简介：

简介：

简介：指向nano探查基于的一个可被细菌破坏的肿瘤poly(?-caprolactone)-b-poly(ethylene乙二醇)有磁性的回声成像(MRI)的块共聚物(PCL-b-PEG)micellefunctionalized对比代理人diethylenetriaminepentaacetic酸金轧(DTPA-Gd3+)在壳上并且一在红外线附近(NIR)在为磁性的回声和光双形式的成像的核心的染料是准备。纵的relaxivity(r1)PCL-b-PEGDTPA-Gd3+，micelle是13.4(mmol/L)?1s?1，DTPA-Gd3+的三褶层，并且比有类似的结构的许多聚合对比代理人的高。在里面忍受xenografted胸肿瘤的一只裸体老鼠的光成像显示出的vivo双形式的micelle优先地经由folic在肿瘤积累了由提高的渗透和保留(EPR)效果的调停酸的活跃指向和被动累积。结果显示dualmodalitymicelle是为癌症察觉和诊断的有希望的nano探查。

简介：Hydrotalcitecanactasaco-stabilizerwithothermainstabilizerforpoly(vinylchloride)(PVC).ThethermalstabilityandfluidpropertyofPVCfilledwithhydrotalcitesurface-treatedwithtitanateandsilanewerestudiedinthiswork.OrganicSnisamainstabilizerandhydrotalciteisastabilizingassistant.ThestabilityofthePVCresinmixedwithorganicSnandhydrotalciteisbetterthanthatofthePVCresinmixedwithorganicSnalone.ItisshownthatthePVCresinfilledwithhydrotalcitepossessesabetterstaticanddynamicheatstability.Moreover,hydrotalcitecanimprovethefluidpropertyofPVC,whichisadvantageoustotheprocessingofPVC,andtheoptimumcontentofhydrotalciteisabout1%-2%(massfraction).

简介：Inordertopredictthemechanicalperformanceofthepolyvinylchloride(PVC)atahighoperatingtemperature,aseriesofshort-termtensilecreeptests(onetenthofthephysicalagingtime)ofthePVCarecarriedoutat63Cwithasmallconstantstressbyadynamicmechanicalanalyzer(DMA).TheStruik-Kohlrausch(SK)formulaandStruikshiftingmethodsareusedtodescribethesecreepdataforvariousphysicalagingtime.AnewphenomenologicalmodelbasedonthemultiplerelaxationmechanismsofanamorphouspolymerisdevelopedtoquantitativelycharacterizetheSKparameters(theinitialcreepcompliance,thecharacteristicretardationtime,andtheshapefactor)determinedbytheagingtime.ItisshownthatthemomentarycreepcompliancecurveofthePVCat63CcanbeverywellfittedbytheSKformulaforeachagingtime.However,theSKparametersforthecreepcurvesarenotconstantduringtheagingprocessattheelevatedtemperatures,andtheevolutionoftheseparametersandthecreeprateversusagingtimecurvesatthedoublelogarithmiccoordinateshaveshownanonlinearphenomenon.Moreover,thecreepmastercurvesobtainedbythesuperpositionwiththeStruikshiftingmethodsareunsatisfactoryinsuchacase.Finally,thepredictedresultscalculatedfromthepresentmodelincorporatingwiththeSKformulaareinexcellentagreementwiththecreepexperimentaldataforthePVCisothermallyagedatthetemperaturerelativelyclosetotheglasstransitiontemperature.

简介：ＨＥＡＴＳ　ＯＦ　ＩＮＴＥＲＡＣＴＩＯＮ　ＯＦ　ＯＲＧＡＮＩＣ　ＢＡＳＥＳ　ＷＩＴＨ　ＰＯＬＹＭＥＲ　ＰＲＯＴＥＣＴＥＤ　ＣＡＴＡＬＹＳＴ　ＰＶＣ－ＡｌＣｌ＿３ＨＥＡＴＳＯＦＩＮＴＥＲＡＣＴＩＯＮＯＦＯＲＧＡＮＩＣＢＡＳＥＳＷＩＴＨＰＯＬＹＭＥＲＰＲ...

简介：ThePVCservesofmacroporoussulfoniccation-exchangeresinswerepreparedbythesulfonationofamacroporousPVCbeadwithconcentratedsulfonicacidorchlorosulfonicacid.theresultingsulfonicresinwasemployedintheinvestigationofcatalyticesterificationandsolfteningofwater,Theresultsshowthattheyieldsofestersreach60.0-84.4%accordingasdifferentfattyacidsandalcohols,therefractiveindexesofestersobtainedresemblethosereportedinthereferencesbasically,meanwhile,345Lsoftenedwaterwhichholds≤0.06mmol/Lhardnesswouldbepreparedby1Lwetsulfonicresinreusingfor4times.Theresultingsulfonicresinswouldhave1.6-2.0or2.5-3.0mmol/gexchangecapacitybyusingconcentratedsulfonicacidorchlorosulfonicacidassulfonatingagent,respectively,Thesulfonicresinhasamacroporousstructuretakingthemorphologywithagglomeratesofminutelysphericalgelparticlesascharacteristic.

简介：在这研究，一新(乙烯基氯化物)(PVC)poly，为Ho3+离子的膜传感器作为ionophore基于N-phenyl-2-(thiophen-2-ylmethylene)hydrazinecarbothioamide(PHC)被准备。这个传感器与阳离子的变化比较向钬离子表明了好选择和敏感，包括碱，碱的地球，转变和重金属离子。电极的反应性质上的膜作文和pH的效果被调查。详细，建议传感器展出了Nernstian行为(与20.4的一个斜坡??洀????x