简介:NewrareearthvanadatesYSrQ-xCaxV3O9-y(x=0.0,0.67,1.0,1.33and2.0)havebeensynthesizedbyanewsimplemethod.X-raypowderdiffractionresultsshowthattheyaremono-phase.Theybelongtoorthorhombicstructureandtheirlatticeconstantsarecalculated.TheresultsofweightgainsinTGcurvesshowthatthelowervalentvanadiumisoxidizedtohighervalentstateathighertemperature.Theoxygencontentsofnewcompoundsarecalculatedfromtheweightgains.BothV3+andV4+coexistinYSr2-xCaxV3O9-y.Thesecompoundsexhibitlowelectricresistivityatroomtemperature.
简介:为它的高氧化抵抗,钇硅酸盐是为在在1600°C上面的温度的carbon-fiber-reinforcedcomposites的保护的涂层的一个重要候选人。一个新奇方法,由一起沉淀组成,弄干水花,热处理和plasma-densification,被开发准备Y2SiO5粉末为热喷洒。作文,形态学和综合Y2SiO5粉末的流动能力被XRD,SEM和霍尔流量计分别地调查。结果证明综合Y2SiO5粉末与高纯净是将近球形的。分别地,Y2SiO5粉末的明显的密度和流动能力是1.87g/cm3和37s/50g它为大气的血浆喷洒导致多达80%的高免职效率。
简介:ForquadraticnumberfieldsF=Q(√2pl…pt-1)withprimespj≡1mod8,theauthorsstudytheclassnumberandthenormofthefundamentalunitofF.TheresultsgeneralizenicelywhathasbeenfamiliarforthefieldsQ(√2p)withaprimep≡1mod8,includingdensitystatements.Andtheresultsarestatedintermsofthequadraticformx2+32y2andillustratedintermsofgraphs.
简介:Inthispaper,theoutputquantumcorrelationsofthreefieldsinteractingwithinvertedY-typeatomsinsideathree-modecavityareinvestigated.Bynumericallycalculatingthestationarynoisespectraofthefields,weshowthatitispossibletogeneratethegenuinetripartitecontinuousvariableentanglementoutsidethecavitybycoherentlypreparingtheatomsinasuperpositionoftheupperexcitedstateandtwogroundstatesinitially.Ournumericalresultsdemonstratethatbothzerofrequencyentanglementandsidebandfrequencyentanglementcanbeobtainedunderdifferentinitialcoherentconditions.Inaddition,weinvestigatethethermalfluctuationeffectsonthequantumentanglement.Itisfoundoutthattheentanglementoccurringinahighfrequencyregimeismorerobustagainstthermalnoisethanthezerofrequencyentanglement,whichmaybeusefulforquantumcommunication.
简介:采用水热方法合成一种新型钼-氧簇化合物Ni(en)3MoO4,并通过X射线单晶结构分析、红外光谱分析、元素分析、差热热重分析对该化合物进行了表征.结构分析数据表明:该化合物属三方晶系,P-31c空间群,晶胞参数a=0.9226(13)nm,b=0.9226(13)nm,c=0.9959(2)cm,α=90°,β=90°,γ=120°,V=0.7342(2)nm3,Z=2,Dc=1.805mg/m3,μ=2.153mm-1,F(000)=408,R=00553,Rw=0.1732;该化合物是分立结构,是由MoO4四面体簇和Ni(en)3八面体簇形成,其中MoO4四面体簇和Ni(en)3八面体簇交替排列,存在较强的氢键作用,结构中分立的手性配合物Ni(en)3的两种对映体构象以MoO4簇为中心对称排布.
简介:为了满足高精度相机在外场环境下的检测要求,采用碳化硅光学材料制作反射镜,碳纤/环氧树脂基复合材料制作遮光筒,设计了一套重量轻、自身精度高、温度稳定性好的离轴平行光管。在二者线胀系数保持二倍关系的情况下,在一定温变范围内保持精度的稳定性。经检测,口径为400mm,焦距为8m的离轴平行光管的温变为(20±10)℃,系统波像差为1/5λ(P-V值,λ=632.8nm)和1/27λ(RMS值),达到了设计要求,能够在外场环境下使用。
简介:TheelectronicpropertiesandtopologicalphasesofThXY(X=Pb,Au,Pt,PdandY=Sb,Bi,Sn)compoundsinthepresenceofspin–orbitcoupling,usingdensityfunctionaltheoryareinvestigated.TheThPtSncompoundisstableintheferromagneticphaseandtheotherThXYcompoundsarestableinnonmagneticphases.Bandstructuresofthesecompoundsintopologicalphases(insulatorormetal)andnormalphaseswithingeneralizedgradientapproximation(GGA)andEngel–Voskogeneralizedgradientapproximation(GGAEV)arecompared.TheThPtSn,ThPtBi,ThPtSb,ThPdBi,andThAuBicompoundshavetopologicalphasesandtheotherThXYcompoundshavenormalphases.Bandinversionstrengthsandtopologicalphasesofthesecompoundsatdifferentpressurearestudied.Itisseenthatthebandinversionstrengthsofthesecompoundsaresensitivetopressureandforeachcompoundasecond-orderpolynomialfittedonthebandinversionstrengths–pressurecurves.
简介:Inthisstudy,factorsaffectingthecrystalstructureofflame-synthesizedY2O3:Euparticleswereinves-tigated,especiallytheparticlesizeeffectanditsinteractionwithEudopingconcentration.PolydisperseY2O3:Eu(sizerange200nmto3m)powdersampleswithEudopingconcentrationsfrom2.5mol%to25mol%weregeneratedineitherH2/airorH2/O2substrate-freeflames.ThecrystalstructureofthepowdersampleswasdeterminedbypowderX-raydiffraction(XRD),whichwascomplementedbypho-toluminescence(PL)measurements.Singleparticlecrystalstructurewasdeterminedbysingleparticleselectedareaelectrondiffraction(SAED),andforthefirsttime,byelectronbackscatterdiffraction(EBSD).H2/airflamesresultedincubicphaseY2O3:Euparticleswithhollowmorphologyandirregularshapes.ParticlesfromH2/O2flameshaddenseandsphericalmorphology;sampleswithlowerEudopingconcen-trationshadmixedcubic/monoclinicphases;sampleswiththehighestEudopingconcentrationswerephase-puremonoclinic.ForsamplesgeneratedfromH2/O2flames,aparticlesizeeffectanditsinteractionwithEudopingconcentrationwerefound:particlessmallerthanacriticaldiameterhadthemonoclinicphase,andthiscriticaldiameterincreasedwithincreasingEudopingconcentration.Thesefindingssug-gestthattheformationofmonoclinicY2O3:Euisinevitablewhenextremelyhotsubstrate-freeflamesareused,becausetypicalflame-synthesizedY2O3:Euparticlesizesarewellbelowthecriticaldiameter.However,itmaybepossibletogenerateparticleswithdense,sphericalmorphologyandthedesiredcubicstructurebyusingamoderatelyhighflametemperaturethatenablesfastsinteringwithoutmeltingtheparticles.
简介:Weinvestigatetheeffectsofspontaneouslygeneratedcoherence(SGC)onboththesteadyandtransientgainpropertiesinafour-levelinverted-Y-typeatomicsysteminthepresenceofaweakprobe,twostrongcoherentfields,andanincoherentpump.Forthesteadyprocess,wefindthattheinversionlessgainmainlyoriginsfromSGC.Inparticular,wecanmodulatetheinversionlessgainbychangingtherelativephasebetweenthetwofields.Moreover,theamplitudeofthegainpeakcanbeenhancedandtheadditionalgainpeakcanappearbychangingthedetuningofthecouplingfield.Asforthetransientprocess,thetransientgainpropertiescanalsobedramaticallyaffectedbytheSGC.ComparedtothecasewithoutSGC,thetransientgaincanbegreatlyenhancedwithcompletelyeliminatedtransientabsorptionbychoosingtheproperrelativephasebetweenthetwofields.Andtheinverted-Y-typesystemwithSGCcanbesimulatedinbothatomicandsemiconductorquantumwellsystemsavoidingtheconditionsofSGC.
简介:Ca3Y2(BO3)(4):Eu3+黄磷被高温度solid-statereaction方法综合,并且光特征被调查。排放光谱在相应于电的dipoleD-5(0)的613和621nm展出二强壮的红排出物在365nm刺激下面的Eu3+的-F-7(2)转变,原因是Eu3+代替forY3+在Ca3Y2(BO3)(4)的水晶结构占据非中心对称的位置。为613nm的Theexcitation光谱显示黄磷能是有效地激动的由紫外(紫外)(254nm,365nm和400nm)并且蓝色(470nm)光。Ca3Y2(BO3)(4)的排放紧张上的Eu3+集中的效果:Eu3+黄磷被测量,排放紧张与增加Eu3+集中增加的结果表演,然后减少。Ca3Y2(BO3)(4)的CIE颜色坐标:Eu3+黄磷是(0.639,0.357)在15mol%Eu3+。