简介:Thestarch/D,L-lactidegraftcopolymersweresynthesizedbyreactingD,L-lactidewithcornstarchinN,N-dimethylacetamide(DMAM)inthepresenceoftriethylamine(NEt3)andanhydrouslithiumchloride.TheeffectofreactiontimeandthemolarratioofD,L-lactidetoglucosestructuralunitofstarchonmonomerconversion(C%),graft(G%)andgraftefficiency(GE%)werestudied,TheC%,G%andGE%couldapproach37.3%179.7%and68.0%,respectivelywhenthemolarratioofD,L-lactidetoglucosestructuralunitofstarchis10:1andthegraftcopolymerizationwascarriedoutat80-85℃for4hrundernitrogenatmosphere.TheFouriertransformsinfra-red(FTIR)spectroscopy.differentialscanningcalorimetry(DSC)andX_raydiffraction(XRD)spectroscopywereusedinordertocharacterizethegraftcopolymers.FTIRspectrashowthatabsorptionbandat1740cm^-1confirmedtheformationofesterbond,indicatingthestarch/D,L-lactidegraftcopolymerswereproduced,theDSCcharacteristicresultsshowthemeltingtemperatureofthegraftcopolymerwereelevatedslightlyasthemolarratioofD,L-lactidetoglucosestructuralunitsofstarchincreasedandtheX-raydiffractionspectrashowthesynthesizedgraftcopolymerswereamorphous.Thedegradabilityofgraftcopolymerwastestedwiththeaidofacid,alkaliandmicrobesuchasbacillussubtilisandstaphylococcusaureus.Theresultsofwaterrsistanceshowthegraftcopolymerproducedcanbeusedasacomponentofimpermeablecoatingforcardboard.
简介:N-acetyl-D-methionine,NaAcandtheremainsofN-acetyl-L-methioninedramaticallyaffectthepurificationofL-methioninewhenpurifiedfromthemixtureofenzymaticallydeacylatedN-acetyl-DL-methionine,leadingtoalowyieldconventionally.Here,thispaperreportsasuccessfulseparationandpurificationofbothL-methionineandN-acetyl-D-methioninebyanHion-exchangecolumn.ThepH,L-Metconcentrationandtheratiobetweenthecontentofsodiumcationandtheion-exchangecapacitywereoptimizedtoobtainthemaximumyield.Experimentalresultsindicatethat,undertheoptimizedconditions,theyieldsofL-methionineandN-acetyl-D-methioninecanreachashighas85%and75%,respectively.
简介:新课程倡导信息技术与课堂教学的有机整合,促进课堂教与学方式的转变.所谓整合有两个层次的意义:一是“替代”‘,即用信息技术替代原有的教学手段,帮助教师或学生解决教与学的问题;二是“创新”,即把信息技术作为构建自主、探究学习环境的重要因素来支持学习.图形计算器是一台计算与作图功能合二为一的新型计算器,具有智能型模拟仿真功能,它可以使学生在学习的过程中自己进行试验操作,完成课堂上一些难以完成的实验,解决教学上的难点,产生出一种图文并茂、丰富多彩的人机交互方式,这样一种交互方式对于教学过程具有重要意义.现以《函数图像的变换》课堂为例,来初步感受手持技术运用于学生的探究实践活动,进一步思考“如何运用信息技术促进学生的数学学习”.