学科分类
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8 个结果
  • 简介:Thepotentialenergycurves(PECs)ofBOmolecule,includingΣ+andΠsymmetrieswithdoubletspinmultiplicities,areobtainedemployingmulti-referenceconfigurationinteraction(MRCI)methodandDunning'scorrelationconsistentbasissets.Theanalyticalpotentialenergyfunctions(APEFs)arefittedusingtheMurrell-Sorbie(MS)functionandtheleastsquaremethod.BasedonthePECs,thespectroscopicconstantsofthestateshavebeendeterminedandcomparedwiththetheoreticalandexperimentalresultsavailabletoaffirmtheaccuracyandliabilityofthecalculations.Theroot-mean-square(RMS)errorsbetweenthefittedresultsandtheabinitiovaluesaretoolittleincomparisonwiththechemicalaccuracy(349.755cm-1).ItisshownthatthepresentAPEFsareaccurateandcandisplaytheinteractionbetweentheatomswell.ThepresentAPEFscanbeusedtoconstructmorecomplicatedAPEFordosomedynamicinvestigations.

  • 标签: 组态相互作用 分子势能函数 势能曲线 分析势能函数 最小二乘法 光谱常数
  • 简介:Manyapproachesforhigh-resolutionimagereconstructionhavebeenproposedinsomeliteratures.Oneofthemostcommonlywaysistoreconstructahigh-resolutionimagefromanumberofrotatedandtranslatedimageswithlowresolution.Inthisprocess,theexposuredifferenceamongoriginalimageswilldecreasethequalityofthereconstructedimage.Inordertoremovetheinfluenceoftheexposuredifference,alightenergymatchingmethodisproposedinthispaper.Thetheoreticalanalysisisillustratedindetails.Experimentalresultsshowthatthetheoreticalanalysisiscorrectandtheproposedmethodisvalid.

  • 标签: 高分辨率图像重建 图像处理 光能匹配法 数字成像技术 CCD 电荷耦合器件
  • 简介:Consideringtheperturbation,theresultsoftheoreticalcalculationoffiveRydbergseriesenergylevels6s~2ns~2S_(1/2)(n=7-20),6s~2nd~2D_(3/2)(n=6-20),6~s2nd~2D_(5/2)(n=6-20),6s~2np~2p_(1/2)~0(n=7-20),and6s~2np~2p_(3/2)~0(n=7-20)forT11arepresentedusingtheweakestboundelectronpotentialmodel(WBEPM)theory.Furthermore,theradiativelifetimesofthisfiveseriesarealsocalculated.Thecalculatedvaluesofenergylevelsandlifetimesareingoodagreementwiththeexperimentalresults.

  • 标签: 放射周期 电子 电势 物理学 TlI
  • 简介:EnergystorageandheatdepositioninCr,Yb,Erco-dopedphosphateglasswerereported.Amodelbasedonrateequationswasusedtodeterminetheenergystoragefromthefree-oscillatingoutputenergycharacteristics.Theheatdepositionwascalculatedbymeasuringthetemperatureriseoftheglassrod.TheresultsprovidedimportantinformationfortheglassoperatinginQ-switchedmode,andalsoforcalculatingthetemperatureprofilesandcoolingrequirementsoftheglassundersingleshotandrepetitivepulsedconditions.

  • 标签: 能量储存 热沉积 磷酸盐玻璃 脉冲情形 冷却需求 激光技术
  • 简介:Intense-laser-inducedabove-thresholdionizationofaboundelectronintocontinuumstateswithlowenergyisinvestigatedinthecontextofthestrong-fieldapproximationthatallowsforoneactofrescatteringoftherevisitingelectron.Thequantumorbitsforforwardandbackwardscatteringareevaluatedandgeneralizedtoarbitraryscatteringangles.Thevelocitymapoftheliberatedelectronexhibitsthewell-knownlow-energystructureaswellasotherfeaturesoffthepolarizationaxis.

  • 标签: 轨道理论 阈上电离 量子 离轴 低能 束缚电子
  • 简介:InthisLetter,wefocusonthetheoreticalanalysisoftherelativisticenergyandangulardistributionsoftheejectedphotoelectronsduringtherelativistictunnelionizationofatomsbyintense,circularlypolarizedlight.Wemakeasmallmodificationofthegeneralanalyticalexpressionsforthesedistributions.Theroleoftheinitialmomentum,theponderomotivepotential,andtheStarkshiftareconsidered.Wealsopresentthemaximalangleofelectronemission.

  • 标签: 相对论能量 圆偏振光 能量分布 原子 激光场 低频
  • 简介:Enhanced2.7μmemissionisobtainedinEr3+/Tm3+andEr3+/Ho3+codopedZBYAglasses.Absorptionandemissionspectraaretestedtocharacterizethe2.7μmemissionpropertiesofEr3+/Tm3+andEr3+/Ho3+dopedZBYAglassesandareasonableenergytransfermechanismof2.7μmemissionbetweenEr3+andTm3+Ho3+)ionisproposed.CodopingofTm3+orHo3+significantlyreducesthelifetimeoftheEr3+:4I13/2levelduetotheenergytransferofEr3+:4I13/2→Tm3+:3F4orEr3+:4I13/2→Ho3+:5I7.Thus,the2.7μmemissionisstrengthenedandthe1.5μmemissionisdecreasedaccordinglyespeciallyintheEr3+/Tm3+sample.TheupconversioneffectsbetweentheEr3+/Tm3+andEr3+/Ho3+dopedZBYAglassesaredifferentattributetothedifferentenergytransferefficiencies.Bothofthetwocodopedsamplespossessnearlyequallargeemissioncrosssection(16.6×10-21cm-2)around2.7μm.TheresultsindicatethatthisEr3+/Tm3+orEr3+/Ho3+dopedZBYAglasshaspotentialapplicationsin2.7μmlaser.

  • 标签: 能量转移效率 能量传递机制 氟化物玻璃 发射光谱 共掺杂
  • 简介:Wereportonthecontinuous-wave(CW)andpassiveQ-switchingperformanceofaminiatureYb:Y3Ga5O12crystallaserendpumpedbya935-nmdiodelaser.AmaximumCWoutputpowerof12.03Wisproducedwithanoptical-to-opticalefficiencyof54.4%,whiletheslopeefficiencyis63%.InthepassivelyQ-switchedoperationachievedwithaCr4+:YAGsaturableabsorber,anaverageoutputpowerof2.12Wat1025.2nmisgeneratedwithaslopeefficiencyof46%atapulserepetitionrateof5.0kHz.Thepulse’senergy,duration,andpeakpowerare424μJ,2.3ns,and184.3kW,respectively.

  • 标签: 高功率连续波 晶体激光器 被动调Q 微型 最大输出功率 激光二极管抽运