简介:Theoxidationbehaviorofthreebiodieselsofdifferentorigins,viz.rapeseedoilderivedbiodiesel,soybeanoilderivedbiodieselandwasteoilbasedbiodiesel,weretestedonanoxidationtester.Thechemicalcompositionsofthebiodieselswerecharacterizedbygaschromatography.Thereafter,thestructuraltransformationoffattyacidmethylester(FAME)ofthebiodieselswasanalyzedbyaninfraredspectrometerandanultravioletabsorptionspectrometer.TheresultsdemonstratedthattheoxidationbehaviorofbiodieselsofdifferentoriginswascloselyrelatedtothecompositionanddistributionofFAMEs.HigherconcentrationofunsaturatedFAMEwithmulti-doublebondsexhibitedpooreroxidationresistance.Furthermore,cis-transisomerizationtransformationoccurredintheunsaturatedFAMEmoleculesandconjugateddouble-bondproducedduringtheoxidationprocessofbiodiesel.Greatercis-transvariationscorrespondedtodeeperoxidationdegree.ThehigherthecontentofunsaturatedFAMEwithmulti-doublebondsinabiodiesel,themoretheconjugateddoublebondswasformed.
简介:Inordertomeettheurgentneedforreducingolefincontentincrackednaphtha,theinfluenceoffeedstockcharacteristicsontheolefincontentwasdiscussed.ThedifferenttypesandperformanceofcatalystsdevelopedbyRIPPwereintroduced.Moreover,someeffectiveoperationapproachesincommercialunitswerepresentedtoserveasareferencetotherefinersforcatalystselection.
简介:TheSargentdividingwallcolumncanimplementfourproductsseparationsequencesinonecolumnbasedonFullyThermallyCoupledDistillationColumn.TheinitialdesignparametersarerequiredforthedesignoptimizationordynamiccontroloftheSargentdividingwallcolumn,andinordertomaketherigoroussimulationoftheSargentdividingwallcolumnmoreconducivetoconvergence,atencolumnmodelforcomplexSargentcolumnisestablishedinthispaper,andtheshortcutdesignmethodofthismodelisproposed.TheinternalminimumvaporandliquidflowareobtainedbytheUnderwoodequationsandthemassbalancemethodandtheV-minmethod.Theseparationfora4-componentshortcutmixtureofpentane,hexane,heptaneandoctanewasconsidered,whiletheinitialvaluesofdesignparametersandtheratioofvapor-liquiddistributionofeachcolumnwerecalculatedbyusingtheshortcutdesignmethodofatencolumnmodel.Andbycomparingtheshortcutcalculationswithrigoroussimulationresults,thepracticalityandreliabilityofshortcutcalculationswereverified.Thereasonforenergysavingwasanalyzedbasedonback-mixing.AvirtualheatexchangerisproposedtomaketheSargentdividingwallcolumnmoreenergyefficient.
简介:<正>TherulesofMIPreactionsforcatalyticcrackingofsulfurcompoundsanditsinfluenceonthesulfurcontentintheMIPnaphthawerestudied.ThemamfactorsinfluencingthesulfurcontentintheMIPnaphthawerethoughttobethesulfurcontentoffeedstockandwerecloselyrelatedwiththeolefincontentofnaphtha.TakingintoaccountthecharacteristicfeaturesofMIPprocess,themethodsforreducingthesulfurcontentintheMIPnaphthawerecomprisedofdecreasingthesulfurcontentoffeedstockbyhydrotreatinganddecreasingtheolefincontentofnaphthathroughpromotinghydrogentransferreactions.Therefore,theEuroⅣcleangasolinewithlowsulfurcontentandlowolefincontentcouldbeobtaineddirectlythroughtheMIPtechnology.