简介:Thenon-isothermalcrystallizationkineticsofpolyamide6/diamine-modifiedmulti-walledcarbonnanotube(PA6/D-MWNT)nanocompositewasinvestigatedbydifferentialscanningcalorimetry(DSC).ThemodifiedAvramiequation,theOzawaequationandthecombinedAvrami/Ozawaequationwereemployedtoanalyzethenon-isothermalcrystallizationdata.ThecrystallizationactivationenergieswerealsoevaluatedbytheKissingermethod.ItwasfoundthatthecombinedAvrami/Ozawaequationcouldsuccessfullydescribethenon-isothermalcrystallizationprocess.TheresultsshowedthatD-MWNTsnotonlyactedaseffectivehetero-geneousnucleatingagentsforPA6andnoticeablyincreasedthecrystallizationtemperatureofPA6,butalsoinfluencedthemechanismofnucleationandcrystalgrowthofPA6andthenreducedtheoverallcrystallizationrateoftheneatPA6matrix.ThecrystallizationactivationenergyforthenanocompositesamplewasgreaterthanthatoftheneatPA6,whichindicatedthattheadditionofD-MWNTshinderedthemobilityofPA6chainsegments.
简介:微观结构和Ni//3艾尔的机械性质基于拥有低杂质内容的Ni-Al-Mosuperalloy-IC6,由水花免职技术的高密度被学习了。结果显示IC6合金在空间和中间的温度两个都有好张力的力量和延伸。(编辑作者摘要)6个裁判员。
简介:Ionbeamenhanceddeposition(IBED)wasemployedtoincreasethefrettingfatigueresistanceofTi6AI4V.CrNandTiNhardcoatingswereappliedonthebasematerialandshotpeeningwascombinedwiththehardcoatingstostudytheduplexeffectonfrettingfatigueresistance,TheIBEDcoatingsexhibitedagoodbondingstrength.Theydidnotspalloffevenaftershotpeening.However,anoptimumcompositionofCrNshowedbetterfrettingfatigueresistancethanthatofTiNwiththesameprocessingparameters.
简介:Becauseoftheexcellentmechanicalpropertiesof34C「NiMo6steel,itiswidelyusedinhigh-valuecomponents.Manyconventionalapproachestostrengthening-steelstypicallyinvolvethelossofusefulductility.Inthisstudy,34CrNiMo6Steelhavinghighstrengthandductilityisproducedbylasersolidforming(LSF)w让haquenching-tempering(QT)treatment.TemperingofbainiteismainlybysolidphasetransformationinthepreviousLSFlayersduringtheLSFprocess.ThestablemicrostructureofLSFconsistsofferriteandfinecarbides.Themicrostructuretransferstotemperedsorbiteafterheat-treatment.ThetensilepropertiesoftheLSFsteelmeetthoseofthewroughtstandard.TheUTSandelongationofLSFsampleat858MPa,19.2%,respectively,aregreaterthanthoseofthewrought.TheQTtreatmentenhancedtheultimatetensilestrengthandyieldstrengthoftheLSFsample.Theultimatetensilestrength,yieldstrength,reductioninarea,andelongationoftheLSF+QTsampleat980MPa,916MPa,58.9%,and13.9%,respectively,aregreaterthanthoseofthewroughtstandard.TheyieldstrengthoftheLSF+QTsampleisapproximately1.27timesthatofthewrought.TheLSFsamplesfailedinaductilefracturemode,whiletheLSF+QTsamplesshowedmixed-modefailure.ThedefectshaveonlyasmalleffectonthetensilepropertiesowingtotheexcellentductilityoftheLSFsample.
简介:AnewcompoundK6Ti0.67Nb15.33O42waspreparedforthefirsttimebysolidstatereactioninK2O-Ni2O3-Nb2O5ternarysystem.Thenewcompoundwascharacterizedbyelectronprobe,X-raypowderdiffractionandDTA.TheresultofX-raypowderdiffractionshowsthatK6Ti0.67Nb15.33O42crystallizesthehexagonalsystemwithunitcellparametersa=9.1341(5)A,c=12.090(1)A.andspacegroupP62/mcm(193).