简介：Inviewoftheimportanceofsolventextractionofrareearthmetalswiththeacidicorganophosphorousreagent,thedevelopmentofachemicallybasedmodelapplicabletohighconcentrationisdesired.Inthepresentstudy,theequilibriumdistributionofdysprosium(Ⅲ)betweenanaqueousnitricacidsolutionand2-ethylhexylphosphonicacidmono-2-ethylhexylester(PC88A)wasmeasuredintherangeofaninitialaqueousdysprosium(Ⅲ)concentrationfrom1.0×10-3to1.0×10-1kmol/m3andPC88Aconcentrationfrom0.16to0.65kmol/m3inShellsolD70asthediluent.Theobtaineddatawereanalyzedusingthechemicallybasedmodelinordertocorrelatetheequilibriumdistributionratios.Inthismodel,dysprosium(Ⅲ)wasassumedtobeextractedwiththePC88Adimerasa1:3complex,theactivitieswereconsideredfortheaqueousspecies,andtheeffectiveconcentrationofthePC88AdimerwascalculatedusingAlstad'sempiricalequation.Asaresult,theapparentextractionequilibriumconstantwasdeterminedtobe253(kmol·m-3)-2withanexcellentcorrelationbetweentheexperimentandcalculationresultsinthewiderangeofthelogarithmofthedistributionratiofrom-2to3.5.Inconclusion,themethodologyinthismodelwouldbeeffectiveforquantitativedescriptionofsolventextractionbehaviorofgeneralrareearthelementsaswellasdysprosium.

简介：酸的分解的动力学在气压下面与一个钠氢氧化物系统溶解了钛炉渣被学习。钛抽取上的反应温度，粒子尺寸和NaOH-to-slag集体比率的效果被调查。结果证明温度和粒子尺寸在钛抽取上有重要影响。有化学反应的缩小的核心模型控制了的钛抽取表演的试验性的数据过程为炉渣的分解是很适用的，与62.4kJ·mol−1的一个明显的激活精力。钛的约85wt.%−90wt.%能在最佳的条件下面从炉渣被提取。另外，在产品获得的钛二氧化物的纯净直到98.5wt.%。

简介：Theflotabilityandmechanismofthecompositetantalite-niobitemineralswhichhavedifferentcontentoftheTa,Nb.Fe,Mnwithstyrenephosphonicacid（SPA）ascollectorareinvestigatedanddiscussed.Someimportantflotationparametersarefoundasfollows:SPAisabettercollectorforflotatingniobite-tantalitemineralthanother,theoptimumpHvalueinpulpislessthan5,theflotabilityofthosemineralsvarieswiththedifferentcontentofmineralcomposition,theflotabitityofthemineralswithhigherNb2O5contentisbetterthanthatwithhigherTa205content.HereweemphasizethatinwiderangeofpHinsolu-tiontheFe,Mnonthemineralsurfacesarethemainactivespeciesforflotationoftheseminerals.Inadditiontothis,someofre-searchworkbyusingAugerelectronspectroscopy,infraredspectroscopyandultravioletspectroscopyfordeterminingthesurfaceconditions,pretreatedbyacidornot,hasbeendone.ThecharacteristicsofadsorptionofSPAonthemineralsurfacesareexam-inedanddiscussed.ItisindicatedthattheSPAinteractswithFe,Mnionsonmineralsurfacesbythechemicalbondforce.Butonthewholeouterlayerofcollector,whichisnon-uniformmultilayer,itmaybesaidthattheadsorptionofSPAonthemineralsur-faceisbothchemico-adsorptionandphysico-adsorption,butthechemico-adsorptionispredominant.

简介：Thebinarycomplexesofeuropiumwithbenzoicacidanditsderivatives(phthalicacid,m-phthalicacid,o-aminobenzoicacid,salicylicacid,andsulfosalicylicacid)weresynthesizedandtheircompositionswereidentifiedbyelementalanalyses.UVandIRofthecomplexeshavebeeninvestigated.TheUVspectraindicatedthatthecomplexes'ultravioletabsorptionweremainlytheligands'absorption.TheIRspectrashowedthattheIRspectraofcomplexesaredifferentfromthoseoffreeligands.Thefluorescencepropertiesofthemwereinvestigatedbyusingluminescencespectroscopy,theresultsshowedthatonlythreecomplexesappearasbetterluminescence,theywereEu-benzoicacid,Eu-m-phthalicacidandEu-phthalicacid,whiletheothersexhibitedtheligands'widebandemission.

简介：ThetreatmentoftheGacuncomplexCu-PbbulkconcentratewithhighZn,Ag,etc.,byoxygenpressureacidleachingwasstudied.Theprimarycopperandleadmineralsintheconcentratearetetrahedriteandgalena.Thetreatmentoftetrahedritewasrarelystudied,andmostofsilveroccurredinthemineraltoo.Theoptimumoperatingparametersofoxygenpressureacidleachingwereestablishedbyconditionaltests.Undertheseparameters,theresultofpilotscaletestshowedthattheleachingpercentagesofcopperandzincwereseparatelyashighas98.9wt.％and94.9wt.％,whileleadandsilverweretransformedintosulfateandsulfideprecipitations,respectively.Thecopperandzincinlixiviumwerereclaimedbyextraction-electrowinningandpurification-electrowinning,respectively,andtheleadandsilverintheresiduewerereclaimedseparatelybycarbonatetransformation-silicofluoricacidleachingandthiourealeaching.

简介：二酸矿排水(AMD)样品TS和WK，从在Guangxi省的Dachang充满金属的矿，中国，用基于PCR的克隆被学习途径。44个运作的分类单位(OTU)的一个总数从二件AMD样品被获得。然而，仅仅三OTU(GXDC-9，GXDC-19和GXDC-50)在样品TS检测了能也在样品WK被观察。种系发生的分析表明在二件样品的细菌掉进四个通常认为的部门，它是Nitrospira，Alphaproteobacteria，Gamaproteobacteria，和Acidobacteria。类Acidithiobacillus和Leptospirillum的有机体，在gamaproteobacteria班和Nitrospira家庭上，分别地在二件样品是主导的。在样品TS，它被低pH描绘，高硫酸盐，高铁，和高砷化物，二种(Acidithiobacillusferrooxidans和Leptospirillumferrooxidans)组成了98.22%全部微生物引起的社区。与样品TS相比，在样品WK的微生物引起的社区根据观察是更多样化的。抱持兴趣地，Legionella种类，很少在low-pH环境被观察，在样品WK被检测。这个工作帮助我们进一步理解微生物引起的社区与唯一的地球化学和acidophiles的忍耐能力在极端酸矿排水住在一起到重金属的差异。

简介：FluorescenceandcofluorescencepropertiesofTb(Ⅲ)solidcomplexeswerestudiedusingpyromelliticacid(PMA)asligandandfluorescenceinertionsasdopingelements.Thecofluorescenceenhancement,aresultofligandsensitizedfluorescence,wasobservedinTb(Ⅲ)solidcomplexesdopedwithfluorescentinertionsLa(Ⅲ),Gd(Ⅲ),Ca(Ⅲ),andSr(Ⅲ).Theeffectofthetypeandcontentofdopingelementsonfluorescenceenhancementwasstudied,andoptimumconditionsweredetermined.TheresultsshowthatGd(La,Ca,Sr)hasclearcofluorescenceeffectinsolidcomplexTb-M-PMAsystem,andinpresentwork,rareearthcomplexfluorescentpowderthatemitsbrightgreenfluorescenceatultravioletexcitationwasobtained,whichhadpotentialapplicationasfluorescentanti-counterfeitink.

简介：AnewtypeofcomplexsolidsuperacidcatalystWO3-ZrO2-SO42-withanacidstrengthH0≤-16.04waspreparedbykneadingZr（OH）4oramorphousZrO2withtungsticacid（H2WO4）（W/Zr=0.15）,followedbyexposingthiscomplexhydroxidesto0.5tool/LH2SO4,calcininginairat700～800℃for3h.ThiscatalystpossessesbothstrongBronstedacidityandstrongLewisacidityexperimentallyshowedbyIRobservationofpyridineabsorbedonit.XPSandAEStechniqueswereemployedtoexaminethevalencestatesoftungsten,zirconium,sulfurandtheirinteractions.Thestructureofsulfurspecieswasstudiedbyinfraredspectroscopyandastructuremodelofactivesitewasproposedupontheseresults.