简介:Wereporteddiversesolitonoperationsinathulium/holmium-dopedfiberlaserbytakingadvantageofataperedfiber-basedtopologicalinsulator(TI)Bi2Te3saturableabsorber(SA).TheSAhadanonsaturablelossof53.5%andamodulationdepthof9.8%.Stablefundamentallymode-lockedsolitonsat1909.5nmwithdistinctKellysidebandsontheoutputspectrum,apulserepetitionrateof21.5MHz,andameasuredpulsewidthof1.26pswereobservedinthework.Byincreasingthepumppower,bothbunchedsolitonswithsolitonnumberupto15andharmonicallymode-lockedsolitonswithharmonicorderupto10wereobtained.Toourknowledge,thisisthefirstreportofbothbunchedsolitonsandharmonicallymode-lockedsolitonsinafiberlaserat2μmregionincorporatedwithTIs.
简介:Inthispaper,wereportedamultiwavelengthpassivelyQ-switchedYb3+:GdAl3(BO3)4solid-statelaserwithtopologicalinsulatorBi2Te3asasaturableabsorber(SA)forthefirsttime,tothebestofourknowledge.Bi2Te3nanosheetswerepreparedbythefacilesolvothermalmethod.TheinfluenceofthreeBi2Te3densitiesonthelaseroperationwascompared.Themaximumaverageoutputpowerwasupto57mWwithapulseenergyof511.7nJ.Theshortestpulsewidthwasmeasuredtobe370nswith110kHzpulserepetitionrateand40mWaveragepower.Thelaseroperatedatthreewavelengthssimultaneouslyat1043.7,1045.3,and1046.2nm,ofwhichthefrequencydifferenceswerewithintheterahertzwaveband.OurworksuggeststhatsolvothermalsynthesizedBi2Te3isapromisingSAforsimultaneouslymultiwavelengthlaseroperation.
简介:Generally,ROSareregardedashostdefensemoleculesthatarereleasedbyneutrophilstodestroyexogenouspathogenssuchasbacteriaandtoactassecondarymessengersinsignaltransduction.However,increasedproductionofROSisalsoinvolvedininducingpathophysiologicalchangessuchasapoptosis,cellcycledisruption,andnecrosis.Forthisreason,inductionofROS-mediateddamageincancercellsbypharmacologicalagentsthateitherpromoteROSgenerationordisablethecellularantioxidantsystemisconsideredapotentialtherapeuticstrategyforpreferentiallykillingcancercells[1].
简介:Pt/WO3/CnanocompositeswithparallelWO3nanorodsweresynthesizedandappliedasthecathodecatalystforprotonexchangemembranefuelcells(PEMFCs).Electrochemicalresultsandsinglecelltestsshowthatanenhancedactivityfortheoxygenreductionreaction(ORR)isobtainedforthePt/WO3/CcatalystcomparedwithPt/C.ThehighercatalyticactivitymightbeascribedtotheimprovedPtdispersionwithsmallerparticlesizes.ThePt/WO3/Ccatalystalsoexhibitsagoodelectrochemicalstabilityunderpotentialcycling.Thus,thePt/WO3/CcatalystcanbeusedasapotentialPEMFCcathodecatalyst.
简介:Amolybdenumdisulfide(MoS2)saturableabsorberwasfabricatedbythermallydecomposingtheammoniumthiomolybdate.ByusingtheMoS2absorber,acompactdiode-pumpedpassivelyQ-switchedTm:GdVO4laserhasbeendemonstrated.AstableQ-switchedlaserwithrepetitionratesfrom25.58to48.09kHzwasachieved.Maximumaverageoutputpowerwas100mWwiththeshortestpulsedurationof0.8μs.Maximumpulseenergyis2.08μJatcenterof1902nm.
简介:Theshapeofnanostructurehasimportanteffectsontheirproperties,thereforeinthisstudy,wehavepreparedandcharacterizedthreedifferentmorphologiesofWO3nanostructuresi.e.nanorod,nanosphereandnanoplateforsurveyingshapeeffectontheirphotocatalyticpropertiestowarddegradationofRhodamineB(RhB)dye.ObtainedresultsshowthatnanoplateWO3incomparisonwithothershasthebestphotocatalyticactivity.AccordingtoSEM,andphotocatalyticdegradationresults,thereasonforthisbehavioristhesharpedgesandcornersofWO3nanoplates.Becauseoftheirlowcoordinationnumber,atomslocatedintheedgesandcornersoftheWO3nanoplateshavemoreactivity,adsorbmoreRhBandthereforegivemorephotocatalyticactivitytotheWO3nanoplates.UsingofdifferentscavengersshowedthathydroxylradicalsaremainlyresponsibleforphotocatalyticactivityofWO3nanoplatesandnanospheresbutforWO3nanorods,superoxideradicalsarethemainphotocatalyticdegradationagents.
简介:Grapheneanditsderivativeshaveattractedtremendousresearchinterestbecauseoftheiruniquecompositionandphysicochemicalproperties[1??3].However,thepotentialbiologicaltoxicityofGQDshasbecomeahealthriskbecauseoftheirinherentchemicalcompositionandnanoscaleproperties[4].Zebrafish(Daniorerio)isoneofthemostpromisinginvivomodelsystemsfortoxicitystudies[5].
简介:AsimpleandefficientcascadeMichael/cyclizationreactionof3-aminoindolin-2-oneswithenones/enalswasidentifiedforthesynthesisofpotentiallybiologicallyactive3’,4’-dihydrospiro[pyrrol-3,2’-oxindoles],usingDBUasanefficientcatalystandethyleneglycolasanenvironmentallybenignsolvent.Morediverse3’,4’-dihydrospiro[pyrrol-3,2’-oxindoles]analoglibrarieswerepreparedingoodyields(upto97%).Thestructureof3’,4’-dihydrospiro[pyrrol-3,2’-oxindoles]wasconfirmedbymassspectrometryanalysis,NMRanalysisandsinglecrystalX-raydiffraction.Themainadvantagesofthismethodincludetheavailabilityofstartingmaterials,simpleexperimentaloperation,shortreactiontime,aswellashighyieldsobserved.
简介:MalignanttumorsorcancershavebecomeoneofthemostfrequentcausesofdeathinChina;cancertherapiesareattractingmuchattention.Becauseofthenoninvasivenatureofradiationtherapy,lesserphysiologicalandpsychologicalburdenisplacedonpatientsthancomparedtothatresultingfromsurgicalorpharmaceuticaltreatments.Hadrontherapy(heavyiontherapyandprotontherapy)isconsideredsuperiorapproachforthetreatmentoftumorslocatedinhighlysensitivetissues(brain,neck,eyes),pediatriccancers,andalsotumorsthatareresistanttoradiotherapy.