简介:Cr的Nanopowder:Cr的GGG和nanopowder,Nd:有从0.1at.%到1.5at.%的Cr3+的不同集中的GGG被大音阶的第五音胶化方法用醋酸和乙烯乙二醇综合。热gravimetric分析和微分扫描热量测定(TGA-DSC),X光检查衍射(XRD)和光致发光光谱学被用来描绘粉末。当在1000点对待时,雏晶尺寸是大约58nm?????????????????猯灵?匠?猼'T资???猼灵?????????猯'T??猼灵???? ̄?????猯'T????猯灵??猼'T?????吗????????????????‵渠????????浮??
简介:Precipitationstrengtheningaswellassolutionstrengtheningiskeymechanismforheatresistantsteels.Itisveryimportanttocharacterizetheprecipitatesin9%Crferriteheatresistantsteels,especiallytoshowthenanometer-sizedparticles.Bytransmissionelectronicmicroscopeattachedwithanenergydispersivespectrometeraswellasopticalmicroscope,scanningelectronicmicroscope,themicrostructureandchemicalcompositionofprecipitatesina9%Crheatresistantsteelafterdifferentheattreatmentswereinvestigated.ItwasfoundthatthemicrostructureofnormalizedsamplewasmartensitewithfineNbCandFe3C.Themicrostructureoftemperedsampleistemperedmartensite,andtheremainlyweretwotypesofprecipitates,M23C6withthesizerangeof50-300nmandMXwiththesizeof10-100nm.SuperfineM23C6precipitatedpreferablyonpriorausteniticgrainboundariesandmartensiticlathboundaries,whilenanometer-sizedMXprecipitatesweredistributedrandomly.Aftershort-termcreep,Lavesphaseformedalonggrainboundariesofthe9%Crsteel,andM23C6andMXprecipitateswerefoundtobecomecoarser.Moreinformationaboutprecipitatesinthe9%Crsteelhadbeenexhibitedbyatomicforcemicroscopy.Thereby,distribution,sizeandshapeoftheprecipitatesaswellastheircompositionsandstructureswererevealed.
简介:以便改进金属压路机的表演,Mo+Y2O3合金粉末由CO2激光为激光表面alloying处理在40Cr钢压路机底层的表面上一致地习惯于上衣,结果证明许多好后果在增加稀土元素氧化物Y2O3以后被获得。合金层的水晶谷物显著地被精制。水晶谷物的边界被加强。微观结构的一致性和密度被增加。坚硬和合金层的穿的抵抗更加被改进。合金层的原子价电子结构分析被固体和分子(EET)的实验电子理论做。计算结果证明Y应该在第一个阶段被混合,Fe应该在第十八个混合乐队。说明的分析结果稳固的答案的电子理论在alloying上显示出加强的效果层,它提高了契约并且证实了试验性的结果。
简介:Ni-Cr-Mo合金经冷压成型后于真空中以不同温度进行烧结.通过测定其相对密度、线收缩率、拉伸强度和硬度,研究烧结温度对合金性能的影响.研究结果表明:当烧结温度不超过1330℃时,合金的相对密度、收缩率、拉伸强度和硬度随烧结温度的上升而缓慢增加;当温度上升到1360℃时,合金的这些性能指标急剧增大;当温度上升到1390℃时,烧结后的合金试样外形发生严重变形.
简介:Inordertoutilizetheadvantageofoxidesinstainlesssteel,theformationoftitaniumnitride(TiN)andoxide(TixOy)inthe17CrsteelwasinvestigatedbythecalculationofthefreeenergyofreactionandthermodynamiccalculationwithThermo-calcsoftware.Theresultindicatesthatthecompetitivereactionbetweenthedissolved[O]andthedissolved[N]withthedissolved[Ti]inmoltensteelresultsindifferentprecipitationsequencesofTiNandTixOy.TheprimaryprecipitationofTiNrequiresalow[O]andtheprimaryprecipitationofTixOyrequiresalow[N].Theincreaseof[Ti]causesahigherprecipitationtemperatureofTiNandTixOyinbothTi-NandTi-Oalloysystems.Equilibriumrelationsof[Ti]vs[N]and[Ti]vs[O]showthatthesolubilityproductsfallwiththedecreaseofthetemperature,andthentheprecipitationoftheinclusionsbecomeseasier.IntheTi-Oalloysystem,ahigh[O]andalow[Ti]arefavorabletotheprecipitationofTi3O5,andahigh[Ti]contentandalow[O]favorabletotheTi2O3precipitation.
简介:Martensiticstainlesssteelcontaining12%-18%Crhavehighhardnessduetohighcarboncontent.Thesesteelsarecommonutilizedinquenchingandtemperingprocessesforknifeandcutlerysteel.Thepropertiesobtainedinthesematerialsaresignificantlyinfluencedbymatrixcompositionafterheattreatment,especiallyasCrandCcontent.Comprehensiveconsideredthehardnessandcorrosionresistance,anewtypemartensiticstainlesssteel6Cr15MoVhasbeendeveloped.Thisstudyemphaticresearchestheeffectofheattreatmentprocessesonmicrostructureandmechanicalpropertiesof6Cr15MoVmartensiticstainlesssteel.Thermo-Calcsoftwarehasbeencarriedouttothermodynamiccalculation;opticalmicroscope(OM),scanningelectronicmicroscope(SEM)andtransmissionelectronmicroscope(TEM)havebeencarriedouttomicrostructureobservation;hardnessandimpacttoughnesstesthavebeencarriedouttoevaluatethemechanicalproperties.Resultsshowthattheequilibriumcarbidein6Cr15MoVsteelisM23,C6carbide,andfinelydistributedofM23C6carbidescanbeobservedonannealedmicrostructureof6Cr15MoVstainlesssteel.6Cr15MoVmartensiticstainlesssteelhasawiderquenchingtemperaturerange,thehardnessvalueofsteel6Cr15MoVcanreachto60.8-61.6HRCwhenquenchedat1060-1100℃.Finelydistributedcarbideswillexistinquenchedmicrostructure,andeffectivelyinhabitthegrowthofaustenitegrain.Withtheincreasingofquenchingtemperature,thevolumefractionofundissolvedcarbideswilldecrease.Theexcellentcomprehensivemechanicalpropertiescanbeobtainedbyquenchedat1060-1100℃withtemperedat100-150℃,anditismainlyduetothehighcarbonmartensiteandfinegrainsize.Atthesetemperatureranges,thehardnesswillretainabout59.2-61.6HRCandtheCharpyU-notchimpacttoughnesswillretainabout17.3-20J.Themorphologyofimpactfracturesurfaceoftestedsteelissmalldimpleswithasmallamountofcleavageplanes.Theareaofcleavageplanesincreaseswiththeincreas
简介:探讨了在大生产条件下4Cr5MoSiV1钢的脱碳层测定原则。结果表明,金相法测定结果较准确且操作简便
简介:Inthelastthreedecadesnewstrongermodified9%Crsteelshavebeenintroducedinnewpowerplantswithsteamparametersupto300bar(1bar=10~5Pa)and600℃.Inordertofurtherincreasethesteamparametersofsteelbasedpowerplantsuptoatargetvalueof650℃/325baritisnecessarytodoublethecreepstrengthcomparedwithtodaysstrongest9%Crsteels,andatthesametimetheresistanceagainststeamoxidationmustbeimprovedbyadding12%Crtothesteel.However,sofarallattemptstomakestronger12%Crsteelshavebeenunsuccessfulbecausethehighchromiumcontentintroducedseveremicrostructureinstabilitiesinthetestedsteels.Recently,itwasfoundthatthemicrostructureinstabilitiesin11%-12%CrsteelscanbeexplainedbytheprecipitationofcoarseCr(V,Nb)NZ-phases,whichdissolvefine(V,Nb)Nnitrides.AnewpossibilitytousetheZ-phaseforstrengtheningof12%Crsteelshasbeenidentified,andthedevelopmentofstablestrongmartensitic12%Crsteelsbasedonthisconceptisexpectedtoallowtheconstructionof325bar/650℃steampowerplantsallbasedonsteel.
简介:Thisstudyinvestigatesthecorrosionpropertiesof0Cr11Tiand0Cr11NbTiferriticstainlesssteels(FSS)forautomotiveexhaustsystems.Theresultsindicatethatthebasemetalandweldseamof0Cr11NbTisteelexhibitbetterintergranularandcondensatecorrosionresistantpropertiesbecausecarbonandnitrogenarestabilizedbyNbandTi,andtheprecipitationofCrcarbideisretardedingrainboundaries.
简介:Abstract:TheeffectofTiandNbontherecrystallizationandtherecrystallizedgrainsizeofthehot-rolledplatesandcold-rolledsheetsofultralowcarbonandnitrogen(ULCN)Cr18ferriticstainlesssteel(FSS)isinvestigated.Theresultsshowthattherecrystallizationofhot-rolledplatesandcold-rolledsheetswith0.29%Nbisdelayed,andtherecrystallizedgrainsaresignificantlyrefined.