简介:Recently,aSm-GdcompoundheatinsulationceramicsmaterialcontractandanapplicationproductresearchcontractonREnano-catalystincatalyticburningenergysavingandenvironmentalprotectionweresignedbyTsinghuaUniversity,BaotouResearchInstituteofREandBaotouJingruiAdvancedMaterialsCo.,Ltd.Sm-GdcompoundheatinsulationceramicmaterialtechnologytransferprojectreliesontheexistingtechnologyofTsinghuaUniversityandutilizesabundantSm-GdbyproductofBaotoutoproducehighperforman...
简介:Thispaperreportsthekineticsofgrouptransferpolymerization(GTP)ofethylacrylate(EA)withzinciodidecatalystin1,2-dichloroethaneusingdimethylketenemethyltrimethylsilylacetal(MTS)asinitiatorat0℃andabove0℃.Theamountofcatalystusedwasstudied.Whenzinciodidecatalystusedismorethan10mol%relativetomonomer,therateofpolymerizationisproportionaltotheconcentrationofmonomer,whereaszinciodidecatalystusedislessthan10mol%ofthemonomer,therateofpolymerizationisindependentofthemonomerconcentration.IntheGTPofEAaninductionperiodwasobservedwhenthezinciodidecontentsarelessthanl0mol%.Ifthereactiontemperatureisover0℃,livingspeciesbecomeunstableanddiminish,leadingtoincompletemonomerconversion.Thereactioncurvesequationsareobtained.Thepolymershavenarrowmolecularweightdistributionswhicharenotchangedasdecreasingzinciodidecontents.Thepolydispersityisabout1.2.
简介:Accordingto350MWand600MWboilers,underoxygenfuelcondition,throughthereasonablecontroloftheprimaryandsecondaryflowandthecorrectoptionandrevisionofmathematicalmodel,thetemperaturedistribution,heatfluxdistributionandabsorptionheatdistribution,etc.wasobtainedwhichcomparedwiththoseunderaircondition.Throughcalculation,itisobtainedthattheprimaryandsecondaryflowmixedwell,goodtangentiallyfiredcombustioninfurnacewasformed,thetemperatureunderairconditionobviouslyhigherthanthetemperatureunderO26condition.Theadiabaticflametemperatureofwetcyclewasslightlyhigherthanthatofdrycycle.Themaximumheatloadappearedonthewaterwallaroundtheburnerarea.Theheatloadgraduallydecreasedalongthefurnaceheightupanddowninburnerarea.TheheatabsorptioncapacityofthefurnaceunderO26waslowerthanthatundertheaircondition.Theheatabsorptioncapacityoftheplatenheatingsurfaceunder026wasequaltothatunderaircondition.AndtheheatabsorbingcapacityofwaterwallunderO26wasabout7%~12%lessthanthatunderaircondition.
简介:Hydrodynamicandthermalcharacteristicsinapipewithsinusoidalwavysurfaceforsteadylaminarflowareinvestigatednumericallyinthepresentstudy.TheintegralformsofgoverningequationsarediscretizedusingcontrolvolumebasedFinitevolumemethodwithcollocatedvariablearrangement.SIMPLEalgorithmisusedandTDMAsolverisappliedforsolutionofsystemofequations.Apipeoflengthequalto4λisconsidered.Effectofsurfacewaviness,determinedbywavelength-amplituderatioλ/a(=L^*),onflowandthermalfieldispresented.ThesimulationworkhasbeencarriedoutforL^*=11.0-30.0foraReynoldsnumberrange50to2000.Resultsarepresentedintheformofstreamfunction,isothermallines,velocityandvorticityprofiles,changeofmeanfrictionfactor,variationinskinfriction,localandaverageNusseltnumberwithReynoldsnumber,wavenumber(n)andL^*.Foraparticulargeometry,lengthofcirculationzoneincreaseswithreynoldsnumberandapproachesalimitingvalueforhigherReynoldsnumber.Wallshearstressinthebulgepartofthechannelshowssmallervaluesthataffectlargely.therateofheattransferandNusseltnumbershowsminimumvaluesinthisregion.Thiscirculationzonedrasticallyincreaseswiththeincreaseofsurfacewavinessshowinghighmeanfrictionfactorperwavelength.MeanfrictionfactorinverselyvarieswithReynoldsnumber.Acorrelationisproposedforcalculatingfrictionfactorintheformf=C/(Re)^m,where‘C’and‘m’representstwopolynomialsofdegree4and2respectivelyandarefunctionofL^*.Higherwavinessofthesurfaceshowsthehigherheattransferratethanlowerwaviness.Heattransferratefallsalmostexponentiallyalongtheaxialdirectionwiththeincreaseofwavenumber.
简介:Bioluminescenceimagingisakindofemergingdetectiontechnologyatcellular,molecularandgeneticlevel.Themostpopularbioluminescenceimagingmodelisdiffusionapproximation(DA).However,becauseoftheill-posednessoftheDA-basedinverseproblemandtheinstabilityofreconstructionalgorithms,thelocationaccuracyofthereconstructedsourcesislow.Radiativetransferequation(RTE),whichconsidersthedirectionofthephotonmigrationandtheeffectofabsorptionandscatteringintissues,canaccuratelyexpressthetransmissionofbioluminescentphotonsthroughthetissues.Inthispaper,westudiedthebioluminescenceimagingbasedontheRTE.2Dsimulationswereperformed,andquantitativeevaluationwasgivenbytheabsolutesourcepositionerror,therelativesourceareaerrorandtheminimumboundingbox.TheresultsoftheexperimentshowedthattheimagingqualitybasedonRTEwasbetterthanthatonebasedonDA.
简介:IntroductionReductivedesulfurizationofthioamidestoaminesisoneofthemethodstoprepareaminesandisgenerallyachievedbya)Zninacid,b)sodiumoraluminumamal-gams,c)lithiumalumminiumhydride,d)RaneyNiande)electrolyticreduction.Thesemethodsarenotveryconvenienttobeoperatedandsomeneedmorecomplexinstrument.Hereisreportedthereductivedesulfurizationofthioamidestoaminesbycatalytichydrogentransferreaction(CHT).
简介:Roboticgasmetalarcwelding(GMAW)experimentswereconductedusinganERTOS-1electrodewithAr+10%CO_2shieldinggas,andtheweldingcurrentandarcvoltagesignalswerecollectedbyadataacquisitionsystem.TheboundariesbetweenglobulartransferandspraytransferintermsoftheweldingcurrentandarcvoltageweredeterminedaccordingtothewaveformofelectricsignalsandtheFouriertransformresultsofarcvoltage.Theoptimumweldingparametersforthetwotransfermodeswereobtained,whichlaidafoundationforthenumericalsimulationandcontrolofGMAWprocess.
简介:Theeffectofpressureoncombustionandheattransferisanalyzed.Theresearchisbasedonthebasiccombustionandheattransfertheorem.Acorrectionfortheheatcalculationmethodforpressurizedfurnaceismadeonthebasisofthenormalpressurecase.Thecorrectiontakestheeffectofpressurizingintoaccount.Theresultsshowthatthecorrectionisreasonableandthemethodisapplicabletocombustionandheattransferofthemarinesuperchargedboiler.
简介:Thermodynamicsisabranchofphysicswhichdealswiththeenergyflowintosystems.Therearetwoprincipallawsofthermodynamicswhicharedescribedonseparateslides.Thefirstlawofthermodynamicsrelatestothetransferofvariousformsofenergy,asheat,electric,magneticandchemicalenergiestoproducemechanicalwork.Thislawissometimestakenasthedefinitionofinternalenergy,andintroducesanadditionalstatevariable,enthalpy.Thefirstlawofthermodynamicsallowsformanypossiblestatesofasystemtoexist.Butexperienceindicatesthatthereisonlyonedirectionfornaturalprocessestoproceed.Thisleadstothesecondlawofthermodynamicsandthedefinitionofanotherstatevariablecalledentropy.Thesecondlawstipulatesthatthetotalentropyofasystemplusitsenvironmentcannotdecrease;itcanremainconstantforareversibleprocessbutmustalwaysincreaseforirreversibleornaturalprocesses.However,thelimitednumberofauthorsisconcernedbysystemsthatinvolvethetransferofelectricandmagneticenergiesinadditiontotheflowofheatinstudyingageneralthermodynamicsystem.Thesubmittedreviewfollowsanentropyapproachthatintroducescleardefinitionsoftheelectricchargeandmagneticfluxtoclarifyambiguitiesofthenaturesofsuchfluxesinliterature.So,thefirstandsecondlawsofthermodynamicsareappliedonthermo-electromagneticprocessesthatembracetheflowofmechanical,thermal,electric,andmagneticenergiesintosystemsthatinvolvefluidsorsolids.Accordingly,itwaspossibletomodifyredundanciesintheSIsystemofunits.Followingtheentropyapproach,itwaspossibletocasttheMaxwell’sequationsintoanenergyframeofreferencetoexplainthediscoveredTesla’swirelesspowertransmissionas“ElectricalRadiantEnergy”,andtheMITdiscoveryofwirelesspowertransmissionofthemagneticfluxas“EvanescentWaves”andtoclarifyfuzzinessofthedualityconfusionbyspecifyingauniquepropertyfortheelectronasaparticleandaun