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281 个结果
  • 简介:Thesolidaddofthefirstprotonatedzincoborophosphate,(H3O)Zn(H2O)2BP2O8·H2O(1),wassoventothermallysyn-thesizedbythereactionofZn(NO3)2·6H2OandH3BO3withH3PO4inamixedsolvent,andstructurallycharacterizedbysingle-ystalX-raydiffractionanalysis.ItcrystallizesinthehexagonalP6122,a=0.9604(4)nm,c=1.5297(6)nm,V=1.2218(8)nm^3,Dc=2.921g/cm^3,Z=6,F(000)=1080,μ=3.495mm^-1.Thestmchwefeaturesthatthetetrahedra-te-trahedrahdlcesinterconnectedbyoctahedraandstronghydro-gembondinteractionsformathree-dimensionalframework.Theprotonatedwatermoleculesarelocatedatuniquepositions.othercharacterizationsbyIRandthermalanalysisarealsode-scribed.

  • 标签: (H3O)Zn(H2O)2BP2O8·H2O 合成 结构 质子化 螺旋带状物 硼磷酸锌化合物
  • 简介:Theobjectinthispaperistoconsidertheproblemofexistence,uniqueness,explicilrepresentationof(0,2)-interpolationonthezerosof(1-x2)Pn-1(x)/xwhennisodd,wherePn-1denotesLegendrepolynomialofdegreen-1,andtheproblemofconvergenceofinterpolatorypolynomials.

  • 标签: INTERPOLATION CONST UNIQUENESS details polynomial arbitrary
  • 简介:0.5%Pt-K/γ-Al2O3catalystsforthesynthesisofo-phenylphenol(OPP)fromo-cyclohexenyl-cyclohexanone(dimer)dehydrogenationwerepreparedbymeansofatwosubsequentimpregnationmethod.Theeffectsofcatalystpreparationparameters,suchasKpromoters,calcination,andreductionconditions,wereinvestigated.TheresultsshowedthattheadditionofK2SO4toPt/γ-Al2O3catalystnotablypromotedtheselectivityofOPP,anditsoptimumcontentwasfoundtobe6%inmassfraction.ThehigheractivitywasobtainedwhenPt/γ-Al2O3catalystwascalcinedinnitrogenatmosphereat400―500°Candthenreducedatthesametemperaturefor3hinhydrogenatmosphere.TheconversionofthedimerandtheselectivityofOPPwerealwaysabove99%and90%,respectively,over0.5%Pt-6%K2SO4/γ-Al2O3catalystduringthepilotscaletestof8000h.

  • 标签: 苯基苯酚 PT催化剂 K助催化剂 焙烧
  • 简介:WeuseMnforthesetofalln×nrealmatrices;(n)for{1,…,n};Snforthesymmetricgroupon〈n〉;A[α]α∈

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  • 简介:Theenantiomersofthirty-nineO-ethylO-phenylN-isopropylphosphoroamidothioateshavebeenseparatedbyhighperformanceliquidchromatographyonaPirklemodelchiralstationaryphaseusingtenmobilephase.Chromatographicdataarepresentedfortheseparationoftheseorganicphosphorusenantiomersonthechiralphase.Theinfluencesofmolecularstructuresandcompositionsofmobilephaseshavebeendescribed.

  • 标签: HPLC phosphorus ENANTIOMER SEPARATION PESTICIDE ENANTIOMERS
  • 简介:有N-(2-propionic酸)的新奇金轧(III)建筑群-salicyloylhydrazone(C10H10N2O4,H3L)并且1,10-phenanthroline(C12H8N2,phen)被准备并且描绘。水晶结构[Gd(H2L)(HL)-(H2O)3]2潲楰湯捩???慳楬祣潬汹?票牤穡湯??ㄠ??桰湥湡桴潲楬敮???????楢慯瑣癩瑩?

  • 标签: 邻二氮杂菲 晶体结构 X射线衍射 三斜晶系
  • 简介:伪-芳基nitrone是nitrones的最有用的类型之一并且广泛地在最近的年里被探索了。然而,糖一半以前没被介绍进这些分子。我们这里在苯经由代替N的hydroxylamine和芳基醛glycosides的冷凝作用介绍了伪-芳基nitroneO-glycosides的有效合成。

  • 标签: 高效合成 糖基 芳基 硝酮 缩合 芳醛
  • 简介:利用直接法合成未见文献报道的K8[ZnMg(H2O)W11O39]·15H2O,通过ICP,IR和XRD等方法对其结构进行表征,结果表明所合成的配合物具有Keggin结构.采用化学热扩渗法对合成配合物进行稀土扩渗实验,经XPS测试表明,有微量的钆渗进配合物的体相,并与组成元素存在键合作用,导电性测试结果表明,扩渗后试样的导电率提高10^5倍,是一种优良的固体电解质,有望成为具有实用价值的功能材料.

  • 标签: 多金属氧酸盐 稀土多元渗 导电性
  • 简介:Fivechiralstationaryphases(CSPs)wereusedtoseparatetheenantiomersofaseriesofO,O-diethyl(p-methyl-benzenesulfonamindo)-aryl(alkyl)-methylphosphonates.Achiralrecognitionmechanismwaspresentedtoexplaintheresolutionofthesecompounds.ResultsshowthatCSPwithstrongπ-acceptor3,5-dinitrobenzoylgroupandhighsterichindrancehasthebestresolutionabilityinchiralseparationofO,O-diethyi(p-methyl-benzenesulfonamindo)-aryl(alkyl)-methylphosphonates.WhenaCSPhasjustastrongπ-acceptor3,5-dinitrobenzoylorhighsterichindranceitdoesnothavegoodchiralresolutionability.ThechiralrecognitionismoredifficultwhentheCSPhasmorethanoneasymmetriccenter.

  • 标签: CHIRAL stationary PHASES (CSPs) CHIRAL recognition
  • 简介:AquantummechanicalcalculationwasperformedtostudytheTranslation-Vibration(T-V)energytransferofacolinearOH+O/OD+Osystem,forwhichDelvescoordinatesandR-matrixpropagatationmethodswereappliedtoaMulius-Blintpotentialenergysurface.ThecalculatedresultoftheT-Venergytransferprobabilityshowsstrongoscillationphenomenaandthecollisiondelaytimeofthetitlesystemwasinthe10-15—10-12stimescale.Thekineticisotopeeffectwasdiscussedinthisworktoo.

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  • 简介:FurfuralinaqueoussolutionwastreatedbyUV/O3method.Theresultsshowthattheremovalrateoffurfuralisseverelyenhancedandthesynergismphenomenonappearswhenultravioletandozonearepresenttogether.TheinfluencesofexperimentalparameterssuchaspH,theintensityoflightandthenegative-positiveionsonfurfuraldegradationwereinvestigated.Theresultsindicatethatfurfural(300mg/L)isalmostcompletelydegradedafter3hundertheoptimumconditions.TheintermediateinthefurfuraldegradationwascharacterizedbyGC-MSandIRspectrumandthedegradationmechanismoffurfuralbyUV/O3technologywasproposed.

  • 标签: 全降解 糠醛 技术 协同作用 实验参数 光照强度
  • 简介:ThecapacitytocaptureCO2wasdeterminedinseveralstoichiometriccompositionsintheLi2O–Bi2O3system.Thecompounds(Li7BiO6,Li5BiO5,Li3BiO4andLiBiO2phases)weresynthesizedviasolid-statereactionandcharacterizedbyX-raydiffraction,scanningelectronmicroscopyandN2adsorptiontechniques.Thesampleswereheat-treatedattemperaturesfrom40to750°CundertheCO2atmospheretoevaluatethecarbonateformation,whichisindicativeofthecapacityofCO2capture.Moreover,Li7BiO6showsanexcellentCO2capturecapacityof7.1mmol/g,whichisconsiderablyhigherthanthoseofotherpreviouslyreportedceramics.Li7BiO6isabletoreactwithCO2from240°Ctoapproximately660°CshowingahighkineticreactionevenatCO2partialpressurevaluesaslowas0.05.

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  • 简介:利用室温液相还原、晶种生长的方法,成功的制备了大小形貌均一、性能稳定且具有磁性的Fe3O4@Cu2O复合纳米粒子,并且对制备的Fe3O4@Cu2O纳米粒子进行了光催化性能的研究.在以紫外光为光源的照射下,合成的Fe3O4@Cu2O纳米粒子对有机染料甲基蓝溶液起到很好的降解作用.更重要的是,在外加磁场的作用下,Fe3O4@Cu2O纳米粒子容易回收,具有良好的可循环利用性能.

  • 标签: Fe3O4@Cu2O纳米粒子 晶种生长 催化剂 循环利用性
  • 简介:Thecrystalandmolecularstructuresof[(C3H7O)2PS2]2(CCDCNo.217201)weredeterminedbymeansofX-raycrystallography.ItcrystallizedinatriclinicsystemwithspacegroupP1^-andlatticeparametersa=0.82794(3)nm,b=0.84764(2)nm,c=0.85034(3)nm,α=97.78(3)°β=110.77(3)°,γ=94.95(3)°,V=0.54701(9)nm^3,Z=1.Inthismolecule,thetwodiisopropyldithiophosphategroups,[(C3H7O)2PS2]2,whichareparalleltoeachother,arelinkedbyanS--Sbondandthereexistinversioncentersinthemolecule,Inthestructure,theP=Sbondsinthetwodithiophosphateunitsaretrans-orientedtoeachother.

  • 标签: X射线结晶学 二烃基二硫代磷酸盐 中心对称 2 晶体结构 O'-二异丙基二硫代磷酸盐
  • 简介:AsimplespectrophotometricassayofH2O2andglucoseusingAgnanoparticleshasbeencarriedout.RelyingonthesynergisticeffectofH2O2reductionandultraviolet(UV)irradiation,Agnanoparticleswithenhancedabsorptionsignalsweresynthesized.H2O2servedasareducingagentintheAgnanoparticlesformationinwhichAg+wasreducedtoAg0byO2àgeneratedviathedecompositionofH2O2inalkalinemedia.Ontheotherhand,photoreductionofAg+toAg0underUVirradiationsalsocontributedtothenanoparticlesformation.ThesynthesizednanoparticleswerecharacterizedbyTEM,XPS,andXRD.TheproposedmethodcoulddetermineH2O2withconcentrationsrangingfrom5.010à7to6.010à5mol/L.Thedetectionlimitwasestimatedtobe2.010à7mol/L.SincetheconversionofglucosetogluconicacidcatalyzedbyglucoseoxidasewascompaniedwiththeformationofH2O2,thesensingprotocolhasbeensuccessfullyutilizedforthedeterminationofglucoseinhumanbloodsamples.Theresultswereingoodagreementwiththosedeterminedbyalocalhospital.Thiscolorimetricsensorthusholdsgreatpromisesinclinicalapplications.

  • 标签: 银纳米粒子 葡萄糖利用 过氧化氢 H2O2 UV 分光光度测定法
  • 简介:ThecorrelationbetweenphasestructuresandsurfaceacidityofAl2O3supportscalcinedatdifferenttemperaturesandthecatalyticperformanceofNi/Al2O3catalystsintheproductionofsyntheticnaturalgas(SNG)viaCOmethanationwassystematicallyinvestigated.Aseriesof10wt%NiO/Al2O3catalystswerepreparedbytheconventionalimpregnationmethod,andthephasestructuresandsurfaceacidityofAl2O3supportswereadjustedbycalciningthecommercialγ-Al2O3atdifferenttemperatures(600–1200C).COmethanationreactionwascarriedoutinthetemperaturerangeof300–600Catdifferentweighthourlyspacevelocities(WHSV=30000and120000mL·g-1h-1)andpressures(0.1and3.0MPa).ItwasfoundthathighcalcinationtemperaturenotonlyledtothegrowthinNiparticlesize,butalsoweakenedtheinteractionbetweenNinanoparticlesandAl2O3supportsduetotherapiddecreaseofthespecificsurfaceareaandacidityofAl2O3supports.Interestingly,NicatalystssupportedonAl2O3calcinedat1200C(Ni/Al2O3-1200)exhibitedthebestcatalyticactivityforCOmethanationunderdifferentreactionconditions.LifetimereactiontestsalsoindicatedthatNi/Al2O3-1200wasthemostactiveandstablecatalystcomparedwiththeotherthreecatalysts,whosesupportswerecalcinedatlowertemperatures(600,800and1000C).ThesefindingswouldthereforebehelpfultodevelopNi/Al2O3methanationcatalystforSNGproduction.

  • 标签: Ni catalyst ALUMINA CO METHANATION synthetic