简介:Anovelsupportedliquidphasefilmcatalyst:SupportedPdCl2-(n-C4H9)4N+Cl-moltensaltswasfoundtobeaneffectivecatalystwithgoodstabilityforselectivehydrodechlorinationofCCl2F2(CFC-12)toitsalternativesCH2F2andCHClF2.AdditionofCoCl2,GaCl3andCuCl2toPdCl2-(n-C4H9)4N+Cl-modifiesthecatalyticperformanceofsupportedmoltensalts.
简介:Opticallyactive(R)-(+)-2,2’-bis(2-trifluoro-4-aminophenoxy)-1,1’-binaphthylwaspreparedfrom1,1’-bi-2-naphthol.Theopticallyactivearomaticpolyimidewasalsosuccessfullysynthesized.Thisnewpolymerhasgoodsolubility,thermalstabilityetc.Itsspecificrotationwasfoundtobe+174°,anditschiropticalpropertywasalsostudied.
简介:ThespectrumoftheΣ(1193)excitedstates,Σ,withisospinI=1andstrangenessS=??1isoneofthemostimportantissuesinhadronicphysics.TheΣresonancesaremostlyproducedandstudiedinK-inducedreactions.ManyΣresonancesarenowcatalogedbytheParticleDataGroup[1].However,ourknowledgeoftheseresonancesisstillverypoor.Intheenergyregionbelow2GeV,onlyafewofthemarewellestablished,suchastheΣ(1385)ofspin-parityJP=3=2+,Σ(1670)ofJp=3=2??andΣ(1775)ofJp=5=2??.Theothersarenotwellestablishedandsomeofthemareevenoflargeuncertaintiesontheirexistence.Thus,thestudyoftheΣresonancewiththeavailableexperimentaldataisnecessary.
简介:TofindoptimalconditionsforexpressingthesolubleformofsFv-2F3andtostudythepurificationandpropertyofitsderivativeSe-sFv-2F3,thepreferredexpressionconditionswereinvestigatedbymeansoforthogonaldesign.Thesecultureconditionsincludedincubationtemperature,inducerconcentration,inductiontimeandcellconcentration.TheevaluationofexpressionwasaccomplishedbytheanalysisofwholecelllysatesandtheyieldofsolublesFv-2F3wascalculatedaccordingtotheanalysisofProfinder(FTI-500,Pharmacia).Thepurificationprocedurewascarriedoutviaatwo-steppurificationprocedureconsistingofion-exchangechromatography,followedbyimmobilizedmetalaffinitychromatography(IMAC).TheantioxidantefficacyofSe-sFv-2F3wasdemonstratedbythedeterminationofthecontentofthemainproductoflipidperoxidation,MDA,theviabilityofcellsandtheactivityofLDH.WeobtainedthepreferredcultureconditionstogrowtheengineeredbacteriaandtheprocedureforpreparingsolublesFv-2F3andconfirmedtheantioxidantefficacyofSe-sFv-2F3.
简介:Anewspectralproblemisproposed,andnonlineardifferentialequationsofthecorrespondinghierarchyareobtained.Withthehelpofthenonlinearizationapproachofeigenvalueproblems,anewfinite-dimensionalHamiltoniansystemonR2nisobtained.Ageneratingfunctionapproachisintroducedtoprovetheinvolutionofconservedintegralsanditsfunctionalindependence,andtheHamiltonianflowsarestraightenedbyintroducingtheAbel-Jacobicoordinates.Atlast,basedontheprinciplesofalgebracurve,thequasi-periodicsolutionsforthecorrespondingequationsareobtainedbysolvingtheordinarydifferentialequationsandinversingtheAbel-Jacobicoordinates.
简介:建立了非线性热力学模型,定性分析了外加应力和外加温度对外延生长在正交基底上的Pb(Zr1-xTix)O3(PZT)薄膜相变的影响。在外力场下,固定其中一个方向失配应变e1=0.005,模拟得到了不同组分的PZT薄膜的失配应变一外加应力的相图。研究发现,随着Ti组分的减少,出现了新相正交a1c相和四方相a1相,且新相区域也会随Ti组分的不同而变化。在外加拉应力下,c相是薄膜较易出现的相,而在外加压应力下薄膜易处于a1a2相。在不同温度场下,模拟非等轴失配应变的PZT薄膜得到不同组分的PZT薄膜的失配应变一外加温度相图。当组分x≤0.7时,相图中出现了正交a1c相,由于非等轴失配应变的存在,使得从顺电相向r相发生相变的过程中,多出了正交a1a2相;同时另一新的四方a1相也出现在沿失配应变正方向e2被拉伸的区域。随着Ti组分的增加,单斜r相的面积缩小且位置下移。之前存在的四相点也变为了三相点,而正交相a1a2相则向相图的中心位置移动。模拟结果对研究外场下铁电薄膜微器件的性能变化具有一定的指导意义。
简介:Anecessaryandsufficientconditionofregularityof(0,1,…,m-2,m)interpo-lationonthezerosoftheLaguerrepolynomialsLn(α)(x)(α≥-1)inamanageableformisestablished.Meanwhile,theexplicitrepresentationofthefundamentalpolynomials,whentheyexist,isgiven.Moreover,itisshownthat,iftheproblemof(0,1,…,m-2,TO)interpolationhasaninfinityofsolutions,thenthegeneralformofthesolutionsisf0(x)+Cf1(x)withanarbitraryconstantC.
简介:Usingtheextensionhomogeneousbalancemethod,wehaveobtainedsomenewspecialtypesofsolitonsolutionsofthe(2+1)-dimensionalKdVequation.Startingfromthehomogeneousbalancemethod,onecanobtainanonlineartransformationtosimple(2+1)-dimensionalKdVequationintoalinearpartialdifferentialequationandtwobilinearpartialdifferentialequations.Usually,onecanobtainonlyakindofsoliton-likesolutions.Inthisletter,wefindfurthersomespecialtypesofthemultisolitonsolutionsfromthelinearandbilinearpartialdifferentialequations.``
简介:S.M.LozinskiiprovedtheexactconvergencerateatthezeroofLagrangeinterpolationpolynomialsto|x|basedonequidistantnodesin[-1,1].In2000,M.RevergeneralizedS.M.Lozinskii'sresultto|x|α(0≤α≤1).Inthispaperwewillpresenttheexactrateofconvergenceatthepointzerofortheinterpolantsof|x|α(1<α<2)..
简介:WehavecomprehensivelyinvestigatedthefrustratedJ1-J2-J3Heisenbergmodelonasimplecubiclattice.Thismodelallowsthreeregimesofmagneticorder,viz.,(π;π;π),(0;π;π)and(0;0;π),denotedasAF1,AF2,andAF3,respectively.Theeffectsoftheinterplayofneighboringcouplingsonthemodelarestudiedintheentiretemperaturerange.Thezerotemperaturemagneticpropertiesofthismodelarediscussedutilizingthelinearspinwave(LSW)theory,nonlinearspinwave(NLSW)theory,andGreen’sfunction(GF)method.ThezerotemperaturephasediagramsevaluatedbytheLSWandNLSWmethodsareillustrated,andareobservedtoexhibitdifferentparameterboundaries.Incertainregionsandalongtheparameterboundaries,thepossiblephasetransformationsdrivenbytheparametersarediscussed.TheresultsobtainedusingtheLSW,NLSW,andGFmethodsarecomparedwiththoseobtainedusingtheseriesexpansion(SE)method,andareobservedtobeingoodagreementwhenthevalueofJ2isnotclosetotheparameterboundaries.ThegroundstateenergiesobtainedusingtheLSWandNLSWmethodsareclosetothatobtainedusingtheSEmethod.Atfinitetemperatures,onlytheGFmethodisemployedtoevaluatethemagneticproperties,andthecalculatedphasediagramisobservedtobeidenticaltotheclassicalphasediagram.Theresultsindicatethatattheparameterboundaries,atemperature-drivenfirst-orderphasetransitionbetweenAF1andAF2mayoccuralongtheboundaryline.AlongtheAF1-AF3andAF2-AF3boundarylines,AF3islessstablethanAF1andAF2.OurcalculatedcriticaltemperatureagreeswiththatobtainedusingMonteCarlosimulationsandpseudofermionfunctionalrenormalizationgroupscheme.
简介:首次制备出粉末微晶BaCl0.5Br0.5F:Sm2+红色发光材料,并测量了其低温光谱。发现其谱线宽度与BaClF:Sm2+的相比较有了约十倍左右的非均匀增宽,而且相应于5D0,1,2→7F0,1的谱线由两个峰间距分别为15cm-1,65cm-1的谱线构成,峰间距只与基态7F0和7F1有关。W.Lenth&W.E.Morener[1]讨论了光子门光谱烧孔作为频率微区光学记录的理论和应用的可能性。对于长存的光谱烧孔,可以进行二进制的数据存储与改写。该技术为实现大容量、高速度的光学计算机的应用提供了新的前景。在这方面已经有了不少的研究工作[2~6]。为提高存储容量,需使光谱线非均匀增宽,以提供更多的光谱烧孔可能性。为此目的,首次制备出粉末微晶BaCl0.5Br0.5F:Sm2+红色发光材料,并测量了其低温光谱,并将其与BaClF:Sm2+的低温光谱进行了比较分析。
简介:WeinvestigatethesensitivityoftheangularrotationmeasurementwiththemethodofhomodynedetectioninSU(2)andSU(1,1)interferometersbyemployingorbitalangularmomentum(OAM).BycombiningacoherentbeamwithavacuumbeaminanSU(2)interferometer,wegetthesensitivityoftheangularrotationmeasurementas1/(2N1/2l).WecansurpassthelimitoftheangularrotationmeasurementinanSU(1,1)interferometerbycombiningacoherentbeamwithavacuumbeamorasqueezedvacuumbeamwhentheprobebeamhasOAM.Withoutinjection,thesensitivitycanreach1/(2N1/2l).Inaddition,byemployinganotherconstructionofanSU(1,1)interferometerwherethepumpbeamhasOAM,withthesameinjectionofanSU(1,1)interferometer,thesensitivityoftheangularrotationmeasurementcanbeimprovedbyafactorof2,reaching1/(4Nl).Theresultsconfirmthepotentialofthistechnologyforprecisionmeasurementsinangularrotationmeasurements.
简介:利用Gaussian03软件包,采用多种方法和多种基组对CCl和CCl2分子的基态结构进行优化计算,优选出B3P86/6-311+G(3df)方法对CCl分子进行计算得到基态为X2Π、键长RCCl=0.16442nm,谐振频率ωe=886.3062cm-1;优选出B3P86/6-311G(2df)方法对CCl2分子进行计算得到基态为X1A1,平衡核间距RC—Cl=0.17194nm、键角βCl—C—Cl=109.2457°、离解能De=3.4635eV,并计算出了谐振频率和力常数,其结果与实验值符合很好.并采用多体展式理论推导出CCl2自由基的解析势能函数,其等值势能图准确呈现出CCl2分子的结构特征及能量变化曲线.由此讨论了Cl+CCl和C+ClCl分子反应的势能面特征.可用于研究该分子的微观反应动力学特性.