简介:Sodiumparanitrophenolatedihydrate(NPNa·2H2O)isanexcellentsemiorganicnonlinearoptical(NLO)material,crystallizesbothinwaterandmethanolwithhighdegreeoftransparency.Goodopticalqualitysinglecrystalsofdimensionupto18mmx6mmx3mmareobtainedbyisothermalsolventevaporationtechnique.Thesolubilityofthecrystalindifferentsolventswasmeasuredgravimetrically.ThesinglecrystalsofNPNa·2H2Oshowvariationinphysicalpropertiesandgrowthrateindifferentsolvents.Methanolorethanolsolutionyieldscrystalsofbipyramidalshapewithclearmorphology.However,methanolgrowncrystalisexhibitingimprovedhardnessparametersandpossessesexcellentthermalstabilityascomparedtowatergrowncrystals.TheeffectsofsolventonhardnessparameteralongwiththermalandopticalpropertiesofNPNa·2H2Owasrevealedinthispaper.
简介:Throughmeasuringthecoefficientoflinearexpansion,thestructureandpropertiesoftheLi2O-Al2O3-SiO2lowexpansionglassceramicscontainingB2O3arestudiedbyJRandXRD.ItisshoutnthattheIRmethodisefficientinthestudyoftheglass-ceramicsstructure.Thereisa"Boronabnormality"inthesystemwhichhasanimportantinfluenceonthepropertiesoftheglass-ceramics.
简介:TheelectronicstructuresofCuS2,CuSe2andCuTe2withpyritestructures,withintheframeworkthedensity-functionaltheoryhavebeeninvestigated.ThecalculatedresultsexplainedtherecentexperimentalresultswhichshowthatthereisnoclearindicationofstrongelectroncorrelationsintheelectronicpropertiesofCupyrites,duetothedominantchalcogenpcharacterratherthandcharacteristicofCuattheFermilevel.
简介:TheantibacterialeffectofcarryingsilverB2O3-SiO2-Na2Oglassmaterialwasstudiedbymeansofantibacterialring,nephelometery,MICvalue,thinfilmattachmentandmicrocalorimetry,respectively.TheexperimentalresultsoffivekindsofantibacterialtestmethodsarealmostidenticalandcanverifythatcarryingsilverB2O3-SiO2-Na2Oglassmaterialexertsanexcellentantibacterialperformance.Antibacterialringandnephelometeryaresimple,quick,buttheprecisionisrestrictive.MICvalue,thinfilmattachmentmethodandmicrocalorimetrycanquantitativelycomparetheantibacterialeffectsoftheantibacterialglassmaterial.Comparedwiththetraditionalmicrobetestmethods,themicrocalorimetrycananalyzetheinhibitingeffectofthecell'sgrowthandmetabolismontheantibacterialglassmaterialbymonitoringthethermaleffectcontinuouslyandautomatically.
简介:TiB2ceramicspowderwassynthesizedfromB2O3-TiO2-Mgsystem.TheeffectsofTiB2additionasdiluentonthecombustionsynthesisprocesswereinvestigated.TheresultsofthermodynamiccalculationandexperimentsshowthattheincreaseofTiB2contentrangingfrom0to20wt%canreducetheadiabatictemperatureTadfrom3100Kto2896KandcombustiontemperatureTcfrom2139Kto1621Krespectively.TheparticlesizeandhalfwidthoftheparticledistributionarealsoincreasedwiththeadditionofTiB2increasingfrom0to20wt%.ThecombustionproductisamixtureofTiB2,MgO,andotherintermediatephases.TheleachedproductcontainsmainlyTiB2,TiO2andTiN,anditsoxygencontentis7.77wt%.
简介:Defectsofpolymer-derivedSi-C-OfiberswereintensivelystudiedbytheSEMandTEMtechniquesandtheiroriginationswerealsodiscussedonthebasisoffactorsexperiments.Thedefectswerefoundmainlyintheformofstrumaes,pitsandsplitsonsurfacesaswellasmicroflawnetworks,porosityclustersandinclusionsinthebulk.Factorsexperimentsrevealthatanonuniformoraninsufficientcuringwouldresultinlarger-sizedstru-maesorinteriormicroflaws.Gasevolutionratesduetodifferentfiringrateshaveagreatinfluenceontheformationofinternalmicrofiawsorporosityclustersandsomeoxidation-inducedpitsorsplitsmaybeformedonsurfacesbe-causeoratraceofoxygenorwatervaporaccumulatedfromtheflowinginertatmosphereduringpyrolysis.
简介:Usingdirectfinitedifferencemethod,anumericalmodelforsimulatingthetemperaturefieldinthechargeduringinductionskullmelting(ISM)hasbeendeveloped.Onthebasisofthemodel,thetemperaturefieldinTi-47Ni-9Nbingothasbeencalculatedundervariousmeltingconditions.Finally,theprocessingparameters(meltingpower,melting-downtimeandthefinalmelttemperature)havebeenoptimized.
简介:Aneffectivedispersion-strengtheningphaseinAl-8Fe-2Mo-2Zr-2Nd-0.7Ti-1.6SialloywasidentifiedtobeanagedprecipitatephasewithpossiblechemicalstoichiometryofAl20(Ti,Mo)2Ndandfcccrystalstructurewithao=1.455nm.ThestructurewasdeterminedtobeFm3mspacegroup.
简介:Theimplantedionrange,thedepthprofileandthefilmsttuctureoftheimplantedlayerwerestudied;thecarrierconcentrationandthemobilityweremeasured;theconductivitymechanismofthefilmimplantedFeintoAl2O3ceramicwasdiscussed.TheconclusionisthattheimplantedFe2+ionsmoveintoAl2O3latticeandreplaceAl3+toformsubs-titutionimpuritiessothattheionimplantedlat-tice,ascomparedwiththeoriginalone,presentsaneffectivenegativechargewhichformsanegativechargecenter.Avacancyisboundarroundit,andanacceptorisintroducedintheforbiddenband.
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简介:三新奇Ba_5RNiNb_9O_(30)(R=La,Nd和Sm)陶艺在BaO-R_2O_3-NiO-Nb_2O_5系统被准备并且描绘。所有三混合物areparaelectjicphasesadopting。在房间温度的充满的四角形的钨铜(TB)结构。在1MHz,Ba_5RNiNb_9O_(30)陶艺有高电介质在范围193-245.3,在范围0.0059-0.0087的低绝缘的损失,和在范围的绝缘的常数(tau_e)的温度系数的常数-1140-1310X10~(-6)中心点degC。他们绝缘的常数的温度系数显著地Ba_5RNiNb_9O_(30)与那些相比被减少(R=La,Nd,Sm)陶艺。