简介:WepresentthetemperaturedependentelectricaltransportmeasurementsofAg/Si(111)-(√3×√3)R30°bytheinsitumicro-four-pointprobemethodintegratedwithscanningtunnelingmicroscopy.Thesurfacestructurecharacterizationsshowhexagonalpatternsatroomtemperature,whichsupportstheinequivalenttriangle(IET)model.Ametal-insulatortransitionoccursat-115K.Thelowtemperaturetransportmeasurementsclearlyrevealthestronglocalizationcharacteristicsoftheinsulatingphase.
简介:Basedonconsolidationequationsproposedforunsaturatedsoil,ananalyticalsolutionfor1Dconsolidationofanunsaturatedsingle-layersoilwithnonhomogeneousmixedboundaryconditionisdeveloped.Themixedboundaryconditioncanbeusedforspecialapplications,suchastestsoccurinlaboratory.Theanalyticalsolutionisobtainedbyassumingallmaterialparametersremainconstantduringconsolidation.Inthederivationoftheanalyticalsolution,thenonhomogeneousboundaryconditionisfirsttransformedintoahomogeneousboundarycondition.Then,theeigenfunctionandeigenvaluearederivedaccordingtotheconsolidationequationsandthenewboundarycondition.Finally,usingthemethodofundeterminedcoefficientsandtheorthogonalrelationoftheeigenfunction,theanalyticalsolutionforthenewboundaryconditionisobtained.Thepresentmethodisapplicabletovarioustypesofboundaryconditions.Severalnumericalexamplesareprovidedtoinvestigatetheconsolidationbehaviorofanunsaturatedsingle-layersoilwithmixedboundarycondition.
简介:Thispaperisconcernedwithexperimentalandnumericalresearchon3DflowpastprismaticturbinecascadeSE1050(knowninQNETnetworkasopentestcaseSE1050).Theprimarygoalwastoassesstheinfluenceoftheinletvelocityprofileontheflowstructuresintheinterbladechannelandontheflowfieldparametersatthecascadeexitandtocomparethesefindingstoresultsofnumericalsimulations.Investigationsof3Dflowpastthecascadewithnon-uniforminletvelocityprofilewerecarriedoutbothexperimentallyandnumericallyatsubsonic(M2is=0.8)andattransonic(M2is=1.2)regimeatdesignangleofincidence.Experimentaldatawasobtainedusingatraversingdevicewithafive-holeconicalprobe.Numerically,the3DflowwassimulatedbyopensourcecodeOpenFOAMandin-housecode.AnalysesofexperimentaldataandCFDsimulationshaverevealedthedevelopmentofdistinctivevortexstructuresresultingfromnon-uniforminletvelocityprofile.Originofthesestructuresresultsinincreasedlossofkineticenergyandspanwiseshiftofkineticenergylosscoefficientdistribution.Differencesfoundbetweenthesubsonicandthetransoniccaseconfirmearlierfindingsavailableintheliterature.ResultsofCFDandexperimentsagreereasonablywell.
简介:利用水热合成方法合成了2个新的配位聚合物[Ag(4,4′-bpy)(H2PO4)].2H2O(1)和[Cu4(L)8H4](2)(4,4′-bpy=4,4′-联吡啶,L=4-咪唑基苯甲酸),并通过元素分析、红外光谱和X-射线单晶衍射方法确定了该化合物的晶体结构.结构分析表明化合物1属于单斜晶系,P2/c空间群,晶胞参数a=8.4909(17)nm,b=8.7284(17)nm,c=18.498(4)nm,β=100.99(3)°,V=1.3458(5)nm3,Z=4,R1=0.0362,ωR2=0.0966.化合物1展示了一个一维的链式结构.化合物2属于单斜晶系,C2/c空间群,晶胞参数a=24.509(5)nm,b=18.957(5)nm,c=17.246(5)nm,β=119.807(5)°,V=6.953(3)nm3,Z=4,R1=0.0455(3564),ωR2=0.1519(6161).化合物2中存在着丰富的π…π堆积作用.
简介:Anewefficientmeshlessmethodbasedontheelement-freeGalerkinmethodisproposedtoanalyzethestaticdeformationofthinandthickplatestructuresinthispaper.Usingthenew3Dshell-likekinematicsinanalogytothesolid-shellconceptofthefiniteelementmethod,discretizationiscarriedoutbythenodeslocatedontheupperandlowersurfacesofthestructures.Theapproximationofallunknownfieldvariablesiscarriedoutbyusingthemovingleastsquares(MLS)approximationschemeinthein-planedirections,whilethelinearinterpolationisappliedthroughthethicknessdirection.Thus,differentboundaryconditionsaredefinedonlyusingdisplacementsandpenaltymethodisusedtoenforcetheessentialboundaryconditions.TheconstrainedGalerkinweakform,whichincorporatesonlydisplacementdegreesoffreedom(d.o.f.s),isderived.Amodified3Dconstitutiverelationshipisadoptedinordertoavoidoreliminatesomeself-lockingeffects.Thenumericefficiencyoftheproposedmeshlessformulationisillustratedbythenumericexamples.
简介:标题化合物(C30H35N3)以4-甲基苯甲醛、环十二酮和3-甲基-1-苯基-1H-吡唑-5-胺,在三氟乙酸和醋酸的作用下,经微波辐射合成得到.其结构通过单晶X射线衍射法确定,晶体属单斜晶系,空间群P21/c,相对分子质量Mr=437.61,晶胞参数a=1.08926(11)nm,b=2.1927(2)nm,c=1.04954(14)nm,V=2.4641(5)nm3,Z=4,晶胞密度Dc=1.180g/m3,吸收系数μ=0.069mm-1,单胞中电子的数目F(000)=944.晶体结构用直接法解出,经全矩阵最小二乘法对原子参数进行修正,最终的偏离因子为R=0.0468,ωR=0.0905.在晶体结构中新形成的吡啶环为共平面结构.