简介:通过化学沉积法制备Ni-P、Ni-Mo-P单镀层以及与其成分相同的Ni-P/Ni-Mo-P双镀层。采用纳米压痕法和AFM分析测量镀层表面和截面的残余应力,并用电化学法评估镀层在10%HCl溶液中的腐蚀行为,以获得镀层残余应力与腐蚀行为之间的关系。结果表明:Ni-P单镀层和Ni-P/Ni-Mo-P双镀层表现为残余压应力,分别为241和206MPa;Ni-Mo-P单镀层呈现出257MPa的残余拉应力。残余压应力阻止镀层中孔洞的生长,保护镀层的完整性。Ni-P/Ni-Mo-P双镀层比它们的单镀层具有更好的耐蚀性。此外,镀层的应力状态影响其腐蚀形式。
简介:InordertocontrolthesizeanddistributionofthehighconductiveFe2PinLiFePO4/Fe2Pcomposite,twodifferentcoolingrates(Fast:15℃·min-1,Slow:2℃·min-1)wereemployedaftermechanicalalloying.Thedischargecapacityofthefastcooledwas83mAh·g-1andtheslowcooled121mAh·g-1.TheparticlesizeofthesynthesizedpowderwasexaminedbytransmissionelectronmicroscopyanddistributionofFe2Pwascharacterizedusingscanningelectronmicroscopy(SEM).Inaddition,two-stepheattreatmentwascarriedoutforbetterdistributionofFe2P.X-raydiffraction(XRD)andRietveldrefinementrevealthatLiFePO4/Fe2Pcompositeconsistsof95.77%LiFePO4and4.33%ofFe2P.
简介:Weldshapecontrolisafundamentalissueinautomaticwelding.Inthispaper,adoublesidevisualsystemisestablishedforpulsedgasmetalarcwelding(P-GMAW),andbothtopsideandbacksideweldpoolimagescanbecapturedandstoredcontinuouslyinrealtime.Byanalyzingtheweldshaperegulationwiththemoltenmetalvolume,sometopsideweldpoolcharacterizedparameters(WPCPs)areproposedfordeterminingpenetrationinbuttweldingofthinmildsteel.Moreover,someBPnetworkmodelsareestablishedtopredictbacksideweldpoolwidthwithweldingparametersandWPCPsasinputs.
简介:Thehotdeformationbehaviourof7075aluminiumalloyreinforcedwith10%ofSiCparticleswasstudiedbyemployingboth'processingmaps'andmicrostructuralobservations.Thecompositewascharacterizedbyemployingopticalmicroscopetoevaluatethemicrostructuraltransformationsandinstabilityphenomena.Thematerialinvestigatedwasdeformedbycompressioninthetemperatureandstrainraterangesof300-500℃and0.001-1.0s-1,respectively.Thedeformationefficiencywascalculatedbystrainratesensitivity(m)valuesobtainedbyhotcompressiontests.Thepowerdissipationefficiencyandinstabilityparameterswereevaluatedandprocessingmapswereconstructedforstrainof0.5.Theoptimumdomainsandinstabilityzonewereobtainedforthecomposites.Theoptimumprocessingconditionsareobtainedinthestrainraterangeof0.1-0.9s-1andtemperaturerangeof390-440℃withtheefficiencyof30%.
简介:55%SiCp/A356(体积部分)以铜锌金焊接在把Zn-Al合金用作filler金属的空中的composites被调查。在以铜锌金焊接的过程期间,超声的颤动为结合被用于样品,进在基础材料的矩阵合金的filler金属的重要溶解发生了。当以铜锌金焊接的温度被增加,在基础材料的部分融化层的厚度增加了。原文如此,在基础材料的部分融化层的粒子在超声的行动下面被变成液体filler,有同类地分布式的加强的一张契约在团结以后被获得。体积部分原文如此,在契约的粒子能被改变以铜锌金焊接的温度改变。最大值原文如此,契约材料的粒子体积部分在500的以铜锌金焊接的温度到达了37%?????????????敷摬摥??
简介:AmorphousNi–PcoatingwasplatedonAZ31magnesiumalloyviatheelectrolessplatingtechnique,andtheplatedalloywassubsequentlyannealed.X-raydiffraction(XRD),scanningelectronmicroscopy(SEM),energydispersivespectroscopy(EDS),anddifferentialscanningcalorimetry(DSC)wereusedtocharacterizethecoating.Theresultsshowthatthehardnessofthecoatingismuchhigherthanthatofbaremagnesiumalloy,whichfurtherincreasesaftercrystallization.Theelectrochemicalpolarizationandsaltspraytestsshowthatthecoatingexhibitsamuchhighercorrosionresistancethanthatofthebaremagnesiumalloy.Moreover,thecrystallizedcoatingstillexhibitsamuchstrongercorrosionresistancethanthatofthebaremagnesiumalloy,althoughitscorrosionresistanceislowerthanthatoftheas-platedone.
简介:TheunstabledimensionaldistortionofLF21aluminumalloyweldmentsatroomtemperatureandafterthermalcycleswasstudiedbyuseoflightinterferenceandCMM.Atthesametime,distortionmechanismwasanalyzedfromtheviewpointofmechanicsandmicrostructure.ExperimentalresultsshowthatthereexistsobviousdifferenceofunstabledimensionaldistortionbetweenLF21weldedspecimensundertwoconditionsmentionedabove.Underroomtemperature,dimensionalvariationofweldedspecimenswilldecreasegraduallyandfinallytendstobestableduring130hafterwelding.Therelativeelongationofweldedspecimenis4.2×10-5.Afterthermalcycles,distortionofweldedspecimenismuchlargerthanthatatroomtemperature.After11thermalcycles,thedimensionwilltendtobestable.Dimensionalunstabledistortionofweldmentsmainlyresultsfromtemperaturecondition,microstructurevariationandrelaxationofweldingresidualstress.
简介:氮(N)和磷(P)共同做锐钛矿TiO2nanosheets被与外国先锋做的高温度的P跟随的低温度的自我做的N-TiO2认识到。做过程的P能维持好TiO2nanosheets形态学与,这被发现暴露{001}方面。掺杂物的化学状态显示N和P原子在TiO2格子在O地点上代替O。与纯TiO2和做N的TiO2,N-P相比,共同做的TiO2nanosheets在可见轻政体展出更强壮的光吸收和染料分子的更高的降级率。提高的photocatalytic性质被归因于二个因素。一方面,N-P共同做能有效地从3.20~2.48减少TiO2的乐队差距?eV,在可见的光导致吸收的改进政体。在另一方面,存在暴露{001}TiO2nanosheets的方面能在反应导致photogenerated电子和洞的有效分离。