简介:血浆nitrocarburizing和血浆氧化处理被执行改进wear和SKD61钢的腐蚀抵抗。血浆nitrocarburizing在生产epsilon-Fe2_3的氮,氢和甲烷空气在540°C为12h被进行(N,C)血浆nitrocarburising生产的phase.The混合物层主要由电子阶段组成,与gamma'-Fe4的一个小比例(N,C)复合的层和扩散层的phase.The厚度是大约10亩m和大约200/^m,respectively.Plasma柱子氧化为1h.The在500°C的经常的温度与各种各样的氧/氢比率在nitrocarburized样品上被执行在在复合的层上的厚度的1-2亩m的很薄的磁铁矿(Fe3O4)层被获得。阳极极化测试表明那个血浆nitrocarburizing过程贡献了SKD61钢的腐蚀抵抗的重要改进。然而,nitrocarburized混合物层的腐蚀特征被氧化处理败坏。
简介:血浆合金Zr和血浆nitriding的一个双处理被用来改进Ti-6Al-4V的tribological性质。Zr-N的微观结构合成(alloyed)层在Ti-6Al-4V和它的坚硬上形成了,磨擦并且穿性质被使用OM,SEM,GDOES,版本,microhardness测试者以及ball-on-disk摩擦计调查。微结构分析的结果证明alloyed层紧缩、一致并且主要由ZrN,听0.3和AlN组成。很微小的粘合剂和细微氧化穿的A是主要为修改Ti-6Al-4V穿机制。tribological性质在双处理以后显著地被改进。防摩的好联合并且穿抵抗因为修改Ti-6Al-4V主要被归因于在表面上形成并且提高了传播Zr层支持的金属氮化物的更高的表面坚硬。
简介:Surface-graftedpoly(ethyleneglycol)(PEG)moleculesareknowntopreventproteinadsorptiontothesurface.NitinolsampleswerecoatedundertetraglymeECRcoldplasmaconditionstoenhanceitsbiocompatibility.ThemodifiedNitinolsurfaceswerecharacterizedbyhighresolutionESCAandcontactangle,itwasdemonstratedthatthedepositedPEG-likecoatingswerebuiltupmainlyof-CH2-CH2-O-linkagesinsurfaces.ThesurfacewettabilityofthemodifiedNitinolwasincreasedcomparedwiththecontrolsurface.HumanplasmaproteinwasadsorbedonNitinolevaluatedbySEM,theproteinadsorptiononmodifiedsurfacesdecreasedrapidly.Thus,thepotentialbenefitsofcoldplasmatechniquewillbeofusetothebiomedicalindustriesimprovingthebiocompatibilityofmetals.
简介:AnewtechniqueofthesynthesisofNanocrystallineDiamond(NCD)Filmsbyheliconwaveplasma(HWP)chemicalvapordepositionatroomtemperaturewasreported.ThegrowthmorphologyandtheroughnessofNCDsampleswascharacterizedusingfiledemissionscanningelectronmicroscopy(SEM-SU8010)andatomforcemicroscopy(AFM),respectively.Theresultsshowthegrowthrateofthefilmwasveryfast,about833nm/min.TypicalG,Dbands
简介:AmedicalcastCoCrMoalloywascoatedbyplasmanitridingprocesstoenhancethewearresistance.Themicrostructures,phasesandmicro-hardnessofnitridedlayerswereinvestigatedbyatomicforcemicroscopy(AFM),scanningelectronmicroscopy(SEM),X-raydiffraction(XRD)andmicro-hardness.Tribologicalpropertieswereinvestigatedonapin-on-discweartesterunder25%bovineserumsolutions.Theexperimentalresultsshowedthatplasmanitridingwasapromisingprocesstoproducethick,hardandwearresistantlayersonthesurfaceofCoCrMoalloy.TheharderCrNandCr2Nphasesformedontheplasmanitridedlayerwiththecompactnano-crystallinestructure.Comparedwiththeuntreatedsample,allnitridedsamplesshowedthelowerwearratesandhigherwearresistanceatdifferentappliedloadsandnitridingtemperatures.Itwasconcludedthattheimprovementofwearresistancecouldbeascribedtotheformationofthickerandhardernitridedlayerswiththespecificmicrostructuresonnitridedsurfaces.
简介:Inordertostudytheatomicoxygencorrosionofspacecraftmaterialsinlowearthorbitenvironment,anatomicoxygensimulatorwasestablished.Inthesimulator,a2.45GHzmicrowavesourcewithmaximumpowerof600WwaslaunchedintothecircularcavitytogenerateECR(electroncyclotronresonance)plasma.TheoxygenionbeammovedontoanegativelybiasedMoplateundertheconditionofsymmetrymagneticmirrorfieldconfine,thenwasneutralizedandreflectedtoformoxygenatombeam.Thepropertiesofplasmadensity,electrontemperature,plasmaspacepotentialandionincidentenergywerecharacterized.TheatomicoxygenbeamfluxwascalibratedbymeasuringthemasslossrateofKaptonduringtheatomic5~30eVandacrosssectionofφ80mmcouldbeobtainedundertheoperatingpressureof10-1~10-3Pa.Suchahighfluxsourcecanprovideacceleratedsimulationtestsofmaterialsandcoatingsforspaceapplications.
简介:TheeffectoftitaniumadditiononthemicrostructureandmechanicalpropertiesofbrassCu40Znhasbeenstudiedviathepowdermetallurgy(P/M)route.Thewater-atomizedCu40Zn—1.0wt%Tialloypowderwasconsolidatedatdifferenttemperaturesintherangeof400—600℃usingsparkplasmasintering(SPS)andhotextrusionsubsequently.Resultsshowthatthesuper-saturatedsolidsolutiontitaniumelementinrapidlycooledbrassCu40Znpowdercreatedhighchemicalpotentialforaprecipitatereaction,showingsignificantgrainrefinementeffectsontheconsolidatedCu40Znmatrix.Consequently,excellentmechanicalpropertieswereobtainedbyprecipitationhardeningandworkhardeningaftersinteringandextrusion,withyieldstrengthof390MPa,ultimatetensilestrengthof617MPa,andVickersmicro-hardnessof192HV,whichare28.7%,23.4%,and23.9%highervaluesthanthoseofextrudedCu40Znbrass,respectively.
简介:
简介:
简介:Layeredcathodematerialsofhigh-temperaturelithiumbatteries,LiNi1/3Mn1/3Co1/3O2aresynthesizedbyasol-gelmethodwithvariationinfinalsinteringtemperatureforboreholeapplications.Thestructure,morphologyandhigh-temperaturedischargeperformanceoftheseresultingproductsareinvestigatedbyX-RayDiffraction(XRD),scanningelectronmicroscopy(SEM),laserparticlesizeanalysis,galvanostaticandpulsedischarge.Theresultsofstructuralanalysisindicatethatthesamplesinteredat800℃hasthecharacteristicsofgoodcrystallinity,narrowsizedistributionandlargespecificsurfaceareaatthesametime.Thedischargeexperimentsalsoindicatethatthissamplehasthebestelectrochemicalproperties,withthemaximumdischargecapacitiesof314.57and434.14mAh·g-1at200and300℃respectivelyandtheminimumcellinternalresistancesatbothtemperatures.
简介:Anovelfluorescentprobe9-(4-(1,2-diamine)benzene-N1-phenyl)acridine(DABPA)wassynthesizedforthedetectionofnitricoxide(NO)andcharacterizedbyIR,1H-NMRandEI-MSspectroscopy.Basedonaphotoelectrontransfermechanism,thefluorescenceintensitiesofDABPAwereinvestigatedwiththedifferentconcentrationsofNO.Undertheoptimalexperimentalconditions,thefluorescenceintensityofDABPAhadagoodlinearrelationship(R2=0.9977)withNOconcentrationintherangefrom1×10-7to1.5×10-6mol/Lwithadetectionlimitof1×10-8mol/L.ThecytotoxicityinducedbyDABPAwasevaluatedbytheMTT(3-(4,5-dimethylthiazol-2-yl)-2,5diphenyltetrazoliumbromide)assayforbiologicalapplication.Furthermore,theprobeDABPAhadalsobeensuccessfullyappliedtoreal-timeimageNOproducedinPC12cellsinthepresenceofL-arginine.