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500 个结果
  • 简介:本文通过高分辨X射线衍射及掠入射(GID)的实验方法对生长在SrTiO3衬底上的LLa2/3Ca1/3MnO3和YBaCu3O7单层膜及YBa2Cu3O7-x/La23Ca13MnO3异质结构双层薄膜的微结构进行了研究。结果发现,所有薄膜都呈c向生长。由于热膨胀系数的不同而引起的热应力使得LCMO膜的晶格参数与靶材的相差较大。La2/3Ca1/3MnO3在单层腹及双层膜中都由靶材的立方结构变成了薄膜状态的四方结构。YBa2Cu3O7在单层膜及双层膜中都由靶材的正交结构变成了薄膜状态的四方结构。La2/3Ca1/3MnO3膜与YBa2Cu3O7膜在不同的样品中处于不同的应力状态。

  • 标签: YBa2Cu3O7-x/La2/3Ca1/3MnO3 异质结构薄膜 微结构 X射线衍射 X射线掠入射 锰酸盐
  • 简介:ThetransportpropertiesintheLa2/3(Ca1-xSrx)1/3MnO3(x=0,1/3,2/3)filmspreparedusingtheRFmagnetronsputteringmethodwereinvestigated.TheeffectoftheCa,Srdouble-dopingattheApositionintheLa2/3A1/3MnO3onthestructureofthetargetsandtransportofthefilmshasbeenstudied.Withtheincreaseofx,thestructuresofthetargetstransformfromtherhombohedralphasetothecubicphase;themetal-insulatorphasetransitiontemperature(Tp)ofthefilmsincreases;andthecorrespondingpeakresistivitydecreases.Allthephenomenacanbequalitativelyexplainedbythelatticeeffect.

  • 标签: 格子效应 传输性质 氧化锰薄膜 电子喷射 磁致电阻
  • 简介:美国宇航局在加州帕萨迪纳的喷气推进实验室研究成功了一种制造YBa2Cu3O7-α高温超导电缆(封装在金属套管内)的新方法。据称,这种方法成本较低,过程易于控制,且对各种前体材料有很强的适应能力。该法分4个步骤:生产具有化学(配)比的前体(Precursor)粉;将前体粉包封在金属套管内;用轧制的方法使前体粉固结;在液态锂金属浴槽内进行处理,使之转变成超导组

  • 标签: 粉末冶金 金属套管 高温超导电缆 锂金属 实验室研究 喷气推进
  • 简介:ScanningElectronMicroscopyStudiesofYBa_Cu_O_(-δ)SuperconductorsShaWei(沙维)(DepartmentofCivilEngineering,TheQueen′sUniversit...

  • 标签: SUPERCONDUCTORS Thin film Ion IMPLANTATION Scanning
  • 简介:(1-x)La_(0.67)Ca_(0.33)MnO_3/Cr_2O_3(LCMO)+xCr_2O_3composites被一个新液相方法综合。XRD和SEM大小表明在LCMO结构和LCMO的晶格常数可溶的很少Cr_2O_3几乎没变化,当大多数Cr_2O_3在谷物边界或在LCMO谷物的表面上是分布式的时。Inresistivity对温度大小,金属--绝缘体转变被观察什么时候x<0.20。抵抗力增加和金属--绝缘体转变温度与Cr_2O_3的增加的内容减少。一个随机的电阻器网络(KRN)模型被使用,到模仿混合样品的运输性质。模拟结果同意试验性的观察。结果证明方法为理解maganite的composites的电子运输是合理的。

  • 标签: 巨磁电阻 水锰矿 无规则电阻网络 蒙特-卡洛模拟 La0.67Ca0.33MnO3/Cr2O3复合物
  • 简介:研究了YBaCuO6~超导催化剂上CO的加氢制醇反应。考察了温度、压力和空速等条件对催化剂反应性能的影响。反应的主要产物是甲醇、CO和少量甲醚。利用XPS、XRD和AFM等技术对催化剂的结构、铜的存在状态和反应活性位进行表征发现,在反应过程中,YBaCuO6~由orthombic相转变为tetragonal相。反应活性位可能是Cu(I)物种。反应后催化剂颗粒的分散程度明显提高

  • 标签: CO2加氢 YBa2Cu3O6~7超导催化剂 结构 活性位
  • 简介:YBa2Cu3Ox(YBCO)thinfilmsgrownondifferentsubstrateswithand/orwithoutEu2CuO4(ECO)bufferlayerwereinvestigatedbyX-raywideanglediffraction,reflection,diffusescatteringandtopography.TheresultsshowthatfortheyttriastabilizedZrO2(YSZ)substrate,thepresenceofanECObufferlayerimprovesthecrystallinequalityoftheYBCOfilm,whileanegativeeffectisobservedfortheSrTiO3(STO)substrate.ThelateralcorrelationlengthforasamplegrownonaYSZsubstratewithECObufferLayerismuchgreaterthangrownonanSTOsubetrate.TheSTOsubstrateusedhasmosaicstructure.2001ElsevierScienceB.V.Allrightsreserved.

  • 标签: 微观结构 X射线衍射分析 YBa2Cu3O7薄膜 钇钡铜复合氧化物薄膜 缓冲层 薄膜生长
  • 简介:Inordertorealizetheco-firingwithAg/Pdelectrodesinmultilayerdevices,Pb(Zn1/3Nb2/3)1-,-yZrxTiyO3(0.25<x<0.35,0.25<y<0.35)piezoelectricceramics(hereafterdesignatedPZN-PZT)modifiedbyLa2O3hasbeenpreparedbyconventionaltechniquewithsinteringtemperaturefrom1100℃to1140℃.X-raydiffractionpatternsdemonstratedthatpureperovskitephasewasobtained.Secondaryelectronimage(SEI)showedthatcrystallinegrainsinceramicswerewellgrown.d33ofmanufacturedsamplewasashighas560×10-12C/N.kpwasabout0.61andtgδabout30×10-3.TheexistenceofliquidphaseexaminedbyelectrondiffractioninPZN-PZTsampleisbeneficialtosinteringoftheceramic.

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  • 简介:Inthispaper,varioustechniquesincludingBET,XRD,SEMandXPSwereusedtostudythesinteringofpureandLa2O3-dopedtitania.Theexperimentalresultsshowthatsinteringoftitaniaproceedsviavolumediffu-sion.Addingoflanthanumoxidedecreasestherateofsinteringandhindersthephasetransitionfromanatasetorutilecrystalbystrongsurfaceinteractionbetweenthemixedcrystals(La4Ti9O24,La0.66TiO2.99)andTiO2.

  • 标签: La2O3 TiO2 SINTERING kinetics Thermal stability
  • 简介:BondingofAl2O3tocuisperformeddirectlyusingTifoilattemperatureof1273K.Themicrostructureofthejointinterfaceisinuestigatedthroughscanningelectronmicroscope(SEM),electron.probemicroanalysis(EPMA)andX-raydiffraction(XRD).theeffectoftheinitialtifoilthicknessonthereactionlayerthicknessandthejointStrengthareinvestigated.

  • 标签: ALUMINA active BRAZING INTERFACIAL reaction joint
  • 简介:本文主要研究添加微量稀土La2O3对Li2O-Al2O3-SiO2微晶玻璃晶相组成,显微结构,抗折强度的影响,研究结果表明:添加微量La2O3有利于Li2O-Al2O3-SiO2微晶玻璃中的主晶相β-锂辉石发育成完整的柱状,板状晶体,提高了微晶玻璃的抗折强度。

  • 标签: 稀土La2O3 LI2O-AL2O3-SIO2 微晶玻璃 结构 性能 影响
  • 简介:TherepresentativesampleLa0.58Dy0.09Ca0.33MnO3ofDydopedLa0.67Ca0.33MnO3rare-earthmanganiteswasinvestigated.ThemostimportanteffectofDydopingistointroducethemagnetoimpurityandformthespinclusterswhichinducedramaticallylargeCMRinLa0.58Dy0.09Ca0.33MnO3.Thefittingresultsoffield-inducedresistivitydecreasetotheBrillouinfunctionindicatethattheCMRiscausedbythespindependenthoppingbetweenspinclusters.Itisthemagneticfieldthatreducesthesizeofspinclustersandinducesafield-inducedirreversibleCMRbehaviour.

  • 标签: 磁致电阻 La0.58Dy0.09Ca0.33MnO3
  • 简介:关于O2+、O2-、O22-、O3O3-结构,是一个很重要的问题.弄清楚它们的结构就不难了解由它们所引起的化学反应及形成的化合物的性质.本文只想简析它们的结构,而对于它们的性质将不加详细讨论.

  • 标签: 分子轨道理论 杂化轨道 氧原子 超氧离子 成键特征 键级
  • 简介:AseriesofLa2O3/MCnylonnanocompositeswerepreparedviainsitupolymerization.Theeffectsofcontentofnano-La2O3onthemechanicalpropertiesofnanocompositeswerestudied.Dispersionofnano-La2O3inMCnylonmatrixwasobservedwithSEM.ThecrystalstructureofnanocompositeswascharacterizedbymeansofXRD.SEManalysisshowsthatLa2O3nanoparticlesareuniformlydispersedinMCnylonmatrixandlittleclusteringexistswhenthecontentofnano-La2O3islowerthan1%,however,whenthecontentofnano-La2O3ismorethan1%,itbeginstocluster.XRDanalysisindicatsthatnano-La2O3doesnotchangethecrystalstructureofMCnylon.Mechanicalpropertiestestsshowthatthetensilestrength,elongationatbreak,impactstrength,flexuralstrength,andflexuralmodulusofnanocompositesfirstincreasethendecreaseasthecontentofnano-La2O3isincreased.Whenthecontentofnano-La2O3is0.5%,thetensilestrengthandelongationatbreakofnanocompositesreachmaximum,whichare17.9%and52.1%higherrespectivelythanthoseofMCnylon.Whenthecontentofnano-La2O3is1.0%,theimpactstrength,flexuralstrengthandflexuralmodulusofnanocompositesreachmaximum,whichare36.6%,12.7%and16.3%higherrespectivelythanthoseofMCnylon.

  • 标签: LA2O3 MC尼龙 纳米复合材料 聚合反应 稀土 机械性能
  • 简介:TheZrO2-Al2O3ceramiccompositeswerepreparedbyappropriatetechniqueswithcommercialZrO2andAl2O3powdersasrawmaterialsandY2O3asstabilizer.TheresultsindicatethatwiththeintroductionofAl2O3intotheZrO2matrixwherethequantityofadditiveY2O3is3.5%(molefraction),thegrowthofZrO2grainsisefficientlyinhibited,whichhelpstheZrO2grainsexistinametastabletetragonalmanner;thushigherstrengthandtoughnessareacquired.Whenthecontentofaluminais20%(massfraction),thebendingstrengthandfracturetoughnessofthecompositesare676.7MPaand10MPa·m1/2respectively,themechanicalbehaviorsareclosetothosepreparedwithZrO2andAl2O3powderssynthesizedthroughwetchemicalapproach.Themechanicalbehaviorsofthecompositesarewellimprovedowingtothedispersiontougheningofaluminagrainsandphasetransformationtougheningofzirconiagrains.

  • 标签: 无机非金属材料 陶瓷 稳定设备 稀土
  • 简介:LayeredcathodematerialLiCo1/3Ni1/3Mn1/3O2wassynthesizedbyPechiniprocess,andinvestigatedusingX-raydiffraction(XRD),scanningelectronmicroscopy(SEM)andgalvanostaticcharge/dischargecycling.Thesampleiswell-crystallizedandhasaphase-purea-NaFeO2structure.Theparticlesizesareuniform,anddistributedintherangeof20-200nm.TheinitialdischargecapacityoftheLi/LiCo1/3Ni1/3Mn1/3O2cellwasabout149mAh·g-1whenitwascycledatavoltagerangeof4.5-2.3Vwithaspecificcurrentof0.25mA.Theresultisbetterincomparisonwithsolid-statesolutionmethod.Thesyntheticprocedurewasdiscussed.Threemajorreactions:chelation,esterification,andpolymerizationsuccessivelyoccurred.

  • 标签: LAYERED CATHODE material LiCo1/3Ni1/3Mn1/3O2 PECHINI method