简介:Theeffectsofprocessparametersonthemicrostructuralevolution,includinggrainsizeandvolumefractionoftheαphaseduringhotformingofaTC6alloywereinvestigatedusingcompressiontests.Experimentswereconductedonthematerialwith(α+β)phasesatdeformationtemperaturesof800,860,920,and950°C,strainratesof0.001,0.01,1,and50s-1,andheightdirectionreductionsof30%,40%,and50%.Afterreachingapeakvaluenear920°C,thegrainsizeandvolumefractiondecreasewithfurtherincreaseofdeformationtemperature.ThestrainrateaffectsthemorphologiesandgrainsizeofαphaseoftheTC6titaniumalloy.Atalowerstrainrate,theeffectofthestrainrateonthevolumefractionisgreaterthanthatatahigherstrainrateundertheexperimentalconditions.Theeffectsofthestrainrateonthemicrostructurealsoresultfromdeformationheating.Thegrainsizeoftheαphaseincreaseswithanincreaseinheightdirectionreductionafteranearlydrop.Theeffectofheightdirectionreductiononthevolumefractionissimilartothatofthegrainsize.AlloftheopticalmicrographsandquantitativemetallographyshowthatdeformationprocessparametersaffectthemicrostructureduringhotformingoftheTC6alloy,andacorrelationbetweenthetemperature,strain,andstrainrateappearstobeasignificantfuzzycharacteristic.
简介:采用纯Mg、Zn、Ca粉末和纳米羟基磷灰石(nHA)粉末,通过粉末冶金方法制备Mg-5Zn-0.3Ca/nHA生物复合材料,研究不同nHA增强相含量(1%、2.5%和5%,质量分数)对Mg-5Zn-0.3Ca合金腐蚀性能的影响。通过模拟体液浸泡试验和电化学技术测试其耐腐蚀性。结果显示,添加1%和2.5%的nHA提高镁合金的耐腐蚀性,这是因为生物活性nHA促进稳定的磷酸盐和碳酸盐表面沉积层的形成,从而提高纳米复合材料的耐蚀性。然而,在镁合金中添加更高含量的nHA作为增强相时,表面沉积层的密度增加,导致局部腐蚀产生的气体无法及时排出而聚集在沉积层下,减小层与基体的粘着力,导致耐腐蚀性能下降。对镁合金及其纳米复合材料的间接细胞毒性评价表明其浸提液无细胞毒性,添加1%nHA的纳米复合材料的测试结果与阴性对照组几乎相似。
简介:本文对TB6钛合金锻件弦向和径向两种取样方向分别进行了室温和200℃下旋转弯曲高周疲劳、轴向低周疲劳和疲劳裂纹扩展性能试验研究。试验结果表明,弦向(C)和径向(R)两种取样方向对该合金锻件的旋转弯曲高周疲劳、轴向低周疲劳性能和疲劳裂纹扩展性能没有影响;温度升高可加速该合金锻件的疲劳裂纹萌生,但在裂纹扩展阶段,该合金高温下的韧性优势与屈服强度降低的劣势平衡的结果使其在室温~200℃温度范围内的疲劳性能基本不受温度的影响;在10—20mm的厚度范围内,厚度对该合金的疲劳裂纹扩展性能没有影响;在3.5%NaCl盐雾环境中。腐蚀介质对TB6钛合金的疲劳裂纹扩展速率在初始阶段有迟滞作用,但在应力强度因子范围大于14MPam后有加速作用。
简介:通过基于密度泛函理论的第一性原理计算方法,对MgCu2,Mg2Ca和MgZn2的力学性能和电子结构进行计算,计算所得晶格参数与实验值和文献值相吻合。合金形成热和结合能的计算结果表明,MgCu2具有最强的合金形成能力和结构稳定性。计算了MgCu2,Mg2Ca和MgZn2的弹性常数,推导了体模量、剪切模量、弹性模量和泊松比。结果表明,MgCu2、Mg2Ca和MgZn2均为延性相,MgCu2的刚度最大,MgZn2的塑性最好。通过对结合能和弹性常数的计算,预测了MgCu2、Mg2Ca和MgZn2的熔点。通过对态密度(DOS)、Mulliken布居数、电子占据数和差分电荷密度的计算,分析了MgCu2、Mg2Ca和MgZn2的结构稳定性和力学性能机制。最后,计算和讨论了3种金属间化合物的Debye温度。
简介:WeldingresearchofA6N01S-T5aluminumalloyprofileforhigh-speedtrainwasdonebyusinglaser-MIGhybridweldingandMIGweldingindividually.Andtheweldappearance,weldingdistortion,mechanicalpropertiesofthejointsandmicrostructureswereanalyzed.Thetestresultsdemonstratedthathigh-efficientweldingfortheprofilecanbeachievedbyusinglaser-MIGhybridwelding,thespeedofwhichcanbeover3.0m/min.Theprocessinghadagoodgapbridgingability,evenifthegapofthebuttjointwasupto2.0mm,agoodweldappearancecanalsobegot.Whilethehybridweldingspeedwasgreaterthan2.5m/min,theweldingdistortionofthelaser-tandemMIGhybridjointswasjustabout33%ofthatoftheMIGjoints,buttheweldingefficiencywasover3timesofMIGwelding.Andtensilestrengthofthehybridjointswas85%ofthatofA6N01S-T5basemetal,9%higherthanthatoftheMIGjoints.Fatiguepropertieswastestedindividuallywithpulsedtensilefatiguemethodintheconditionof1×107lifetime.Thetestresultsdemonstratedthatthefatiguestrengthofthejointswasalittlelowerthanthatofbasematerial,whichcouldbeupto115MPa.Butthefatiguestrengthofhybridweldingjointswas107.5MPa,whichwas23%higherthan87MPaofMIGweldingjoints.
简介:微结构和电子横梁的机械描述焊接了伪造Ti-6Al-4V的关节被调查。Microhardness测试显示熔化地区(FZ)的坚硬比影响热的地区(HAZ)和贱金属的高。张力的结果证明焊接关节的机械性质以静态的力量与贱金属的那些是可比较的并且根据在微观结构和焊接关节的机械性质之间的关系。焊接的最终的张力的强度等于时漏关节的,它显示横向的FZ的纵的FZ和那些的机械性质是一样。基础材料,关节,和焊接标本的Macromechanical行为和macrofracture和microfracture被观察。在标本破裂现象的三种类型之中的比较揭示下列特殊差别:(1)破裂模式,(2)在中央区域的酒窝模式的显微图,并且(3)在中央区域和转变区域的酒窝的尺寸。
简介:FlameheatingcombinedwithwatercoolingwasusedtostraightenA6N01aluminumalloyweldedjointandeffectofflameheatingpassonitsmicrostructureandmechanicalpropertieswasstudied.ResultsshowedthattheflameinducedtheprecipitationandgrowthoftheMg2SiphaseontheAlsubstrateforthethermalagingA6N01aluminumalloyweldedjoints,thusitledthedecreaseofmicro-hardnessandtensilestrengthoftheA6N01aluminumalloyweldedjointwiththeincreaseoftheheatingpass.However,thefatiguepropertyoftheflameheatedjointwasimprovedbecausetheMg2Siprecipitationhinderedtheinitiationandpropagationofthefatiguecrack.
简介:Themetal-organicchemicalvapordeposition(MOCVD)techniqueisapromisingprocessforhigh-temperaturesuperconductorYBa2Cu3O7-δ(YBCO)preparation.Inthistechnique,itisachallengetoobtainbariumprecursorswithhighvolatility.Inaddition,thepurity,evaporationcharacteristics,andthermostabilityofadoptedprecursorsinwholeprocesswilldecidethequalityandreproducibleresultsofYBCOfilm.Inthepresentreport,bis(2,2,6,6-tetramethyl-3,5-heptanedionato)barium(Ⅱ)(Ba(TMHD)2)wassynthesized,anditsstructurewasidentifiedbyFTIR,1HNMR,13CNMR,andESI-MSspectroscopy.Subsequently,thethermalpropertiesandthekineticsofdecompositionweresystematicallyinvestigatedbynonisothermalthermogravimetricanalysismethods.BasedontheaverageapparentactivationenergyevaluatedbytheOzawa,Kissinger,andFriedmanmethods,thevolatilizationprocesswasdiscussed,andallresultsshowthatBa(TMHD)2isunstableandhighlysensitivetothechangeoftemperatureduringthewholeevaporationprocess.Therefore,itisveryimportanttochoosesuitablevolatilizationtechnologyandconditionsforavoidingBa(TMHD)2break-down(orthermalaging)duringMOCVDprocess.Subsequently,thepossibleconversionfunctionisestimatedthroughtheCoats-Redfernmethodtocharacterizetheevaporationpatternsandfollowsaphaseboundaryreactionmechanismbythecontractingsurfaceequationwithaverageactivationenergyof118.7kJ.mol-1.