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500 个结果
  • 简介:用EXAFS方法研究了重金属Zn(Ⅱ)在δ-MnO2上吸附的微观结构及吸附机制。在pH5.50,0.1M硝酸钠介质中,吸附-解吸实验表明Zn(Ⅱ)在δ-MnO2上的吸附可逆性很高.EXAFS结果表明,δ-MnO2表面上吸附态Zn2+以六配位的水合离子八面体形式存在。八面体的水合Zn^2+离子与δ-MnO2的结构单元MnO6八面体通过共用O原子结合,形成角-角结合的弱吸附.Zn-O平均原子间距为2.071A,Zn-Mn平均原子间距为3.528A。同一条等温线上随着吸附量增加,角-角结合的弱吸附形式基本上没有变化。Zn(Ⅱ)在δ-MnO2上较高的吸附可逆性是由于吸附态Zn(Ⅱ)与δ-MnO2以弱吸附的角-角形式结合所导致的。

  • 标签: Zn/δ-MnO2吸附结构 EXAFS 重金属污染 硝酸钠 可逆性 解吸
  • 简介:从中学教材中得知,对于任意复数z1,z2,…,zn都有|z1|+|z2|+…+|zn|≥|z1+z2+…+zn|.运用这个不等式,求复杂函数的最小值,方法简捷,但是z1,z2,…,zn满足什么条件,|z1|+|z2|+…+|zn|才取得最小值呢?下面用代数形式给出这个条件.

  • 标签: 最小值 函数最小值 中学教材 代数形式 复杂函数 复数的模
  • 简介:Thecorrosionbehaviorandanti-corrosionmechanismoftheZn-Ni-Al2O3compositecoatingwereinvestigatedbySEM,EDSandXPS.TheresultsindicatethatthecorrosiontypeoftheZn-Ni-Al2O3coatingsinneutral5wt.%NaClsolutionisuniformcorrosion.ThepresenceofcompactanduniformlydispersednanoaluminaparticlessubstantiallyinhibitsthecorrosionofZn-Ni-Al2O3compositecoatings.Intheinitialcorrosionstage,thecorrosiveproductsofZn-NimatrixformacompactZnCl2·4Zn(OH)2layer.Withthedevelopmentofcorrosion,somenanoaluminaparticlesareembeddedandformaNienrichmentlayer.InNienrichmentlayer,NipresentsasNiandNiO.

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  • 简介:提出问题:Zn+H2SO4的反应研究问题:(读者怎样研究?想后再看)研究问题程序:学生独立研究——小组研究——班集体研究原理研究:若是少量锌与过量浓硫酸反应:

  • 标签: “Zn+H2SO4” 研究性学习 高中 化学 原理
  • 简介:Thesolidaddofthefirstprotonatedzincoborophosphate,(H3O)Zn(H2O)2BP2O8·H2O(1),wassoventothermallysyn-thesizedbythereactionofZn(NO3)2·6H2OandH3BO3withH3PO4inamixedsolvent,andstructurallycharacterizedbysingle-ystalX-raydiffractionanalysis.ItcrystallizesinthehexagonalP6122,a=0.9604(4)nm,c=1.5297(6)nm,V=1.2218(8)nm^3,Dc=2.921g/cm^3,Z=6,F(000)=1080,μ=3.495mm^-1.Thestmchwefeaturesthatthetetrahedra-te-trahedrahdlcesinterconnectedbyoctahedraandstronghydro-gembondinteractionsformathree-dimensionalframework.Theprotonatedwatermoleculesarelocatedatuniquepositions.othercharacterizationsbyIRandthermalanalysisarealsode-scribed.

  • 标签: (H3O)Zn(H2O)2BP2O8·H2O 合成 结构 质子化 螺旋带状物 硼磷酸锌化合物
  • 简介:Inapreviousgreenhouseexperiment,weshowedthattherewasaninteractionbetweencuandZn,whichaffectedgrowthandmetaluptakebyyoungbarleyplantsgrownonsoiltowhichCd,Cu,Pb,andZnhadbeenadded.Wesuggestedthattheunderlyingmechanismwasthecontroloftheamountofplant-availableZnbycompetitiveadsorptionbetweenCuandZn,Inordertotestthishypothesis,theadsorptionofZnalone,andinthepresenceofaddedCd,CuandPb,hasbeenmeasuredusingthesamesoil.Followingadsorption,theextractabilityoftheZninCaCl2solutionwasmeasured.TheadsorptionisothermsshowedthatoftheaddedmetalsonlyCuhadalargeeffectonZnadsorption.TheeffectofCuwastoreduceZnadsoptionandtoincreasetheamountofCaCl2-extractable(i.e.plant-available)Zn,inagreementwiththeconclusionsfromthegreenhouseexperiment.ThemagnitudeoftheeffectofCuonplant-avalilableZnwassimilarinbothexperiments.

  • 标签: 金属污染土壤 植物 锌吸收 可利用性 Zn-Cu相互作用
  • 简介:采用流动注射分析技术建立了Zn^2+的FIA分析方法.谊分析方法可行、简便。其数据可靠,具有较好的选择性和重现性.样品测定频率大于30个/h;在1.0~5.0mg/L范围内呈良好的线性关系,γ=0.9999;回收率大于98%.实现了烟幕剂成烟产物中Zn^2+的快速定量测定.

  • 标签: 流动注射分析 ZN^2+ 烟幕剂 成烟产物
  • 简介:ThecrystalgrowthprocessofZn(Leu)SO4·0.5H2OformwaterandacetonewasinvestigatedusingaCalvetmicrocalorimeter.Theheatandtherateofheatproductionduringthecrystalgrowthprocessat293.15K,295.15K,298.15Kand300.15Kweremensured.Onthebasisofexperimentalandcalculatedresults,therateconstantandthekineticparameters(theactivationenergies,thepre-exponential)duringthecrystalgrowthprocesswereobtained.Theresultsshowthatthecrystalgrowthprocesswereobtainged.TheresultsshowthatthecrystalgrowthprocessaccordedwiththeBurton-Cabrera-Franddislocationtheory.

  • 标签: 结晶动力学 Zn(Leu)SO4·0.5H2O 晶体生长 丙酮 亮氨酸
  • 简介:TheinteractionbetweenZn-AleutecticalloyandAl2O3p/6061Alcompositesinthevacuumfurnacewasinvestigated.Greatattentionhasbeenpaidtotheelementsdiffusion,themicrostructureandformationoftheinterfacebetweenZn-AIeutecticalloyandAl2O3p/6061Alcomposites.ExperimentalresultsshowthatZn-AleutecticalloyhasagoodwettingabilitytoAl2O3p/6061Alcompositesandthewettingangledecreaseswithincreasingthetemperatureinvacuum.Aftertheinteraction,aninteractionlayerformsbetweenZn-AIalloyandAl2O3p/6061Alcomposites.Thephasesintheinteractionlayermainlyconsistofα-Al(Zn),Al2O3andCuZn5resultedfromthediffusionofelementsfromtheZn-Alalloy.SeveralporositiesdistributeintheregionneartheinterfaceoftheZn-Alalloy/interactionlayer.TheamountofshrinkagevoidsintheinteractinglayerisrelevanttothepenetrationofZnelementintoAl2O3p/6061Alcompositeswhichisafunctionoftemperature.SoitisnecessarytolowerheatingtemperatureinordertolimittheZnpenetration.

  • 标签: 锌铝共晶合金 Al2O3p/6061Al化合物 湿润 界面微结构 焊接技术
  • 简介:StudyontheavoidanceresponseofPenaeuschinensistoheavymetals(Pb,Cr,Zn)andheavymetalmixtures(Pb-Cr,Pb-Zn)iscarredoutusingaY-modelavoidanceapparatus.Theconcentrationscalculatedtoinduce50%avoidanceratebyPenaeuschinensisare11.4,33.2and238.1mg/LforPb,CrandZn,respectively.MixturesofPb-CrandPb-ZnproduceadditiveeffectintheavoidancetestusingPenaeuschinesis.ButwhenthemixedPb-Znsolutionhas0.5toxicunitPband0.5toxicunitZn,themixtureseemstohavesynergisticeffect.

  • 标签: PENAEUS chinensis heavy metal AVOIDANCE reaction
  • 简介:Soilswerecollectedfrom2-year(2-y)and3-year(3-y)oldred-pineseedlingplotsintwotreenurseries,HaywardinthenorthandWilsoninthesouthwesternpartofWisconsinStaterespectively,andequilibratedwith0.01MCa(NO3)2)forsoilsolutionZnandMn(solu-ZnandMn),andwith0.01MCa(NO3)2+0.005MEDTAforsoilabsorbedZnandMn(ad-ZnandMn).BufferingcapacityofsoilZnandMn(b-ZnandMn)wasobtainedfromtheratioofad-ZnandMntothesolu-ZnandMn.Theconcernedtracesinpineseedlingneedles(ndls),stems(sts)androots(rts)weresimultaneouslymeasured.Theresultsobtainedshowthat:About60%ofsolu-andad-Znrangedfrom0.2to0.4andfrom1to2μg/gsoilrespectively.About70%ofb-Znwaswithin3-10.Thehighestcontentofsolu-Zncomparedwiththelowestshowedadiscrepanceofmorethan10-fold.ThetwoformsofsoilZnwerecommonlyhigherinWilsonthaninHaywarkNursery.About80%ofsolu-,ad-andb-Mnwerewithin3-10,5-5.8μg/gsoiland1-2respectively.Influenceoflowbufferingcapacityonsolu-ZnandMnwasabout20timesstrongerthanthatofthehigh.TheE-value,aratioofaccumulatedZnandMninneedlestothoseinthesoilsolution,isprovedtobe:E-Zn>E-Mn;E-sts>E-ndlsorE-rts;andE-2y>E-3y.Curvilinearand/orlinearcorrelationsbetweensoilsolu-,ad-andb-ZnandMnandndls-,sts-,rts-ZnandMnwereatverysignificantorsignificantlevels.Forpredictingndls-ZnandMn,tworealizableandsimplemodelsfromtworegressionequationswereestablishedthroughtheselectionofrelatedparametersanddependentvariables.BinaryregressionanalysisbasicallyeliminatedtheinfluenceofsoilpHonthepredictionofZnandMninneedles.SoilpHwasthusthoughttobeexcludedfromthemodel.

  • 标签: 苗圃 红松苗 土壤 预测模式
  • 简介:Thesuper-largePb-ZndepositatFankouisverycomplexinmetallogenicmechanism.Syngeneticbrinesedimentation,hotsubmarinespringeruption-accumulation,syngeneticsedimentation-vadosebrinereplacementhadbeensupposedasthegeneticmodelsbefore.Underthesemodels,syngeneticmineralizationshouldbedominantinoreformation.However,aseriesofgeologicalandgeochemicalpropertiesinvestigatedbyauthorsofthispaperarecontrarytothesemodels.Therefore,theauthorsheresuggestthatthisdepositisatypicalpolygeneticcompoundoredepositwhichsharethepropertiesofmultistagesofgeotectonicevolution,multifactorsofmineralizationcontrol,multisystemofmaterialderivationofmineralization,multimodesofmineralizationandmultitypesofgenesis.

  • 标签: GENESIS ORE DEPOSIT the Fankou ORE
  • 简介:Inordertorealizetheco-firingwithAg/Pdelectrodesinmultilayerdevices,Pb(Zn1/3Nb2/3)1-,-yZrxTiyO3(0.25<x<0.35,0.25<y<0.35)piezoelectricceramics(hereafterdesignatedPZN-PZT)modifiedbyLa2O3hasbeenpreparedbyconventionaltechniquewithsinteringtemperaturefrom1100℃to1140℃.X-raydiffractionpatternsdemonstratedthatpureperovskitephasewasobtained.Secondaryelectronimage(SEI)showedthatcrystallinegrainsinceramicswerewellgrown.d33ofmanufacturedsamplewasashighas560×10-12C/N.kpwasabout0.61andtgδabout30×10-3.TheexistenceofliquidphaseexaminedbyelectrondiffractioninPZN-PZTsampleisbeneficialtosinteringoftheceramic.

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  • 简介:这篇论文在Guiyang的地表的土壤描述象Cu和Zn那样的重金属污染物质的环境联盟者geochemical特征,GuizhouProvince的首都的城市。在土壤和geochemical标准的重金属的基线集中被建立了在环境上区分自然或人工的影响。用统计上分析方法,我们在Guiyang(18.8mg/kg)建立了Cu的基线,土壤(超过68.4mg/kg)可以承受Cu污染。Zn的数据是46。3mg/kg并且112。0mg/kg。Geoaccumulation指数分析显示有sufferednon污染到的地表的土壤为38%,38%,和22%的Cu帐户为中间污染中间污染,并且仅仅对严重污染中间污染的2%between。承受了Zn的非污染tomid污染的地表的土壤占41%,50%,和7%为中间污染,并且仅仅2%betweenmid污染到严重污染。Cu污染的最大的度在Guiyang的surficials油是5.09。没为53承受Cu污染报道的地表的土壤。2%。Cu的全部的污染度是稍微超过零。Guiyang的地表的土壤因此承受了slightCu污染。Zn污染度的最大的价值是2。85在地表的土壤ofGuiyang。77。8%地表的土壤还没承受了任何Zn污染。Zn的全部的污染度是不到零。在Guiyang的地表的土壤因此从Zn的污染是免费的。

  • 标签: 基线 污染物 土壤 贵阳
  • 简介:由陕西宝光真空电器股份有限公司生产的ZN39-40.5系列高压真空断路器是三相交流50HZ、额定电压40.5kV户内高压配电装置。该产品可与JYN1-35/GBC-35型开关柜配套,适用于发电厂、变电站等输配电系统的控制与保护,尤其适用于频繁操作的场所。该产品为手车式,结构合理、维护简便、使用安全可靠。

  • 标签: 高压真空断路器 三相交流 陕西宝光真空电器股份有限公司 开关柜 额定电压 变电站
  • 简介:ZN-1阻尼材料是以丁基橡胶为基与酚醛树脂共混而成的粘弹性阻尼材料,具有损耗系数高、使用温度区域宽、转变峰的峰值温度在室温附近、抗老化性能优异等特点,在阻尼夹层结构中有着广泛的应用。

  • 标签: ZN-1阻尼材料 辐照实验 辐射降解反应 损耗系数
  • 简介:Humanextracellularsuperoxidedismutase(hEC-SOD)isasecretedtetramericproteininvolvedintheprotectionofahumanbodyfromoxygenfreeradicals.Itsthree-dimensionalstructurehasnotbeenconfirmed,hEC-SODcouldn′tbeexpressedinE.coll.Weconstructedahybridenzyme,whichcomprisestheNterminalandC-terminaldomainsfromhEC-SOD,fusedittohumanCu,Zn-SOD.ThehybridenzymeisexpressedsuccessfullyinE.coli.Further,weanalyzedtheexpressionofhEC-SODinE.colibymRNAdifferentialdisplaying.

  • 标签: 细胞外超氧化物歧化酶 混合酶 结构