5mA/cm2andabout92.90%capacityretentioncouldbemaintainedafter2000charge/dischargecyclesin2mol/LKOHsolutionwithaPVPconcentrationof0.3wt%inthecastingsolution.Thefacilehierarchicalporestructurepreparationmethodandthegoodelectrochemicalcapacitiveperformancemakethepreparedcarbonmembraneparticularlypromisingforuseinsupercapacitor.

  • 标签: 电化学电容性能 聚乙烯吡咯烷酮 制备方法 聚丙烯腈 共混膜 炭膜
  • 简介:Itiswellknownthatvanadiumalloywillfacetostrongneutronirradiationandhydrogenenvironmentsasastructuralmaterialinafusionreactor.Someresearcheshavereportedthatvanadiumalloytookstronglyhardeningafteranexposuretohydrogenenvironmentandirradiationbyneutronatatemperaturelowerthan400℃.Theductilityofthealloywaslostlargely,evenentirelybrittlefractureoccurredsometimesintensionloadingofthealloy.Therefore,it'stogettheknowledgeofthehardeningmechanismandthefracturemechanicalforthepurposetoimprovetheperformancesofthealloyunderthecircumstances.

  • 标签: 钒合金 淬水 中子照射 熔化反应堆
  • 简介:我们由导致激光的故障光谱学(解放)的炸药的察觉上的最近的工作在这份报纸被考察。我们学习了器官的炸药的导致激光的血浆的物理机制,TNT。在单个光子的刺激下面的TNT的解放系列用MATLAB被模仿。碳,氢,氧,和氮对血浆温度的原子排放线紧张的变化也被模仿。我们也调查普通无机的爆炸、黑粉末的解决时间的解放系列,在二种包围气氛,表情和氩,并且发现黑色的O原子排放线SBR的最大的价值搽粉发生在596ns的门延期。我们的工作的另一个焦点在使用象原则部件分析(PCA)和部分最少的广场判别式分析(PLS-DA)那样的chemometic方法把器官的炸药与象塑料那样的器官的材料区分开来上。为分类的一个PLS-DA模型被造。TNT和塑料的七种类型被选择为样品测试模型。试验性的结果证明解放结合了chemometric技术有能力从塑料区别器官的炸药。

  • 标签: 激光诱导等离子体 无机炸药 光谱探测 击穿 MATLAB仿真 等离子体温度
  • 简介:WeproposeaschemetocoherentlycontrolspinsqueezingofatomicBose-Einsteincondensate(BEC)viathetechniqueofelectromagneticallyinducedtransparency(EIT).Westudyquantumdynamicsofthemeanspinvectorandspinsqueezing.ItisshownthatthemeanspinvectorandspinsqueezingoftheBECcanbecontrolledandmanipulatedbyadjustingtheexternalcouplingfieldsor/andinternalnonlinearinteractionsoftheBEC.Itisindicatedthatthespinsqueezingcanbegeneratedrapidlyinthedynamicalprocessandmaintainedinalongtimeinterval.ItisfoundthatalargereffectiveRabicouplingbetweenatomsandlaserscanproduceastrongerspinsqueezing,andthesqueezingcanmaintainalongertimeinterval.

  • 标签: Keywords spin SQUEEZING atomic Bose EINSTEIN
  • 简介:OurexperimentsshowthatexternalfocusingandinitiallaserenergystronglyinfluencesfilamentgeneratedbythefemtosecondTi–sapphirelaserinair.Theexperimentalmeasurementsshowthefilamentlengthcanbeextendedbothbyincreasingthelaserenergyandfocallengthoffocusinglens.Ontheotherhand,theplasmafluorescenceemissioncanbeenhancedbyincreasingthelaserenergywithfixedfocallengthordecreasingthefocallength.Inaddition,thecollapsedistancemeasuredexperimentallyarelargerthanthecalculatedonesowingtothegroup-velocity-dispersioneffect.Inaddition,wefindthatthelinewidthsofthespectrallinesfromN2isindependentoffilamentpositions,laserenergiesandexternalfocusing.

  • 标签: FEMTOSECOND LASER FILAMENT FLUORESCENCE