简介:Thispaperreportstwolanthanidecomplexesofformula(C9H7)Ln(C8H8)·(THF)2whereLnisProrNd,C9H7isindenyl,andC8H8iscyclooctatetraene(COT).ThecomplexeswerepreparedbythereactionofLnCl3withK(C9H7)andK2(C8H8)inTHF.(C9H7)Pr(C8H8)·(THF)2crystallizesinTHFat-15℃inthemonoclinicspacegroupP21:withunitcelldimensionsa=8.446(0),b=10.083(2),c=13.407(3),β=105.48(1)°,V=1100.43(35)3,Dc=1.52g/cm3andZ=2.ThefinalRvalueis0.033,Rwvalueis0.030,respectively.In(C9H7)Pr(C8H8)·(THF)2afive-memberedringcentroidofC9H7,theC8H8ringcentroidandthetwooxygenatomsfromthetwoTHFmoleculesformadistortedtetrahedralgeometryaroundthemetal.
简介:ThereactionofNdCl3withlithiummethylnaphthalenein1:2moleratioinTHFgeneratesblackpowder.Thepowderreactswithcyclooctatetraene(COT)inTHFtoformthetitlecomplex.[Li(THF)4Nd(C8H8)2]·2THFcrystallizesinthemonoclinicspacegroupP2/cwithunit-celldimensionsa=1.7858(7)nm,h=1.3243(4)nm,c=1.8086(6)nm.β=106.52(4)°,V=4.10nm3andDc=1.268g/cm3forZ=4.F(000)=1660,R=0.0774,Rn=0.0733.Thecomplexconsistsofdiscreteion-pairandtwoTHFmoleculesadduct.Intheanion,theneodymiumatomiscoordinatedbytwoCOTrings.ThestructureofthecationshowsthatthelithiumatomisattachedwithTHFmoleculesonly.
简介:Catalyticcombustionofpropane-airmixturewasinvestigated.Platinumcatalystsoveraflatstainlesssteelwithγ-aluminawashcoatwereemployed.Theemployedburnerhasthreecatalystssetparalleltothemixtureflow,spacedatanintervalof5,10and15mm.Bothexperimentandnumericalsimulationweremadeatinlettemperatureof553K,inletvelocityof3to7m/sandequivalenceratioof0.3to0.5.Inthenumericalsimulation,two-dimensional,steadystatemodelwasdevelopedtocalculatethetemperatureandspeciesconcentrationingas-phase.Inthismodel.chemicalreactiononthecatalystsurfaceandthatinthegasphasewereassumedtooccurinthree-steps.Thenumericalresultsshowgoodagreementwithexperimentalresults.Itwasfoundthatthepropertiesofthecatalyststronglyaffectthecatalystsurfacetemperature.Especially,thethermalconductivityofcatalysthasagreateffect,whiletheemissivityofcatalysthaslesseffect.
简介:ACupro-8-thioquinolinecoordinationpolymer,[Cu^I(C9H6NS)]n,wassynthesizedbymethano-thermalreactionofCuCland8,8′-dithiodiquinoline(dtdq)inamolarratioof2:1at160℃for7d.X-Raysinglecrystalstructuredeterminationrevealedtheformationofaone-dimensionalstructurebelongingtomonocliniccrystalsystem,spacegroupP21/cwithcellparametersa=0.8043(1)nm,b=1.8949(3)nm,c=1.1048(1)nm,β=110.109(4)°,V=1.5810(4)nm^3andZ=4,Thecrystalwasfoundtobestableuptoapproximately300℃bythermalanalysisandhaveanenergygap(Eg)of2.0eVexhibitedbyUV-Vis-NIRreflectancespectrum.
简介:AlaminarpremixedPropane/Airflamewithafuelequivalenceratioof2.1wasemployedforanalysisofsootparticles.Zeroth-orderIognormaldistributions(ZOLD)wereusedintheanalysisofexperimentaldistributionphenomenaatdifferentresidencetimesduringsootformationintheflame.Rayleigh'stheoryandMie'sscatteringtheorywerecombinedwithagglomerateanalysisusingscatteringandextinctiondatatodeterminethefollowingsootcharacteristics:agglomerateparameters,volumetricfractions,massflowratesandsurfacegrowthrate.Sootdensitymeasurementswerecarriedouttodeterminedensityvariationsatdifferentstagesofgrowth.Themeasuredresultsshowthatmetricfractionandmassflowrateindicatethatthesurfacegrowthrateofsootparticlesexceedstheoxidationratesintheflamestudied.Thedataobtainedinthisworkwouldbeusedtostudysootoxidationrateunderflamingcondition.
简介:Tris)(η5-cyclopentadienyl-μ-carbonyl-iron)-μ3-nitrosylclusterwasobtainedfromthereactionofcyclopentadienyldicarbonylirondimerwithnitrogenmonoxideinxylene.Theclusterwascharacterizedbyelementalanalyses,IR,MSand1HNMR.Thecrystalstructureof[(η5-C5H5)(μ-CO)Fe]3(μ3-NO).C4H8OwasdeterminedbyX-raydiffractionanalysis.ItcrystallizesintheorthorhombicspacegroupPnma,a=9.053(2),6=10.545(2),c=22.525(4)A,V=2150.3(7)A3,Z=4,Dc=1.68g.cm-3;structuresolutionandrefinementbasedon1141reflectionswithI>3.0(I)(MoKa,A=0.71073A)convergedatR=0.0540.Theinfraredabsorptionbandat1325cm-1oftheμ3-NOinthecluster,whichisredshifted,showsthatμ3-NOisactivated.
简介:ColdForcenturies,thebody’sbloodhasbeenmixedcloselywithemotions.Peoplewhoshownohumanemotionsorfeelings,forexample,aresaidtobecold-blooded.Cold-bloodedpeopleactincruelways.Theymaydobrutalthingstoothersandnotbyaccident,forexample,anewspapersaysthepolicearesearchingforacold-bloodedkiller.Thekillermurderedsome-onenotinselfdefenceorbecausehewasreactingtoangerorfear.Heseemedtokillfornoreason,andwithnoemotion,asiftakingsomeone’slifemeantnothing."Cold"canaffectotherpartsofthe
简介:1.在一根长木棍上有两种刻度线,第一种刻度线将木棍分成10等份,第二种刻度线将木棍分成优等份,如果沿每条刻度线将木棍锯断,木棍总共被锯成20段.求m的值.
简介:卢嘉锡名誉主席八十五华诞暨荣获何梁何利奖庆祝会在京举行(本刊讯)金秋十月,卢嘉锡名誉主席可谓双喜临门:10月21日,在1999年度何梁何利基金颁奖大会上,荣获奖金100万港币的“科学与技术成就奖”;10月25日,由农工党中央主办的“卢嘉锡名誉主席八十五华诞暨荣获何梁何利奖庆祝会”在京举行。中央统战部常务副部长刘延东及有关部门负责人常荣军、陈征然、韦顺和,农工党中央副主席姚峻、章师明、宋金升、李蒙出席了会议。农工党中央副主席姚峻受蒋正华主席委托,向德高望重的卢老荣获何梁何利奖表示热烈的祝贺,向卢嘉锡主席八十五华诞表示由衷的祝愿,祝卢老健康长寿。(农工党中央信息教育处)福建省各届祝贺卢嘉锡名誉主席