学科分类
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69 个结果
  • 简介:TheinfluenceofthreedifferentAl2O3powderonself-flowingaluminacastablewasstudied.MaximumcompactionofsamplewascomputedbyAndresenEquation.TheresultshowedthattheAl2O3powder,whichhasmuchsmallerparticlesize,couldimprovethemicrostructureandthemechanicalpropertiesofcastableunderroomtemperatureandhightemperature.Withthesamepowdersize,theroomtemperaturestrengthofthecastableaddedwithAl2O3powderproPertiesofwhichwerealteredbyaddingmineralizingagent,washigherthanthatofthecastableaddedwithcommonAl2O3powder,buttheflowabilityofthesethreedifferentcastablewasalmostthesame.

  • 标签: 合成 Al2O3粉末 性质 氧化铝 浇注材料 流动性
  • 简介:Thestabilizationofγ-aluminiumoxyni-tridespinel(γ-AlON)hasbeeninvestigatedbyadditionofMgO,MgAl2O4,etc.,inreactionprocess.Theresultsindicatedthattherearewidersolidsolutionareasnear,Al2O3-richsideinAlN-Al2O3-MgOternarysystems,ThecontentofstabilizedAlONphaseinsamplesisrelatedtoheatingtemperatures,additives,etc.ThelatticeparametersoftheirAlONphasescouldbewelldescribedbytheequation:a0=0.7900+0.0375[MgO]+0.015[AlN](nm)

  • 标签: γ-AlON 尖晶石 三氧化二铝 氮化铝 氧化镁 AL2O3
  • 简介:α-Fe^2O^3材料在陶瓷、催化剂、颜料、防腐、感光材料和磁性材料等方面都有着重要的应用,而且因其原料来源丰富、用途极广,因而受到格外关注。所以,均分散α-Fe^2O^3胶体粒子的制备,不仅在理论研究具有较高价值,而且在实际应用上也有重要意义。

  • 标签: α-Fe^2O^3粒子 微波法 均分散 制备 透射电镜
  • 简介:Inordertoimprovetheservicelifeofcorundumliningforinductionfurnace,corundumdryrammingmixwaspreparedusingbrowncorundum,fusedmagnesia,andα-Al2O3micropowderasmainstartingmaterials,andtheinfluenceofα-Al2O3micropowderadditions(0,1%,2%,and3%,inmass)onpropertiesofcorundumdryrammingmixwasinvestigated.Theresultsshowthatafterheattreatingat1600℃,withtheincreaseofα-Al2O3addition,thepermanentchangeindimensionsonheatingofthespecimensdecreasesfirstlyandthenincreases,bulkdensityincreases,apparentporositydecreases,andthecrushingstrengthdeclinesfirstlyandthenenhances;whentheadditionofα-Al2O3is2mass%,thepermanentchangeindimensionsonheatingofthespecimensisrelativelysmallandthecrushingstrengthdecreasesto22.8MPa.TheXRDandSEMresultsshowthatafterfiringat1600℃for3hsmallgranularmagnesiumaluminatespinelformsandiswelldistributed,whichenhancesthedensity.

  • 标签: 干式捣打料 AL2O3微粉 棕刚玉 属性 加入量 氧化铝微粉
  • 简介:TheAl2O3-SiCcompositepowderswerepreparedinargonatmosphereusingcoalgangueandcarbonaceousmaterialsO3-SiCcompositepowderswereinvestigated.Theresultsindicatethat:temperature,soakingtimeandchlorideadditivehavesignificantinfluenceonthesynthesizedAl2O3-SiCcompositepowders.Basedontheresults,theoptimizedAl2O3-SiCcompositepowders(Al2O358mass%andSiC42mass%)withparticlesized50≤5μmwerepreparedusingcoalgangueandcarbonblackasstartingmaterialsafter3hfiringat1550℃.andproperadditiveadditioncouldreducethetemperatureby50℃.

  • 标签: 碳化硅微粉 还原合成 碳热还原 氧化铝 煤矸石 复合粉末
  • 简介:Simplethree-pointbendingtestatambienttemperaturecharacterizedthemechanicalbehaviorofburnedAl2O3-Crefractoriesbeforeandafterthermalshockinassociationwiththeprocessingparameters(graphitecontentandcokingtemperature,etc.).Theresultsshowedthatnon-linearplastic-elasticbehaviorunderloadlowerthancoldmodulusofrupture(CMOR)wasregisteredinallspecimensandreallinearelasticbehaviorcouldbeidentifiedafterthefirstload.Thetotaldeformationcouldbedividedintotwoparts,plasticandelasticareas.ThegraphitecontentandjointbondingsystemofcarbonandceramicphaseswereresponsibleformechanicalbehaviorofAl2O3-Crefractories.

  • 标签: 碳化物 氧化铝 混合物 抗氧化 室内温度
  • 简介:UsingAl2O3-MgOcastableinlargeladlecanavoidcontainationofmoltensteelfromcarbon-containingrefractoriesandincreasladleservicliferemarkably,Theadditionofmagnesiaandfinepowder,theeffectofgrainsizeontheproper-tiesofthecastable,especiallylinearchangeandstructurespallinghavebeenstudied,Castablepro-duedforlargeladlewithsmallweareratehasgotgoodapplicatioresult.

  • 标签: 发展趋势 三氧化二铝 氧化镁 浇注块 炼钢
  • 简介:MoltensaltsynthesisofMgAl2O4powderfromindustrialaluminaandlightcalcinedMgOinKCl,LiCl,andKCl-LiClmedia,andtheinfluenceofKFat500-1000℃wereinvestigated.SynthesizedpowderswerecharacterizedbymeansofXRD,laserparticleanalyzer,andSEM,andthesynthesismechanismofMgAl2O4wasdiscussedaswell.Theresultsshowthat(1)themoltensaltcomposite(KCl-LiCl)ismorefavorableforthesynthesisofMgAl2O4thansinglemoltensalt(LiClorKCl),andLiClismorefavorablethanKCl;(2)KFcanacceleratetheformationofMgAl2O4anddecreaseitsformingtemperature;(3)synthesisofMgAl2O4powderinthemoltensaltswithoutKFiscontrolledby'template-growth'mechanism,butinthemoltensaltswithKF,itiscontrolledby'template-growth'and'dissolution-precipitation'mechanism.

  • 标签: 熔盐合成 工业氧化铝 氯化锂 氯化钾 氧化镁 F系统
  • 简介:Cr2O3canbesinteredwellat1500℃incarbon-embeddedconditionorH2atmosphere.Butthehighchromebearingrefractoriescannotreachdensificationwhensinteredat1700℃for10hinweakreducingatmosphereformedbythecombustionoffuel,anditsapparentporosityisabout18%.Thehighchromebearingrefractoriesaremainlyusedincoalgasifiers.Thetemperatureinthefurnaceisabout1500℃andtheproductsareH2andCO,whicharejustthesinteringconditionsofthedensechromerefractorieswithapparentporositylessthan10%.Thehighchromebearingrefractoriesusedincoalgasifiersmaybesinteredagainandthenshrink,destroyingthegasifierlining.Thethermodynamiccalculationshowsthatitissafeaboutthehighchromebearingrefractoriesusedingasifiers.Itisalsoexplainedthatthehighchromebearingrefractoriescan’tbesintereddenselyinweakreducingatmosphereformedbythecombustionoffuel.Thenewsinteringtechnologiescanbeusedtoimprovethebulkdensityofthehighchromebearingrefractories.

  • 标签: 铬质耐火材料 烧结技术 热力学计算 CR2O3 轴承 还原性气氛
  • 简介:Inthisstudy,inordertoevaluatetheperformanceofhomogenizedbauxite,twoAl_2O_3-SiC-Ccastableswerepreparedusinghomogenizedbauxiteandbrownfusedcorundumasaggregates,respectively.5mass%andalusitewasintroducedintothetwocastablessoastoresearchtheeffectandmechanismofandalusiteinAl_2O_3-SiC-Ccastables.Theresultsshowedthat:(1)comparedwiththebrownfusedcorundumbasedcastables,thehomogenizedbauxitebasedcastableshadhighercoldstrengthafterheattreatment,butlowerhotmodulusofrupture;(2)additionof5mass%andalusitecouldenhancethecoldandhotmodulusofrupture,improvethethermalshockresistance,andoptimizethemicrostructureofspecimens;(3)themullitizationofandalusitewasnotobviousinthecastablesfiredat1100-1400℃.

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  • 简介:介绍了用微波辐照均相制备α-Fe2O3胶体粒子的方法。实验表明:采用微波辐照均相制备,可在较短时间内得到均匀分散的α-Fe2O3粒子,其尺寸大且产量大。

  • 标签: 微波辐照法 均相制备 Α-FE2O3 胶体粒子
  • 简介:ThispapertestifiesthataluminiumandsiliconaswellastheircarbidexandnitridescanreactwithCOincarbon-containingzonetoformAl2O3andSiOgasthroughexperimentandthermodyanmicanalysis,ThegasesdiffusetooxidizedzoneandreactwithoxidizerssuchasCO2,Asaresult,Al2O3andSiO2aredepositedfromthegases,wihichblockthepores,thusreducetheamountofgasdiffusionandincreaseoxidationresistnaceofcarbon-containingmaterials.

  • 标签: 氧化铝 石墨 添加剂 被氧化物质 碳化硅 阻塞孔
  • 简介:SiliconoxynitridewasaddedinshapedAl2O3-SiC-Crefractorymaterialtoimprovetheslagresistanceinthispaper.Optimumaddingquantityofsiliconoxynitridepowderwasalsostudied.TheresultsshowthattheslagresistanceofAl2O3-SiC-Cshapedrefractoryisimprovedwhen2%or3%Si2N2Oisadded.AreasonableamountofSi2N2OaddedintoAl2O3-SiC-Cshapedrefractorycanproducesiliconoxideintotheslag,whichcanimprovetheviscosityofslagandpreventtheslagerosionandpenetration.

  • 标签: SLAG resistance SILICON OXYNITRIDE alumina-silicon carbide-carbon
  • 简介:Thecorrosionofrefractoriesresultsfromreactivetransport,namely,transportofagentsandchemicalreactionsoftheseagentswithimpregnatedmedium.Ononehand,thetransportinvolveseitherdiffusionorimpregnationdependingonthestateofthecorrosiveagentsandthemicrostructureofthehostmedia.Ontheotherhand,chemicalreactionsmaybeverynumerousandcomplex.ThisstudyfocusedonthereactiveimpregnationofAl2O3-CaOslagintoporoushighaluminarefractory.Thetransportpropertiesoftherefractorymaterialwereidentifiedbymeansofadedicatedcapillaryrisingtest.ChemicalreactionsbetweenthesolidhighaluminaskeletonandAl2O3-CaOslaginvolvesuccessivedissolution/precipitationmechanismsformingaluminatesoflime.Contrarytothethermodynamicpropertiesofthebinarysystem,thekineticsofthesesolid/liquidreactionsisnotwellknown.Corrosiontestsassociatedwiththequenchingmethod,XRDanalyseswereperformedforabetterunderstandingofthekinetics.Theresultsofthisstudyopenupacouplingapproachforpredictingthecorrosionwearofrefractory.

  • 标签: 高铝耐火材料 反应机制 浸渍介质 氧化钙 腐蚀剂 氧化铝
  • 简介:2004年底锥形煤气炉问世,立即风靡了整个小氮肥行业,一时间大有取代传统直筒炉的趋势。山东红目集团也在多方考证后,其10万t/a甲醇项目上选择了10台Φ261O/Φ2800锥形煤气炉,具体配置:采用Φ261O/Φ2800锥形夹套,水夹套高度2445mm,炉体高度2975mm;炉算高度1600mm选用C600—1.28,双级双支承滑动轴承风机,流量600m3/min,出气压力2800mmH2O

  • 标签: 煤气炉 锥形 运行经验 小氮肥行业 甲醇项目 C600